Shrinkage Behavior of Alkali-Activated Slag Cement Pastes

2018 ◽  
Vol 761 ◽  
pp. 45-48 ◽  
Author(s):  
Vladyslav Omelchuk ◽  
Guang Ye ◽  
Rayisa Runova ◽  
Igor I. Rudenko

Nowadays, alkali-activated cements (AACs) are the most promising alternatives to ordinary portland cement (OPC). Such cements characterized by better strength and corrosion resistance that determine improved durability of materials based on them. However, the shrinkage of AAC systems is noticeably higher compared with OPC. The purpose of this work was to study the shrinkage behavior of alkali-activated slag cement (AASC) pastes. To improve early age performance of AASCs – OPC and Ca(OH)2, as mineral additives, were added to the designed cement mixtures. The properties, like, flexural and compressive strength of cement mortars, chemical shrinkage, autogenous shrinkage and drying shrinkage of cement pastes were studied. The results showed that the chemical shrinkage, autogenous shrinkage and drying shrinkage at 28 days were between 0.064 – 0.074 ml/g, 4.5 – 7.9 mm/m and 3.3 – 4.9 mm/m, respectively. The relationship between the nature of alkaline components, the type of mineral additives and the shrinkage behavior of cements were discussed.

Materials ◽  
2020 ◽  
Vol 13 (16) ◽  
pp. 3499
Author(s):  
Bin Chen ◽  
Jun Wang ◽  
Jinyou Zhao

The shrinkage of alkali-activated slag (AAS) is obviously higher than ordinary Portland cement, which limited its application in engineering. In this study, the effects of NaAlO2 in mitigating drying shrinkage and autogenous shrinkage of AAS were studied. To further understand the shrinkage mechanism, the hydration products and microstructures were studied by X-ray diffraction, scanning electron microscopy and nitrogen adsorption approaches. As the partial substitution rate of NaAlO2 for Na2SiO3 increased, the drying shrinkage and autogenous shrinkage reduced significantly. The addition of NaAlO2 could slow down the rate of hydration reaction and reduce the porosity, change the pore diameter and the composition of generated paste and cause more hydrotalcite and tetranatrolite generated—which contributed to reduced shrinkage. Additionally, raising the Na2O content rate caused obvious differences in drying shrinkage and autogenous shrinkage. As the Na2O content elevated, the drying shrinkage decreased and autogenous shrinkage increased. A high Na2O content would cause complete hydration reactions and provoke high autogenous shrinkage. However, incomplete hydration reactions left more water in the paste, and the evaporated water dramatically influenced drying shrinkage. The results indicate that addition of NaAlO2 could greatly mitigate the drying shrinkage and autogenous shrinkage of AAS.


2010 ◽  
Vol 168-170 ◽  
pp. 2008-2012 ◽  
Author(s):  
Yong Hao Fang ◽  
Ya Min Gu ◽  
Qiu Boa Kang

The chemical shrinkages of alkali-activated slag cement (AASC), and the effect of fly ash, MgO burnt at 900°C and the curing solutions were studied. The shrinkages were compared with that of ordinary portland cement (OPC). The results show that the chemical shrinkage of AASC is lower than that of OPC. Adding fly ash and light-burnt MgO reduced the early age chemical shrinkage, while the shrinkage-reduction effect decreased with the age. The alkality of the curing solution has significant effect on the hydration and shrinkage of AASC. The chemical shrinkage of AASC increased with the alkali concentration of the curing solution. The mechanisms of fly ash, MgO and curing solution on the shrinkage were discussed.


Materials ◽  
2021 ◽  
Vol 14 (22) ◽  
pp. 6962
Author(s):  
Bo Fu ◽  
Zhenyun Cheng ◽  
Jingyun Han ◽  
Ning Li

This research investigates the mechanism of metakaolin for mitigating the autogenous and drying shrinkages of alkali-activated slag with regard to the activator parameters, including concentration and modulus. The results indicate that the incorporation of metakaolin can decrease the initial viscosity and setting time. Increasing activator concentration can promote the reaction process and shorten the setting time. An increase in the metakaolin content induces a decrease in compressive strength due to reduced formation of reaction products. However, increasing activator dosage and modulus can improve the compressive strength of alkali-activated slag containing 30% metakaolin. The inclusion of metakaolin can mitigate the autogenous and drying shrinkage of alkali-activated slag by coarsening the pore structure. On the other hand, increases in activator concentration and modulus result in an increase in magnitude of the autogenous and drying shrinkage of alkali-activated slag containing metakaolin. The influence of the activator modulus on the shrinkage behavior of alkali-activated slag-metakaolin binary system should be further investigated.


2014 ◽  
Vol 11 ◽  
pp. 01002
Author(s):  
F. Puertas ◽  
M. Palacios ◽  
H. Manzano ◽  
J.S. Dolado ◽  
A. Rico ◽  
...  

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