Structure and Properties of Calcium-Magnesium-Silicate Ceramic Fiber with Nd2O3

2011 ◽  
Vol 295-297 ◽  
pp. 406-409 ◽  
Author(s):  
Hao Liu ◽  
Xi Tang Wang ◽  
Zhou Fu Wang ◽  
Bao Guo Zhang
Keyword(s):  
Silicate Glass ◽  
Crystallization Behavior ◽  
Glass Network ◽  
Magnesium Silicate ◽  
Ceramic Fiber ◽  
Structure And Properties ◽  
Viscosity Curve ◽  
Calcium Magnesium ◽  
Lower Temperature ◽  
Silicate Ceramic

Structure, viscosity and crystallization behavior of CaO-MgO-SiO2 ceramic fiber with Nd2O3 were investigated by DTA, XRD and FTIR techniques. The results show that the addition of Nd2O3 enhanced the fiberization by extending the viscosity curve of the glass melt to lower temperature and improved the melt fiberizability. With the reinforcement of silicate glass network by Nd3+, the precipitation of crystals in fibers was inhibited at high temperatures.

Effects of Al2O3 on the Structure and Properties of Calcium-Magnesium-Silicate Glass Fiber

2012 ◽  
Vol 450-451 ◽  
pp. 42-45
Author(s):  
Hao Liu ◽  
Xi Tang Wang ◽  
Zhou Fu Wang ◽  
Bao Guo Zhang
Keyword(s):  
High Temperature ◽  
Glass Fiber ◽  
Silicate Glass ◽  
Network Structure ◽  
Glass Fibers ◽  
Rapid Development ◽  
Magnesium Silicate ◽  
Ceramic Fiber ◽  
Dissolution Properties ◽  
Calcium Magnesium

Calcium-magnesium-silicate glass fiber is a kind of candidate materials for aluminosilicate ceramic fiber in high temperature resistant field. However, the large thermal shrinkage limits its rapid development and industrial application in high temperature insulation field. It has been known that the shrinkage under high temperatures is mainly affected by the structure and crystallization mechanisms of glass fibers. Thus, Al2O3 was chosen as additive in the chemical composition of glass fiber to investigate the glassy network structure, crystallization and dissolution properties of calcium-magnesium-silicate glass fiber by DTA, XRD and ICP-AES techniques. The results show that with the addition of Al2O3, the glassy network structure was strengthened and the precipitation of crystals was inhibited for heat-treated fibers. As for the dissolution properties in physiological fluids, though the weight losses, changes of pH values and leached ions concentration lowered slightly with the addition of Al2O3 for the intensified network structure, fibers still present high dissolution rates.

Dissolution behavior of calcium-magnesium-silicate glass fiber

2011 ◽  
Vol 18 (6) ◽  
pp. 1833-1837 ◽  
Author(s):  
Hao Liu ◽  
Xi-tang Wang ◽  
Bao-guo Zhang ◽  
Zhou-fu Wang
Keyword(s):  
Glass Fiber ◽  
Silicate Glass ◽  
Magnesium Silicate ◽  
Dissolution Behavior ◽  
Calcium Magnesium

Influence of Composition on the Characterization and Crystallization of Calcium-Magnesium-Silicate Glass-Ceramics

2010 ◽  
Vol 105-106 ◽  
pp. 592-596
Author(s):  
Hao Liu ◽  
Xi Tang Wang ◽  
Bao Guo Zhang ◽  
Zhou Fu Wang
Keyword(s):  
Crystallization Behavior ◽  
Density Measurement ◽  
Glass Ceramics ◽  
Weight Ratio ◽  
Magnesium Silicate ◽  
Treatment Procedure ◽  
Density Measurements ◽  
Structural Network ◽  
Calcium Magnesium ◽  
Crystal Phases

The effects of replacement of MgO by CaO, on the characterization and crystallization behavior of glas-ceramics in the CaO-MgO-SiO2 system were investigated by DTA, XRD and FTIR techniques and by density measurements. The results show that the glass transition temperature (Tg) and crystallization temperature (Tc) increase and glassy structural network becomes denser with increasing the CaO/MgO weight ratio. After certain heat-treatment procedure, the major crystal phases change from calcium magnesium silicate (diopside) to calcium silicate (parawollastonite) at the replace of MgO by CaO. Studying of density measurement shows that, the density of glass samples increase by increasing CaO content on the expense of MgO.

Role of vanadium oxide on the lithium silicate glass structure and properties

2021 ◽  
Author(s):  
Anuraag Gaddam ◽  
Amarnath R. Allu ◽  
Hugo R. Fernandes ◽  
George E. Stan ◽  
Catalin C. Negrila ◽  
...  
Keyword(s):  
Vanadium Oxide ◽  
Silicate Glass ◽  
Glass Structure ◽  
Lithium Silicate ◽  
Structure And Properties ◽  
Lithium Silicate Glass

Ceramic Proppants Based on Ultrabasic Rocks of Kazakhstan Chromite Ore Deposits

2019 ◽  
Vol 946 ◽  
pp. 169-173
Author(s):  
A.A. Biryukova ◽  
T.D. Dzhienalyev ◽  
A.V. Boronina
Keyword(s):  
Oil And Gas ◽  
Mineralogical Composition ◽  
Magnesium Silicate ◽  
Gas Production ◽  
Ore Deposits ◽  
Raw Material ◽  
Chrome Spinel ◽  
Overburden Rock ◽  
Oil And Gas Production ◽  
Silicate Ceramic

The purpose of the work is the obtaining of magnesium silicate ceramic proppants, based on ultrabasic overburden rocks of Kempirsai deposits of chromite ores (Kazakhstan). The chemical and mineralogical composition of ultrabasic overburden rock was studied by chemical, microscopic and X-ray diffraction analyzes. It is established that the main mineral of ultrabasic overburden rocks is serpentine, present in the form of fibrous chrysotile and lamellar antigorite. In the impurities are iron oxides and hydroxides, chrome spinel, carbonates, quartz. Assessment of the use of overburden rocks as a raw material for the production of ceramic proppants was carried out. The sintering interval of overburden rocks was determined at 1280-1300 °C. The sintering firing optimum temperature of ceramics, based on this type of raw material is 1300 °C. It is established that to harden the structure of magnesium silicate ceramic it is necessary to activate the raw material thermally at a temperature of 1000 °C. The influence of binder type on the properties of magnesium silicate proppants, based on the Kempirsai serpentinites was studied. Magnesium silicate proppants, based on ultrabasic overburden rocks, were obtained with the following properties: apparent density – 1.6 g/cm3, strength resistance (52 MPa) – 14%, sphericity and roundness – 0.8; chemical resistance (hydrochloric acid) – 98%, static strength of the fraction 16/20 - 72–118 N/granule. The field of application is oil and gas production, metallurgy and ceramic industries.

Luminescence properties of dysprosium doped calcium magnesium silicate phosphor by solid state reaction method

2015 ◽  
Vol 649 ◽  
pp. 1329-1338 ◽  
Author(s):  
Ishwar Prasad Sahu ◽  
Priya Chandrakar ◽  
R.N. Baghel ◽  
D.P. Bisen ◽  
Nameeta Brahme ◽  
...  
Keyword(s):  
Solid State ◽  
Solid State Reaction ◽  
Magnesium Silicate ◽  
Solid State Reaction Method ◽  
Luminescence Properties ◽  
Reaction Method ◽  
Silicate Phosphor ◽  
Calcium Magnesium

scholarly journals Effects of zinc acetate and cucurbit[6]uril on PP composites: crystallization behavior, foaming performance and mechanical properties

e-Polymers ◽  
2018 ◽  
Vol 18 (6) ◽  
pp. 491-499 ◽  
Author(s):  
Yuhui Zhou ◽  
Li He ◽  
Wei Gong
Keyword(s):  
Impact Strength ◽  
Flexural Strength ◽  
Zinc Acetate ◽  
Crystallization Behavior ◽  
Cell Structure ◽  
Weight Ratio ◽  
Crystallization Rate ◽  
Sem Images ◽  
Improvement Effect ◽  
Lower Temperature

AbstractIn this study, polypropylene (PP) foams were prepared with 1.0 wt% of cucurbit[6]uril (Q[6]), zinc acetate (Zn(Ac)2), Zn@Q[6] (a supramolecular compound synthesized from Q[6] and Zn(Ac)2), or a mixture of Zn(Ac)2 and Q[6] (weight ratio of 1:1) through injection molding in the presence of a chemical blowing agent, azodicarbonamide. The effect of the additions on the crystallization behavior and foaming performance of PP and the mechanical characterizations of the foaming samples were determined. The results showed that the additions can change the crystallization type from homogeneous to heterogeneous, increase the crystallization rate and shrink the size but increase the density of spherulites. Among the additions, Q[6] most significantly altered the crystallization properties. Scanning electron microscopy (SEM) images revealed that the PP foaming performance can be improved by Zn(Ac)2 addition at a lower temperature (175°C); however, further increasing the temperature had an undesirable effect. Q[6] exhibited the optimum foaming improvement effect on PP in a wide temperature range (175–195°C). Adding nanoparticles also enhanced the tensile properties, flexural strength and impact strength of foaming PP at low temperatures. However, with increasing temperature, the poor cell structure demonstrated undesirable effects in terms of tensile strength, flexural strength and impact strength.

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