Low Temperature Sinter-Ability of Microwave Dielectric Ceramics 0.4(Ca0.61Nd0.26)TiO3-0.6(Li0.5Sm0.5)TiO3

2008 ◽  
Vol 368-372 ◽  
pp. 176-178
Author(s):  
Xiao Dong Guo ◽  
Zi Long Tang ◽  
Zhong Tai Zhang

Microwave dielectric ceramics 0.4(Ca0.61Nd0.26)TiO3-0.6(Li0.5Sm0.5)TiO3 (CNLST) were prepared by doping CuO as the liquid-phase sintering aid. The effects of CuO on the microstructures and dielectric properties were investigated. Due to the liquid-phase effect, the sintering temperature of CNLST with 0.5wt.% CuO addition has be effectively reduced to 1100°C, while good microwave dielectric properties of εr=83.4, Q•f=3880GHz, τf =2.1ppm/°C.

2014 ◽  
Vol 664 ◽  
pp. 14-17
Author(s):  
Chun Hsu Shen ◽  
Chung Long Pan ◽  
Shin Hung Lin ◽  
Wei Cheng Lin ◽  
Sheng Kai Huang

The effects of 3Z2B addition on the microwave dielectric properties and the microstructures of (1-x)(Mg0.95Co0.05)TiO3-xCa0.6La0.8/3TiO3ceramics prepared with conventional solid-state route have been investigated. Doping with 3Z2B can effectively promote the densification and the microwave dielectric properties of (1-x)(Mg0.95Co0.05)TiO3-xCa0.6La0.8/3TiO3ceramics. It was found that (1-x)(Mg0.95Co0.05)TiO3-xCa0.6La0.8/3TiO3ceramics can be sintered at 1150°C due to the liquid phase effect of 3Z2B additions observed by SEM. TheQ×fvalue of (1-x)(Mg0.95Co0.05)TiO3-xCa0.6La0.8/3TiO3ceramics decreased with increasing 3Z2B content. At 1150°C, 0.9(Mg0.95Co0.05)TiO3-0.1Ca0.6La0.8/3TiO3ceramics with 1.0wt% 3Z2B addition possesses a εrvalue of 22.6, a Qfvalue of 49,000 (GHz) and a τfvalue of-10.7 ppm/°C.


2014 ◽  
Vol 933 ◽  
pp. 12-16 ◽  
Author(s):  
Chung Long Pan ◽  
Ping Cheng Chen ◽  
Tsu Chung Tan ◽  
Wei Cheng Lin ◽  
Chun Hsu Shen ◽  
...  

The effect of V2O5addition on the microstructures and the microwave dielectric properties of 0.9CaWO4-0.1Mg2SiO4(9CWMS) ceramics prepared by conventional solid-state routes have been investigated. The V2O5were selected as liquid phase sintering aids to lower the sintering temperature of 9CWMS ceramics. A small amount of V2O5(0.25~1 wt%) were used for sintering aid and led to high densification at 1050°C. The dielectric properties of 9CWMS ceramics with V2O5additions are strongly dependent on the densification, the microstructure. As the amount of V2O5additives increased from 0.25 to 1.0 wt%, the dielectric constantsεrdecreased following the trend with density. The quality valuesQdecreased with the increase of V2O5amount for all sintering temperatures. The 0.25 wt% V2O5-doped 0.9CaWO4-0.1Mg2SiO4ceramicssintered at 1080°C for 2 h had the optimum dielectric properties: εr= 5.7;Q×f= 73000 (at 14 GHz).


Materials ◽  
2019 ◽  
Vol 12 (24) ◽  
pp. 4187 ◽  
Author(s):  
Min-Hang Weng ◽  
Chihng-Tsung Liauh ◽  
Shueei-Muh Lin ◽  
Hung-Hsiang Wang ◽  
Ru-Yuan Yang

The effect of CuO/B2O3 additions on the sintering behaviors, microstructures, and microwave dielectric properties of 0.95LaAlO3–0.05CaTiO3 ceramics is investigated. It is found that the sintering temperatures are lowered efficiently from 1600 °C to 1350 °C, as 1 wt % CuO, 1 wt % B2O3, and 0.5 wt % CuO +0.5 wt % B2O3 are used as the sintering aids due to the appearance of the liquid phase sintering. The microwave dielectric properties of 0.95LaAlO3–0.05CaTiO3 ceramics with the sintering aid additions are strongly related to the densification and the microstructure of the sintered ceramics. At the sintering temperature of 1300 °C, the 0.95LaAlO3–0.05CaTiO3 ceramic with 0.5 wt % CuO + 0.5 wt % B2O3 addition shows the best dielectric properties, including a dielectric constant (εr) of 21, approximate quality factor (Q × f) of 22,500 GHz, and a temperature coefficient of the resonant frequency (τf) of −3 ppm/°C.


2008 ◽  
Vol 368-372 ◽  
pp. 173-175 ◽  
Author(s):  
Wei Liang Liu ◽  
Chun Bao Tang ◽  
Jun Tan ◽  
Du Song Mao ◽  
Jin Gang Tan

BaCu(B2O5) (BCB) powder was prepared using BaO,CuO and B2O3 as the main materials. Microwave dielectric ceramics of tungsten–bronze-type BaSm2Ti4O12 (BST) were prepared by doping BCB as the sintering aid. The amount of BCB was varied from 1.0 to 10.0wt.%. The microstructure and dielectric properties of BST were investigated. The sintering temperature of BST ceramics with 6.0wt.% BCB addition can be effectively reduced to 900 oC, about 450 oC lower than that of pure BST ceramics. Good microwave dielectric properties of εr = 62.38, Q×f = 4573 GHz and τf = -27.65 ppm/ oC were achieved.


2011 ◽  
Vol 284-286 ◽  
pp. 1442-1446
Author(s):  
Yue Ming Li ◽  
Zong Yang Shen ◽  
Zhu Mei Wang ◽  
Hua Zhang ◽  
Yan Hong ◽  
...  

The B2O3-CuO oxide mixture (abbreviated as BC) was selected to lower the sintering temperature of (Ca0.9375Sr0.0625)0.25(Li0.5Sm0.5)0.75TiO3 (abbreviated as CSLST) microwave dielectric ceramics by solid sate reaction technique. The effects of BC doping amounts on the crystal structure, microstructure and microwave dielectric properties of the ceramics were investigated. For the ceramic sample with the composition of CSLST + 5 wt% BC, its sintering temperature was reduced to 1000 °C as compared to 1200 °C for pure CSLST. In addition to the obtained good microwave dielectric properties as follows: εr = 80.4, Q×f = 1380 GHz, τf = -32.89 ×10-6/°C, this ceramic was a desirable high-permittivity microwave dielectric candidate for low-temperature cofired ceramic (LTCC) applications.


2010 ◽  
Vol 663-665 ◽  
pp. 1028-1031
Author(s):  
Yue Ming Li ◽  
Hua Zhang ◽  
Zhu Mei Wang ◽  
Yan Hong ◽  
Zong Yang Shen

The sintering behavior and microwave dielectric properties of the (Ca0.9375Sr0.0625)0.25(Li0.5Sm0.5)0.75TiO3 (CSLST) ceramics doped with different amounts of Li2O-B2O3-SiO2-CaO-Al2O3 (LBSCA) glass were investigated. The sintering temperature of the CSLST ceramics can be effectively reduced over 200oC due to the addition of LBSCA glass. For the 5 wt% LBSCA-doped CSLST ceramics, which are sintered at only 1000 oC for 5 h, show optimum microwave dielectric properties as follows: εr=84.74, Qf=2446 GHz and τf=-12.48 ppm/oC.


2018 ◽  
Vol 2018 ◽  
pp. 1-5
Author(s):  
Chengxi Hu ◽  
Yuan Liu ◽  
Wujun Wang ◽  
Bo Yang

The effects of B2O3–LiF addition on the phase composition, microstructures, and microwave dielectric properties of (Mg0.95Cu0.05)2SiO4 ceramics fabricated by a wet chemical method were studied in detail. The B2O3–LiF was selected as liquid-phase sintering aids to reduce the densification sintering temperature of (Mg0.95Cu0.05)2SiO4 ceramics. The B2O3 6%–Li2O 6%-modified (Mg0.95Cu0.05)2SiO4 ceramics sintered at 1200°C possess good performance of εr ∼ 4.37, Q×f ∼ 36,700 GHz and τf ∼ −42 ppm/°C.


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