scholarly journals Effect of cobalt (nickel) oxide on the properties of zinc–titanium sorbents for high temperature desulphurization of model coal gas

Author(s):  
M. Chomiak ◽  
J. Trawczyński ◽  
M. Zawadzki

AbstractZn–Ti–Co(Ni) sorbents for H2S removal from model hot coal were prepared and characterized. Effects of cobalt (Co) and nickel (Ni) on the sorbents texture, structure, H2S sorption capacity and regeneration properties were determined. TiO2 formed mixed metal oxides with CoO and NiO in the fresh sorbents, while TiO2 and nanocrystalline sulfides of Zn, Co, Ni were found in sulphided ones. The oxidative regeneration of sulphided sorbents re-formed mixed oxides. Sorption capacity of studied materials increased along with an increase of the amount of added Co (Ni) and also with the number of work cycles. Co-doped Zn–Ti materials adsorbed up to 244% more sulfur than these of Zn–Ti, while Ni-doped materials adsorbed ca. twice more H2S than the corresponding Co-doped sorbents. The addition of Co (Ni) decreased the temperature of ZnS oxidation. The catalytic effect of the Co (Ni) oxides on the oxidation of ZnS was suggested.

Alloy Digest ◽  
1961 ◽  
Vol 10 (12) ◽  

Abstract MULTIMET alloy is cobalt-nickel-chromium-iron austenitic alloy having high oxidation and scaling resistance along with good high-temperature properties. It tends to work harden but does not respond significantly to age-hardening. It is made in a wrought grade (0.08-0.16% carbon) and a casting grade (0.20% max. carbon). This datasheet provides information on composition, physical properties, elasticity, and tensile properties as well as creep and fatigue. It also includes information on high temperature performance as well as forming, heat treating, machining, and joining. Filing Code: SS-28. Producer or source: Haynes Stellite Company. Originally published May 1955, revised December 1961.


2020 ◽  
Vol 13 (12) ◽  
pp. 124002
Author(s):  
Tao Hu ◽  
Wanli Ma ◽  
Jing Wu ◽  
Zhibo Zhang ◽  
Wei Zhou ◽  
...  

2005 ◽  
Vol 19 (4) ◽  
pp. 1606-1610 ◽  
Author(s):  
Yili Li ◽  
Jian Li ◽  
Yuquan Jin ◽  
Youqing Wu ◽  
Jinsheng Gao

2009 ◽  
Vol 156-158 ◽  
pp. 275-278
Author(s):  
Xiang Yang Ma ◽  
Yan Feng ◽  
Yu Heng Zeng ◽  
De Ren Yang

Oxygen precipitation (OP) behaviors in conventional and nitrogen co-doped heavily arsenic-doped Czocharalski silicon crystals subjected to low-high two-step anneals of 650 oC/8 h + 1000 oC/4-256 h have been comparatively investigated. Due to the nitrogen enhanced nucleation of OP during the low temperature anneal, much higher density of oxygen precipitates generated in the nitrogen co-doped specimens. With the extension of high temperature anneal, Oswald ripening of OP in the nitrogen co-doped specimens preceded that in the conventional ones. Moreover, due to the Oswald ripening effect, the oxygen precipitates in the conventional specimens became larger with a wider range of sizes. While, the sizes of oxygen precipitates in the nitrogen co-doped specimens distributed in a much narrower range with respect to the conventional ones.


1996 ◽  
Vol 35 (5) ◽  
pp. 1487-1495 ◽  
Author(s):  
A. G. J. van der Ham ◽  
A. B. M. Heesink ◽  
W. Prins ◽  
W. P. M. van Swaaij

2001 ◽  
Vol 72 (1) ◽  
pp. 23-33 ◽  
Author(s):  
Bin-lin Dou ◽  
Jin-sheng Gao ◽  
Xing-zhong Sha

Sign in / Sign up

Export Citation Format

Share Document