Effect of Nd2O3 on the Microwave Dielectric Properties of 0.67CaTiO3-0.33LaAlO3 Ceramics

2017 ◽  
Vol 726 ◽  
pp. 215-219 ◽  
Author(s):  
Zhan Ming Dou ◽  
Gan Wang ◽  
Juan Jiang ◽  
Tian Jin Zhang

0.67CaTiO3-0.33LaAlO3 ceramics doped with Nd2O3 were prepared using a conventional two-step solid-state reaction, and the effect of Nd2O3 doping on the microwave dielectric properties were studied. A single phase of perovskite structure was confirmed with the Nd2O3 doping. The results showed that the addition of Nd2O3 obviously improved the density and Q×f values of CTLA ceramics. The dielectric constant were almost not affected and the τf values were close to zero with the increase of the doping amount. CTLA ceramics with 0.2 wt% Nd2O3 doping sintered at 1380 °C for 4 h exhibited the optimal microwave dielectric properties of εr = 45.36, Q×f = 37,890 GHz, τf = 7.80 ppm/°C.

2011 ◽  
Vol 687 ◽  
pp. 199-203 ◽  
Author(s):  
Ching Fang Tseng

The microwave dielectric properties of the Mg(Zr0.05Ti0.95)O3ceramics with CuO addition were investigated. All specimens were prepared by solid-state reaction method and sintered at 1270-1420°C for 4 h. When CuO was added, the second phases of MgTi2O5, TiO2and liquid phase were produced. For specimens with 1.5 wt% CuO sintered at 1300°C, the dielectric constant,Q´fand tfvalues are 18.2, 223000 GHz and -2 ppm/°C, respectively.


1999 ◽  
Vol 14 (9) ◽  
pp. 3567-3570 ◽  
Author(s):  
Ji-Won Choi ◽  
Chong-Yun Kang ◽  
Seok-Jin Yoon ◽  
Hyun-Jai Kim ◽  
Hyung-Jin Jung ◽  
...  

The microwave dielectric properties of Ca[(Li1/3Nb2/3)1−xMx]O3−δ (M = Sn, Ti, 0 ≤ x ≤ 0.5) ceramics were investigated. In general, the ceramics prepared were multiphase materials. However, single-phase specimens having orthorhombic perovskite structure similar to CaTiO3 could be obtained in the vicinity of Sn = 0.2 to 0.3, and Ti = 0.2. As Sn concentration increased, the dielectric constant (εr) decreased and the quality factor (Q) significantly increased within the limited Sn concentration. As Ti concentration increased, the dielectric constant (εr) increased, the quality factor (Q) decreased, and the temperature coefficient of resonant frequency (τf) changed from a negative to positive value. The temperature coefficient of resonant frequency of 0 ppm/°C was realized at Ti = 0.2. The Q · fo value and εr for this composition were found to be 26100 GHz and 38.6, respectively.


2007 ◽  
Vol 336-338 ◽  
pp. 287-289
Author(s):  
Wei Wang ◽  
Zi Long Tang ◽  
Zhong Tai Zhang

(1-x)(Ca0.61Nd0.26)TiO3-x(Li0.5Sm0.5)TiO3 (0.2 ≤ x ≤ 0.7) ceramics were prepared by solid-state reaction method and the microwave dielectric properties of the resultant materials at different (Li0.5Sm0.5)TiO3 contents were investigated. A single phase of perovskite in all samples was confirmed by XRD patterns. With increasing (Li0.5Sm0.5)TiO3 content, Q×f value and dielectric constant (εr) decrease slightly and the temperature coefficients of the resonant frequency (τf) of the specimens decreases noticeably. The optimum parameters, i.e.,εr = 109, Q×f = 5259 GHz and τf = ~0 ppm/°C, for the composition of 0.4(Ca0.61Nd0.26)TiO3-0.6(Li0.5Sm0.5)TiO3 was obtained when keep the calcination temperature at 1250°C for 3 h.


2015 ◽  
Vol 41 (2) ◽  
pp. 1937-1942 ◽  
Author(s):  
Brahim Itaalit ◽  
Mohamed Mouyane ◽  
Jérôme Bernard ◽  
Jean-Michel Reboul ◽  
David Houivet

2007 ◽  
Vol 336-338 ◽  
pp. 196-198
Author(s):  
Dong Xiang Zhou ◽  
G. Xiong ◽  
Shu Ping Gong ◽  
Jun Zhao ◽  
M.Z. Hu ◽  
...  

The microwave properties of (Ca1-xBax)[(Li1/3Nb2/3)0.95Zr0.15]O3+δ(0.0≤x≤0.2, CBLNZ) ceramics were investigated. A single phase with orthorhombic perovskite structure was obtained at x = 0.0 − 0.025. Both the εr and Qf value firstly increased with increasing Ba2+ content, and then began to decrease at x = 0.025. The τf value increased from −9.4 ppm/°C at x=0.0 to 18ppm/°C at x=0.2, which could be explained by the decrease of B-site bond valence in perovskite structure.


2011 ◽  
Vol 181-182 ◽  
pp. 439-442
Author(s):  
Gang Xiong

Crystal structure and microwave dielectric properties of (Ca1-xPrx) [(Li1/3Nb2/3)0.95Zr0.15]3+δ (0.0≤x≤0.2, CPLNZ) ceramics were investigated. A single phase with orthorhombic perovskite structure was obtained at x=0.0~0.08. With an increase of Pr3+ content, the quality factor value firstly increased, and then began to decrease at x=0.06 due to a decrease of the degree of B-site 1:2 ordering. The variation of τf with tolerance factor was discussed. When x=0.06, the optimum microwave dielectric properties: the permittivity is 33.2, the quality factor is 17120 GHz,and the temperature coefficient of resonator frequency is −5.7×10−6/°C.


2010 ◽  
Vol 663-665 ◽  
pp. 698-701
Author(s):  
Gang Xiong

Crystal structure and microwave dielectric properties of (Ca1-xSmx) [(Li1/3Nb2/3)0.95Zr0.15]3+δ(0.0≤x≤0.2,CSLNZ) ceramics were investigated. A single phase with orthorhombic perovskite structure was obtained at x=0.0~0.08. With an increase of Sm3+ content, the quality factor value firstly increased, and then began to decrease at x=0.03 due to a decrease of the degree of B-site 1:2 ordering. The variation of τf with tolerance factor was discussed. When x=0.05, the optimum microwave dielectric properties: the permittivity is 32.4,the quality factor is 16560GHz,and the temperature coefficient of resonator frequency is −6.3×10−6/°C。


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