Preparation and Up-Conversion Luminescence of Yb3+ and Er3+ Co-Doped BaF2 Phosphor

2011 ◽  
Vol 287-290 ◽  
pp. 490-493
Author(s):  
Li Qun Cheng ◽  
Guang Cheng ◽  
Rui Dong ◽  
Xi Yan Zhang

Yb3+and Er3+co-doped BaF2phosphors were prepared by high temperature solid reaction method. Effects of mol content ratios of Yb3+ion to Er3+ion (CYb3+∶CEr3+) and charge compensation agent Na2SiF6 contents on the up-conversion luminescence of the samples were studied. The XRD and PL were carried out to investigate the phases and the up-conversion luminescence. Three up-conversion emissions were observed with peaks at 460nm, 548nm and 660nm respectively. The up-conversion luminescence intensity increases firstly, and then decreases with increasing CYb3+∶CEr3+ and the optimal ratio was found to be at 12:2 with fixed Er3+contents 2mol%. The up-conversion emission intensity was enhanced by introducing Na2SiF6 as the charge compensation agents and its optimal content was found to be 2mol%.

RSC Advances ◽  
2016 ◽  
Vol 6 (40) ◽  
pp. 33387-33392 ◽  
Author(s):  
Zhongran Yao ◽  
Ruiqing Chu ◽  
Zhijun Xu ◽  
Jigong Hao ◽  
Guorong Li

Lead-free piezoelectric ceramics with the formula of Sr1−x(Li,Ce)x/2(Na0.5Bi0.5)Bi4Ti5O18 (LCSNBT-x, x = 0.0, 0.1, 0.2, 0.3, 0.4), were prepared by a conventional solid-state reaction method.


2020 ◽  
Vol 49 (24) ◽  
pp. 8194-8200 ◽  
Author(s):  
Jiashan Mao ◽  
Bin Jiang ◽  
Peng Wang ◽  
Liting Qiu ◽  
Muhammad Tahir Abass ◽  
...  

Eu3+ and Er3+ co-doped YNbO4 powder phosphors were synthesized by a traditional high-temperature solid-state reaction method.


RSC Advances ◽  
2017 ◽  
Vol 7 (25) ◽  
pp. 15222-15227 ◽  
Author(s):  
Baoxing Wang ◽  
Qiang Ren ◽  
Ou Hai ◽  
Xiulan Wu

The Ba2P2O7:Tb3+, Eu3+ phosphors were synthesized by a high temperature solid-state reaction method in air atmosphere and their crystal structures, lifetime, luminescence properties, and energy transfer mechanism were investigated in detail.


2018 ◽  
Vol 47 (48) ◽  
pp. 17515-17524 ◽  
Author(s):  
Fengjun Chun ◽  
Binbin Zhang ◽  
Honggang Liu ◽  
Wen Deng ◽  
Wen Li ◽  
...  

A series of Na+ and Pr3+ co-doped orange-emitting CaYAl3O7 (CYAO) phosphors were prepared by a conventional high-temperature solid-state reaction method.


2020 ◽  
Vol 49 (12) ◽  
pp. 3743-3749 ◽  
Author(s):  
Ruling Tang ◽  
Chunli Hu ◽  
Jianghe Feng ◽  
Zhi Fang ◽  
Yan Chen ◽  
...  

Two new inorganic metal borate derivatives, Sr5TeO2(BO3)4 and NaSr5(BO3)(SiO4)2, have been obtained through a high temperature solid reaction method.


RSC Advances ◽  
2016 ◽  
Vol 6 (49) ◽  
pp. 42770-42777 ◽  
Author(s):  
Gui-Gen Wang ◽  
Xiao-Fei Wang ◽  
Li-Wen Dong ◽  
Qi Yang

In this article, novel green-emitting Ce3+, Tb3+ co-doped Al6Si2O13 phosphors with good thermal stability have been successfully prepared by high-temperature solid-state reaction method.


2020 ◽  
Author(s):  
Weihong Lai ◽  
Heng Wang ◽  
Quan jiang ◽  
Zichao Yan ◽  
Hanwen Liu ◽  
...  

<p>Herein, we develop a non-selective charge compensation strategy to prepare multi-single-atom doped carbon (MSAC) in which a sodium p-toluenesulfonate (PTS-Na) doped polypyrrole (S-PPy) polymer is designed to anchor discretionary mixtures of multiple metal cations, including iron (Fe<sup>3+</sup>), cobalt (Co<sup>3+</sup>), ruthenium (Ru<sup>3+</sup>), palladium (Pd<sup>2+</sup>), indium (In<sup>3+</sup>), iridium (Ir<sup>2+</sup>), and platinum (Pt<sup>2+</sup>) . As illustrated in Figure 1, the carbon surface can be tuned with different level of compositional complexities, including unary Pt<sub>1</sub>@NC, binary (MSAC-2, (PtFe)<sub>1</sub>@NC), ternary (MSAC-3, (PtFeIr)<sub>1</sub>@NC), quaternary (MSAC-4, (PtFeIrRu)<sub>1</sub>@NC), quinary (MSAC-5, (PtFeIrRuCo)<sub>1</sub>@NC), senary (MSAC-6, (PtFeIrRuCoPd)<sub>1</sub>@NC), and septenary (MSAC-7, (PtFeIrRuCoPdIn)<sub>1</sub>@NC) samples. The structural evolution of carbon surface dictates the activities of both ORR and HER. The senary MSAC-6 achieves the ORR mass activity of 18.1 A·mg<sub>metal</sub><sup>-1</sup> at 0.9 V (Vs reversible hydrogen electrode (RHE)) over 30K cycles, which is 164 times higher than that of commercial Pt/C. The quaternary MSAC-4 presented a comparable HER catalytic capability with that of Pt/C. These results indicate that the highly complexed carbon surface can enhance its ability over general electrochemical catalytic reactions. The mechanisms regarding of the ORR and HER activities of the alternated carbon surface are also theoretically and experimentally investigated in this work, showing that the synergistic effects amongst the co-doped atoms can activate or inactivate certain single-atom sites.</p>


Author(s):  
M. Chomiak ◽  
J. Trawczyński ◽  
M. Zawadzki

AbstractZn–Ti–Co(Ni) sorbents for H2S removal from model hot coal were prepared and characterized. Effects of cobalt (Co) and nickel (Ni) on the sorbents texture, structure, H2S sorption capacity and regeneration properties were determined. TiO2 formed mixed metal oxides with CoO and NiO in the fresh sorbents, while TiO2 and nanocrystalline sulfides of Zn, Co, Ni were found in sulphided ones. The oxidative regeneration of sulphided sorbents re-formed mixed oxides. Sorption capacity of studied materials increased along with an increase of the amount of added Co (Ni) and also with the number of work cycles. Co-doped Zn–Ti materials adsorbed up to 244% more sulfur than these of Zn–Ti, while Ni-doped materials adsorbed ca. twice more H2S than the corresponding Co-doped sorbents. The addition of Co (Ni) decreased the temperature of ZnS oxidation. The catalytic effect of the Co (Ni) oxides on the oxidation of ZnS was suggested.


2009 ◽  
Vol 156-158 ◽  
pp. 275-278
Author(s):  
Xiang Yang Ma ◽  
Yan Feng ◽  
Yu Heng Zeng ◽  
De Ren Yang

Oxygen precipitation (OP) behaviors in conventional and nitrogen co-doped heavily arsenic-doped Czocharalski silicon crystals subjected to low-high two-step anneals of 650 oC/8 h + 1000 oC/4-256 h have been comparatively investigated. Due to the nitrogen enhanced nucleation of OP during the low temperature anneal, much higher density of oxygen precipitates generated in the nitrogen co-doped specimens. With the extension of high temperature anneal, Oswald ripening of OP in the nitrogen co-doped specimens preceded that in the conventional ones. Moreover, due to the Oswald ripening effect, the oxygen precipitates in the conventional specimens became larger with a wider range of sizes. While, the sizes of oxygen precipitates in the nitrogen co-doped specimens distributed in a much narrower range with respect to the conventional ones.


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