Effect of Rare Earth Y2O3 Content on Microstructure of Gradient Bioceramic Composite Coating Produced by Wide-Band Laser Cladding

2005 ◽  
Vol 288-289 ◽  
pp. 351-354 ◽  
Author(s):  
Qi Bin Liu ◽  
Long Jiang Zou ◽  
Min Zheng ◽  
Chuang Dong
Keyword(s):  
Rare Earth ◽  
Composite Coating ◽  
Laser Cladding ◽  
Dominant Role ◽  
Monosodium Glutamate ◽  
Wide Band ◽  
Experimental Results ◽  
Ti Alloy ◽  
Y2o3 Content ◽  
Rare Earth Content

In the present paper, bioceramic coating with gradient compositional design was prepared on surface of Ti alloy by using wide-band laser cladding. Effect of rare earth Y2O3 content on gradient bioceramic composite coating was studied. The experimental results indicated that adding rare earth can refine grain. Different contents of rare earth affect formation of HA andβ-TCP in bioceramic coating. With increase of rare earth content, HA andβ-TCP were synthesized. When content of rare earth ranged from 0.4% to 0.6%, the active extent of rare earth in synthesizing HA andβ-TCP got best, which indicated that “monosodium glutamate” effect of rare earth played a dominant role. However, when rare earth content was up to 0.8%, the active extent of rare earth in synthesizing HA and β-TCP conversely went down, which demonstrated that rare earth gradually lost its catalysis in manufacturing HA andβ-TCP.

The Bioactivity of Gradient Composite Bioceramic Coating with Different Contents of Multiple Rare Earth Deoxide Fabricated by Wide Band Laser Cladding

2013 ◽  
Vol 706-708 ◽  
pp. 318-322 ◽  
Author(s):  
Ling Yan Zhang ◽  
Qi Bin Liu
Keyword(s):  
Titanium Alloy ◽  
Rare Earth ◽  
Thermal Stress ◽  
Laser Cladding ◽  
Bonding Strength ◽  
Wide Band ◽  
Experimental Results ◽  
Spherical Particles ◽  
Coating Materials ◽  
Gradient Coating

To improve bonding strength between titanium alloy and coating and to eliminate thermal stress during laser cladding, a gradient coating materials is designed. And the gradient coating with different contents of multiple rare earth deoxide was produced by wide band laser cladding technique. The experimental results indicate that when addition of Sm2O3 is fixed to 0.3wt.%, as addition of Y2O3 increases, the microstructure of bioceramic is different. When addition of Y2O3 reaches 0.4wt.%, the amount of Ca-P based bioactive phases such as HA, α-TCP as well as β-TCP becomes biggest. After soaking the coating with 0.3wt.% Sm2O3 and 0.4wt.% Y2O3 in SBF for 14 days, a large amount of Ca-P white spherical particles can be observed on coating, which demonstrates the bioceramic coating is of best bioactivity.

The Biocompatibility and Bioactivity of Gradient Composite Bioceramic Coating with Different Content of Nd2O3 Fabricated by Wide Band Laser Cladding

2011 ◽  
Vol 415-417 ◽  
pp. 1837-1840 ◽  
Author(s):  
Ming Xiao ◽  
Qi Bin Liu ◽  
Yi Zhi Zhu
Keyword(s):  
Rare Earth ◽  
Thermal Stress ◽  
Laser Cladding ◽  
Wide Band ◽  
Composition Gradient ◽  
Ti Alloy ◽  
Coating Composition ◽  
Gradient Coatings ◽  
Different Content ◽  
Number Of Cells

To eliminate thermal stress during laser cladding and to raise the bonding strength between substrate and coating, composition gradient coatings are designed and fabricated by using wide-band laser cladding technique on a Ti alloy. The rare earth Nd2O3 was added to improve the properties of the bioceramic coating. The experimental results indicate that when the adding of Nd2O3 reaches 0.6wt%, the characteristic peaks of HA and β-TCP are the highest, which demonstrates the amount of HA and β-TCP is the largest. However, when the content of Nd2O3 is up to 0.8wt%, the peaks of HA and β-TCP conversely goes down. The biocompatibility and bioactivity are related to the amount of HA and β-TCP catalyzed by Nd2O3. When the content of Nd2O3 is 0.6wt%, the number of cells proliferated and the ALP secreted on coatings is the most, which indicate the biocompatibility and bioactivity of gradient bioceramic coating is the best.

Effect of Mixed Multiple Rare Earth Oxide on the Microstructure of Bioceramic Coating Prepared by Wide Band Laser Cladding

2014 ◽  
Vol 989-994 ◽  
pp. 775-778
Author(s):  
Zheng Zhang ◽  
Qi Bin Liu ◽  
Ling Yan Zhang ◽  
Hai Bin Jiang ◽  
Pei Ze Jiang
Keyword(s):  
Titanium Alloy ◽  
Rare Earth ◽  
Laser Cladding ◽  
Rare Earths ◽  
Wide Band ◽  
Rare Earth Oxide ◽  
Experimental Results ◽  
Bioceramic Coatings

In order to researching the microstructure of bioceramic coating on the surface medical titanium alloy (Ti–6Al–4V), the gradient bioceramic coatings are fabricated by wide-band laser cladding. The influence of multiple rare earths oxide La2O3 and CeO2 on microstructure of bioceramic coating were studied. The experimental results demonstrated that mixed La2O3 and CeO2 have an effect on forming-ability of HA\β-TCP in bioceramic coating and also refined the grain of bioceramic coatings. The largest amount of HA\β-TCP is presented among all the groups when the contents of La2O3 and CeO2 are 0.6wt.%, 0.4 wt.%, respectively.

The Microstructure of Gradient Composite Bioceramic Coating with Single and Multiple Rare Earth Oxide Fabricated by Wide Band Laser Cladding

2013 ◽  
Vol 341-342 ◽  
pp. 171-174
Author(s):  
Ling Yan Zhang ◽  
Qi Bin Liu ◽  
Pei Ze Jiang ◽  
Zheng Zhang
Keyword(s):  
Rare Earth ◽  
Thermal Stress ◽  
Coral Reef ◽  
Laser Cladding ◽  
Bonding Strength ◽  
Wide Band ◽  
Rare Earth Oxide ◽  
Spherical Particles ◽  
Ti Alloy ◽  
Coating Materials

To improve bonding strength between Ti alloy and bioceramic coating and to eliminate thermal stress during laser cladding, gradient bioceramic coating materials is designed. The bioceramic coating is fabricated by wide band laser cladding technique. And the effect of adding single and multiple rare earth oxide on microstructure is investigated. The samples are soaked with SBF for 14 days, the experimental results indicate that when the content of single rare earth oxide is 0.6wt.%Y2O3, a large number of bioactivity phase and chrysanthemum shape microstructure can be observed. When the content of single rare earth oxide is 0.2wt.%Sm2O3, a lot of bioactivity phase and coral reef shape microstructure can be observed. When the content of multiple rare earth oxide is 0.3wt.%Sm2O3 and 0.4wt.%Y2O3, a large amount of bioactivity phase and more homogeneous and dense spherical particles can be observed on coating, which demonstrates the microstructure is of better bioactivity.

The Bioactivity of Gradient Composite Bioceramic Coating with Two Kinds of Rare Earth Oxide Fabricated by Wide Band Laser Cladding

2014 ◽  
Vol 989-994 ◽  
pp. 767-770
Author(s):  
Pei Ze Jiang ◽  
Qi Bin Liu ◽  
Ling Yan Zhang ◽  
Hai Bin Jiang ◽  
Zheng Zhang
Keyword(s):  
Rare Earth ◽  
Laser Cladding ◽  
Wide Band ◽  
Rare Earth Oxide ◽  
Experimental Results ◽  
Addition Amount

To improve bioactivity of gradient bioceramic coating, the coating with two kinds of rare earth oxide was produced by wide band laser cladding technique. As the experimental results, whichadded0.6wt.% La2O3 fixedly, and increased the addition amount of the CeO2, when the addition of CeO2fulfill 0.4wt.%, the amount of HA-β-TCP is the largest in this experiment. Soaking the specimens in SBF for 14 days, the coating blended 0.6wt% La2O3 and 0.4wt% CeO2, then a great quantity of Ca-P white particles can be found on coating, which confirmation this bioceramic coating is of best bioactivity.

Laser Cladding of Hard TiO xN y/Ti Composite Coating on Ti Alloy

2020 ◽  
Author(s):  
Yitian Zhao ◽  
Mingyuan Lu ◽  
Zhiqi Fan ◽  
Qiyang Tan ◽  
Han Huang
Keyword(s):  
Composite Coating ◽  
Laser Cladding ◽  
Ti Alloy

Microstructure and Biocompatibility of Gradient Bioceramic Composite Coating Fabricated by Wide-Band Laser Cladding

2007 ◽  
Vol 342-343 ◽  
pp. 685-688 ◽  
Author(s):  
Qi Bin Liu ◽  
Wen Fei Li ◽  
Bang Cheng Yang
Keyword(s):  
Bone Tissue ◽  
Chronic Inflammation ◽  
Composite Coating ◽  
Laser Cladding ◽  
Transition Layer ◽  
Wide Band ◽  
Pathological Changes ◽  
Hard Tissues ◽  
Piled Structure ◽  
Bioceramic Coatings

In this study, microstructure and biocompatibility of gradient bioceramic composite coating fabricated by Wide-Band Laser Cladding is investigated. The experimental results indicate that the coating consists of an alloyed transition layer and the bioceramic coating. The bioceramic coating is mainly comprised of HA, CaTiO3, CaO, α-TCP, β-TCP and TiO. The coral-shaped structure and short-rod piled structure existing on the surface of coating. After the implantation of the bioceramic coatings into dogs’ femur for 6, 12, and 24 weeks, hypersusceptibility, rejection and pathological changes are not found. No fiber cyst, necrosis of bone tissue and chronic inflammation obviously appear through slice observation of hard tissues. The bioceramic coating with different ratios of Ca : P have different abilities to induce osteogenesis. At Ca: P=1.4 and 0.6wt.% Y2O3 (No.3 sample), the bioceramic coating is of best bioactivity and biocompatibility.

scholarly journals Study of Cracking Mechanism and Wear Resistance in Laser Cladding Coating of Ni-based Alloy

2021 ◽  
Vol 34 (1) ◽  
Author(s):  
Zhenglei Yu ◽  
Lunxiang Li ◽  
Deqiang Zhang ◽  
Guangfeng Shi ◽  
Guang Yang ◽  
...  
Keyword(s):  
Stainless Steel ◽  
Wear Resistance ◽  
Rare Earth ◽  
Fracture Mechanics ◽  
Composite Coating ◽  
Laser Cladding ◽  
Rare Earth Oxide ◽  
Cracking Mechanism ◽  
Crack Susceptibility ◽  
The Rare Earth

AbstractNickel-based alloy coatings were widely used for the remanufacturing of dies and moulds by laser cladding, but the crack sensitivity would be increase due to the higher strength and hardness, which reduced the wear resistance of Ni-based alloys. In this paper, Ni-based coatings with the addition of a plastic phase (an austenitic stainless net) were prepared using laser cladding technology, and the CeO2 was added in cladding layers. The cracking mechanism, microhardness, microstructure, phase composition, and wear properties were investigated. The relationship between thermal stress and the elastic and plastic fracture had been developed from the standpoint of fracture mechanics and thermal elastic fracture mechanics. The fracture criterion of the nickel-based coating was obtained, and the study has shown that the crack sensitivity could be reduced by decreasing the thermal expansion coefficient Δα. Thus, a new method was proposed, which the stainless steel nets were prefabricated on the substrate. It was found that the number of cracks reduced significantly with the addition of stainless steel net. When the stainless steel net with 14 mesh was added in Ni-based coatings, the average microhardness of nickel composite coating was 565 HV0.2, which was 2.6 times higher than that of the 45 steel substrate. Although the rare earth oxide 4 wt.% CeO2 and stainless steel net were added in the Ni-based coating reducing the microhardness (the average microhardness is 425 HV0.2), the wear resistance of it improved substantially. The wear volume of Ni-based composite coating was 0.56×10−5 mm3·N−1·m−1, which was 85.1% lower than that of 45 steel. The experiment results have shown that the Nickel-based composite coating is equipped with low crack sensitivity and high abrasive resistance with austenitic stainless net and the rare earth oxide 4 wt.% CeO2. This research offers an efficient solution to produce components with low crack susceptibility and high wear-resistance coatings fabricated by laser cladding.

Effect of Different Nd2O3Contents on Performances of Rare Earth Active Bioceramic Gradient Coating Produced by Wide-Band Laser Cladding

2011 ◽  
Vol 38 (5) ◽  
pp. 0506003 ◽  
Author(s):  
汪震 Wang Zhen ◽  
刘其斌 Liu Qibin ◽  
肖明 Xiao Ming ◽  
杨邦成 Yang Bangcheng
Keyword(s):  
Rare Earth ◽  
Laser Cladding ◽  
Wide Band ◽  
Gradient Coating
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