Sintering Behavior of Fe-Si Composite Powder by DPR Technique

2007 ◽  
Vol 336-338 ◽  
pp. 2344-2346 ◽  
Author(s):  
Qiang Shen ◽  
Y. Zhou ◽  
Jun Guo Li ◽  
W.J. Yuan ◽  
Lian Meng Zhang
Keyword(s):  
Phase Composition ◽  
Reaction Mechanism ◽  
Composite Powder ◽  
Sintering Behavior ◽  
Composite Powders ◽  
Silicon Iron ◽  
Graded Structure ◽  
Composition And Structure ◽  
High Silicon ◽  
Si Content

The reaction mechanism of silicon and iron composite powders was clarified during the fabrication of high silicon iron sheet with the Si-content of 6.5wt% by Direct Powder Rolling (DPR) technique. The changes of phase composition and structure evolvement were mainly studied. It is found that a local graded structure, Fe-Fe(Si)-Fe3Si(Si)-Si, forms when sintering at 950-1000oC, which plays an important role in the DPR process. Fe3Si(Si) phase keeps higher content of Si, and Fe(Si) phase remains the state with much lower Si-content, thus provides good mechanical proprieties of rolling and cutting. Then, the subsequent sintering at about 1200oC improves the density and makes the distribution of Si homogeneous in the final high silicon iron sheets.

Local Graded Structure in 6.5wt%Si-Fe Alloy and the Effect on Ductility

2005 ◽  
Vol 492-493 ◽  
pp. 59-62 ◽  
Author(s):  
Qiang Shen ◽  
Ran Li ◽  
Lian Meng Zhang
Keyword(s):  
Phase Composition ◽  
Powder Metallurgy ◽  
Deformation Behavior ◽  
Powder Metallurgy Method ◽  
Silicon Phase ◽  
Silicon Iron ◽  
Graded Structure ◽  
Composition And Structure ◽  
High Silicon ◽  
Si Content

The changes of phase composition and structure evolvement of Fe and Si powders with the ratio of 6.5wt%Si to 93.5wt%Fe were mainly studied. It is found that, the local graded structure, Fe-Fe(Si)-Fe3Si-(FeSi)-Si, forms due to the obvious diffusion and the alloying reaction between Fe and Si powders when sintering at 900-975oC. The graded structure, in which the high silicon phase based on Fe-Si alloys is packed by the low silicon solution based on Fe, exhibits a graded concentration of Si distribution. And most of the Fe-containing phase remains a state of lower Si content, less than that of 3wt%Si-Fe alloy, thus provides the good deformation behavior of rolling and cutting for the compacts. Therefore, it is feasible for the high silicon iron sheets to be produced by the powder metallurgy method.

Powder reaction mechanism in fabrication of high silicon iron alloy

2007 ◽  
Vol 50 (4) ◽  
pp. 336-340
Author(s):  
Q. Shen ◽  
R. Li ◽  
W. J. Yuan ◽  
L. M. Zhang ◽  
T. Zhang
Keyword(s):  
Reaction Mechanism ◽  
Iron Alloy ◽  
Silicon Iron ◽  
High Silicon

Phase composition and structure of composite powders based on solid solutions of SiC and AlN

1997 ◽  
Vol 36 (7-8) ◽  
pp. 425-429 ◽  
Author(s):  
A. V. Kurdyumov ◽  
V. F. Britun ◽  
V. B. Zelyavskii ◽  
S. N. Gromyko ◽  
T. S. Bartnitskaya ◽  
...  
Keyword(s):  
Phase Composition ◽  
Solid Solutions ◽  
Composite Powders ◽  
Composition And Structure

Synthesis of Al2O3/AlN composite powders by plasma processed Al2O3with various additives

2004 ◽  
Vol 19 (5) ◽  
pp. 1356-1363 ◽  
Author(s):  
F.Y.C. Boey ◽  
X.L. Zhao ◽  
A.I.Y. Tok
Keyword(s):  
Reaction Mechanism ◽  
Composite Powder ◽  
X Ray Diffraction ◽  
Minor Phase ◽  
Composite Powders ◽  
Major Phase ◽  
X Ray ◽  
Different Types ◽  
Novel Method ◽  
Direct Nitridation

A novel method was developed to produce Al2O3/AlN composite powders. The composite powders were synthesized by the direct nitridation of Al2O3using various additives by plasma processed with two different types of gas (Ar/N2and N2plasma). The effects of these two different plasma gases and additives on the formation of the Al2O3/AlN composites were studied. The x-ray diffraction results in the composite powders showed that the cubic AlN was converted to the major phase while transient γ–Al2O3was the minor phase when the composite powder was fully melted using nitrogen as the sole working gas. In contrast, the main phase was still α–Al2O3when the composite powder was not well melted using the mixture of argon and nitrogen as the working gas. Carbon was found as an effective conversion additive to increase the cubic AlN of this composite powder up to 49 vol%. The reaction mechanism of forming this composite powder was also analyzed.

EFFECT OF ADDITION OF THIRD ELEMENT IN HIGH SILICON-IRON ALLOY

1988 ◽  
Vol 49 (C8) ◽  
pp. C8-133-C8-134
Author(s):  
H. Nakamura ◽  
N. Tsuya ◽  
Y. Saito ◽  
Y. Katsumata ◽  
Y. Harada
Keyword(s):  
Iron Alloy ◽  
Silicon Iron ◽  
High Silicon

DURICHLOR 51M

Alloy Digest ◽  
1996 ◽  
Vol 45 (4) ◽  
Keyword(s):  
Compressive Strength ◽  
Corrosion Resistance ◽  
Hydrochloric Acid ◽  
Physical Properties ◽  
Tensile Properties ◽  
Silicon Iron ◽  
Chlorine Gas ◽  
High Silicon

Abstract Durichlor 51M is a high silicon iron for corrosive services, especially in the handling of hydrochloric acid in all concentrations. It is also very resistant to most chlorine gas and many destructive chloride-containing solutions. The alloy is treated at melting by argon ladle degassing. This datasheet provides information on composition, physical properties, hardness, tensile properties, and compressive strength. It also includes information on corrosion resistance as well as machining and joining. Filing Code: FE-109. Producer or source: The Duriron Company Inc.

DURICHLOR 51 SUPERCHLOR

Alloy Digest ◽  
1993 ◽  
Vol 42 (1) ◽  
Keyword(s):  
Compressive Strength ◽  
Corrosion Resistance ◽  
Hydrochloric Acid ◽  
Physical Properties ◽  
Tensile Properties ◽  
Silicon Iron ◽  
Chlorine Gas ◽  
High Silicon

Abstract DURICHLOR 51 SUPERCHLOR is a vacuum treated high silicon iron for corrosive services, especially in the handling of hydrochloric acid in all concentrations. It is also very resistant to most chlorine gas and many destructive chloride-containing solutions. This datasheet provides information on composition, physical properties, hardness, tensile properties, and compressive strength. It also includes information on corrosion resistance as well as machining and joining. Filing Code: FE-98. Producer or source: The Duriron Company Inc.

Hydrogen Generation by Hydrolysis of the Ball Milled Al-C-KCl Composite Powder in Distilled Water

2012 ◽  
Vol 519 ◽  
pp. 87-91 ◽  
Author(s):  
Xia Ni Huang ◽  
Zhang Han Wu ◽  
Ke Cao ◽  
Wen Zeng ◽  
Chun Ju Lv ◽  
...  
Keyword(s):  
Particle Size ◽  
Reaction Temperature ◽  
Fine Particle ◽  
Composite Powder ◽  
Hydrogen Generation ◽  
Aluminum Particle ◽  
Generation Rate ◽  
Composite Powders ◽  
Fine Particle Size ◽  
Hydrolysis Of

In the present investigation, the Al-C-KCl composite powders were prepared by a ball milling processing in an attempt to improve the hydrogen evolution capacity of aluminum in water. The results showed that the hydrogen generation reaction is affected by KCl amount, preparation processing, initial aluminum particle size and reaction temperature. Increasing KCl amount led to an increased hydrogen generation volume. The use of aluminum powder with a fine particle size could promote the aluminum hydrolysis reaction and get an increased hydrogen generation rate. The reaction temperature played an important role in hydrogen generation rate and the maximum hydrogen generation rate of 44.8 cm3 min-1g-1of Al was obtained at 75oC. The XRD results identified that the hydrolysis byproducts are bayerite (Al(OH)3) and boehmite (AlOOH).

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