Effects of Stabilizing Heat Treatment on Properties of Simulated Microstructures in the Heat-Affected Zone of 347H Stainless Steel

In this paper, two kinds of heat affected zone (HAZ) simulation structures of 347H stainless steel, which are coarse grain zone (CGZ) and unmixed zone (UZ), were prepared by thermal simulator. The material properties of toughness, reheat crack susceptibility and intergranular corrosion susceptibility of the two kinds of HAZ simulation structures were studied by impact test, high temperature tensile test, electrochemical potentiodynamic reactivation (EPR) test and micro morphology test. The result shows that CGHAZ had better toughness. But after the stabilizing heat treatment, it was weakened while that of the UZ was enhanced. The reheat crack susceptibility of the CGZ and UZ both increases after stabilization heat treatment, and the tendency of the UZ are more obvious. Stabilizing heat treatment has a certain effect on the prevention of sensitization process, which can improve the intergranular corrosion resistance of the material. Stabilizing heat treatment is double-edged to 347H HAZ, and it needs combined with the specific situation to used.

Comparative Study on the Thermal Performance of Cr-CrxOy and YSZ-CoNiCrAlY Coatings Exposed at 900 °C

Yttria stabilized zirconia (YSZ) thermal barrier coatings (TBCs) deposited on CoNiCrAlY oxidation protective bond coats are commonly required in temperature regimes up to 1200 °C (e.g., hot gas turbine regions) due to their superior thermal behavior and mechanical properties. For temperatures up to around 900 °C, oxidation protection can be alternatively provided by metallic-ceramic Cr-CrxOy coatings. For the present research, Cr-CrxOy atmospheric plasma sprayed (APS) and YSZ-CoNiCrAlY APS-high velocity oxy-fuel TBC coatings were deposited on a NiCr20Co18Ti substrate. The samples were isothermally heat treated at 900 °C for 10 h in an environmental atmosphere and subsequently isothermally oxidized at the same temperature for 1200 h. Investigations of the physical, chemical, and mechanical properties were performed on the as-sprayed, heat-treated, and oxidized samples. The oxidation behavior, microhardness, cohesion, and adhesion of the samples were correlated with the microstructural investigations and compared to the conventional TBC system. It could be shown that heat treating decreased the Cr-CrxOy coatings crack susceptibility and led to the formation of a protective thermally grown Cr oxide layer. The experimental work on the YSZ-CoNiCrAlY system revealed that the phase composition of the bond coat has a direct influence on the oxidation protection of the coating system.

Influence of Minor Alloying Element Additions on the Crack Susceptibility of a Nickel Based Superalloy Manufactured by LPBF

Inconel 738LC (IN738LC) is a nickel-based superalloy specially used in the hot section components of turbine engines. One of its main drawbacks relies on the cracking susceptibility when it is manufactured by laser powder bed fusion (LPBF). This paper analyzes the influence of minor alloying element concentration on cracking tendency of IN738LC superalloy manufactured by LPBF. For that objective, samples were manufactured using two powders, which presented different minor alloying elements concentration (Si, Zr and B). It was shown that the samples crack tendency was very different depending on the powder used for their manufacturing. In fact, the measured crack density value was 2.73 mm/mm2 for the samples manufactured with the powder with higher minor alloying elements concentration, while 0.25 mm/mm2 for the others. Additionally, a special emphasis has been put on elemental composition characterization in cracked grain boundaries in order to quantify possible Si or Zr enrichment. It has been also studied the differences of solidification ranges and grain structures between both samples as a consequence of different minor alloying elements concentration in order to analyze their effect on crack susceptibility. In this sense, Scheil-Gulliver simulation results have shown that samples with higher Si and Zr contents presented higher solidification range temperature. This fact, as well as an increase of the presence of high angle grain boundaries (HAGB), leaded to an increment in the crack formation during solidification. Therefore, in this research work, an understanding of the factors affecting crack phenomenon in the LPBF manufactured IN738LC was accomplished.

Study of Cracking Mechanism and Wear Resistance in Laser Cladding Coating of Ni-based Alloy

Nickel-based alloy coatings were widely used for the remanufacturing of dies and moulds by laser cladding, but the crack sensitivity would be increase due to the higher strength and hardness, which reduced the wear resistance of Ni-based alloys. In this paper, Ni-based coatings with the addition of a plastic phase (an austenitic stainless net) were prepared using laser cladding technology, and the CeO2 was added in cladding layers. The cracking mechanism, microhardness, microstructure, phase composition, and wear properties were investigated. The relationship between thermal stress and the elastic and plastic fracture had been developed from the standpoint of fracture mechanics and thermal elastic fracture mechanics. The fracture criterion of the nickel-based coating was obtained, and the study has shown that the crack sensitivity could be reduced by decreasing the thermal expansion coefficient Δα. Thus, a new method was proposed, which the stainless steel nets were prefabricated on the substrate. It was found that the number of cracks reduced significantly with the addition of stainless steel net. When the stainless steel net with 14 mesh was added in Ni-based coatings, the average microhardness of nickel composite coating was 565 HV0.2, which was 2.6 times higher than that of the 45 steel substrate. Although the rare earth oxide 4 wt.% CeO2 and stainless steel net were added in the Ni-based coating reducing the microhardness (the average microhardness is 425 HV0.2), the wear resistance of it improved substantially. The wear volume of Ni-based composite coating was 0.56×10−5 mm3·N−1·m−1, which was 85.1% lower than that of 45 steel. The experiment results have shown that the Nickel-based composite coating is equipped with low crack sensitivity and high abrasive resistance with austenitic stainless net and the rare earth oxide 4 wt.% CeO2. This research offers an efficient solution to produce components with low crack susceptibility and high wear-resistance coatings fabricated by laser cladding.

Review of Aluminum Alloy Development for Wire Arc Additive Manufacturing

Processing of aluminum alloys by wire arc additive manufacturing (WAAM) gained significant attention from industry and academia in the last decade. With the possibility to create large and relatively complex parts at low investment and operational expenses, WAAM is well-suited for implementation in a range of industries. The process nature involves fusion melting of a feedstock wire by an electric arc where metal droplets are strategically deposited in a layer-by-layer fashion to create the final shape. The inherent fusion and solidification characteristics in WAAM are governing several aspects of the final material, herein process-related defects such as porosity and cracking, microstructure, properties, and performance. Coupled to all mentioned aspects is the alloy composition, which at present is highly restricted for WAAM of aluminum but received considerable attention in later years. This review article describes common quality issues related to WAAM of aluminum, i.e., porosity, residual stresses, and cracking. Measures to combat these challenges are further outlined, with special attention to the alloy composition. The state-of-the-art of aluminum alloy selection and measures to further enhance the performance of aluminum WAAM materials are presented. Strategies for further development of new alloys are discussed, with attention on the importance of reducing crack susceptibility and grain refinement.

Systematic approach for reducing micro-crack formation in Inconel 713LC components fabricated by laser powder bed fusion

Purpose For high crack-susceptibility materials such as Inconel 713LC (IN713LC) nickel alloy, fabricating crack-free components using the laser powder bed fusion (LPBF) technique represents a significant challenge because of the complex interactions between the effects of the main processing parameters, namely, the laser power and scanning speed. Accordingly, this study aims to build up a methodology which combines simulation model and experimental approach to fabricate high-density (>99.9%) IN713LC components using LPBF process. Design/methodology/approach The present study commences by performing three-dimensional (3D) heat transfer finite element simulations to predict the LPBF outcome (e.g. melt pool depth, temperature and mushy zone extent) for 33 representative sample points chosen within the laser power and scanning speed design space. The simulation results are used to train a surrogate model to predict the LPBF result for any combination of the processing conditions within the design space. Then, experimental trials were performed to choose the proper hatching space and also to define the high crack susceptibility criterion. The process map is then filtered in accordance with five quality criteria, namely, avoiding the keyhole phenomenon, improving the adhesion between the melt pool and the substrate, ensuring single-scan-track stability, avoiding excessive melt pool evaporation and suppressing the formation of micro-cracks, to determine the region of the process map which improves the relative density of the IN713LC component and minimizes the micro-cracks. The optimal processing conditions are used to fabricate IN713LC specimens for tensile testing purposes. Findings The optimal processing conditions predicted by simulation model are used to fabricate IN713LC specimens for tensile testing purposes. Experimental results show that the tensile strength and elongation of 3D-printed IN713LC tensile bar is higher than those of tensile bar made by casting. The yield strength of 791 MPa, ultimate strength of 995 MPa, elongation of 12%, and relative density of 99.94% are achieved. Originality/value The present study proposed a systematic methodology to find the processing conditions that are able to minimize the formation of micro-crack and improve the density of the high crack susceptivity metal material in LPBF process.

Study of Cracking Susceptibility in Similar and Dissimilar Welds Between Carbon Steel and Austenitic Stainless Steel Through Finger Test and FE Numerical Model

Hot cracking susceptibility and the formation of brittle martensite phase are the main factors that limit the weldability of a dissimilar joint between carbon steel (CS) and austenitic stainless steel (SS). In this study, the self-constraint finger test was used to correlate the welding thermo-mechanical field with the crack susceptibility of a dissimilar weld between the CS ASTM A36 and SS AISI 304L. The finger test allowed to intercalate fingers (portions) of tested materials in the weld samples to produce dissimilar welds. The heat dissipation and the distortion behavior were related to the crack susceptibility, critical weld regions extension and chemical species diffusion. Four samples were welded (two similar welds and two dissimilar welds) using the filler metals ER70S-6 and EC410NiMo. Welds were analyzed through light optical microscopy (LOM) and scanning electron microscopy (SEM) to characterize phases, detect cracks, microstructural changes and element diffusion. A finite element (FE) numerical model was applied to simulate the welding thermo-mechanical field. Additionally, electrochemical tests were carried out to assess the corrosion susceptibility of the dissimilar welds. The observed cracks were produced due to different factors such as residual stress distribution, the formation of brittle and untempered martensitic phase in the fusion zone (FZ) and hot cracking associated with the weld sample distortion behavior. The dilution contributed to the formation of d-ferrite in the FZ, which limited the growth of cold and hot cracks. The decarburization and sensitization were not observed in dissimilar welds due to the low element diffusion.

Research for the Optimal Flux-Cored Arc Welding Process of 9% Nickel Steel Using Multi Object Optimization with Solidification Crack Susceptibility

The environment of the global shipbuilding market is changing rapidly. Recently, the International Maritime Organization (IMO) has tightened regulations on sulfur oxide content standards for marine fuels and tightened sulfur oxide emission standards for the entire coastal region of China to consider the environment globally and use LNG as a fuel. There is a tendency for the number of vessels to operate to increase significantly. To use cryogenic LNG fuel, various pieces of equipment, such as storage tanks or valves, are required, and equipment using steel, which has excellent impact toughness in cryogenic environments, is required. Four steel types are specified in the IGG Code, and 9% Ni steel is mostly used for LNG fuel equipment. However, to secure safety at cryogenic temperatures, a systematic study investigating the causes of quality deterioration occurring in the 9% Ni steel welding process is required and a discrimination function capable of quality evaluation is urgent. Therefore, this study proposes a plan where the uniform quality of 9% Nickel steel is secured by reviewing the tendency of the solidification crack susceptibility among the quality problems of cryogenic steel to establish the criteria for quality deterioration and to develop a system capable of quality discrimination and defect avoidance.