A review of Brazilian agro-industrial pig farming systems: environmental impacts and applied anaerobic digestion processes with mineral additives

The agro-industrial systems comprise activities which transform raw materials of agricultural, aquacultural, livestock and forestry industries from primary production stages to consumption. Pig farming stands out in national and international markets for agro-industrial processes such as slaughtering and meat processing. Although this sector positively contributes to the economies of several countries, the high flow of waste resulting from implementing integrated production systems has led to serious environmental consequences (e.g., polluted water bodies and Greenhouse Gases - GHGs emissions). Among the treatment methods, anaerobic digestion reduces the organic load of biomass in the absence of oxygen, generating biogas and organic fertilizer. However, there are limitations associated with high CH4 variability and low yield, resulting a minimal and slow implementation in Brazil. Some research has reported the use of mineral additives to optimize the digestion process. This study comprises a bibliographic review of pig farming systems and production models, followed by an analysis on a global scale and environmental consequences. It is also discussed the use of additive minerals which have been applied in anaerobic digestion of swine manure as well as some prospects for global advances with opportunities to mitigate GHGs and bottlenecks. Despite being a promising technology, detailed evaluations of the use of these additives and their implementation in treatment plants must still be carried out in such a way to understand the optimization of such process.

Effect of modifiers and mineral additives from industrial waste on the quality of aerated concrete products

The given article is devoted to research of influence of polymer modifiers and mineral additives on quality of composite aerated concrete products. When selecting the composition of composite aerated concrete local raw materials and components were used: portland cement, sand, aluminum powder, polyvinyl acetate, fly ash, post-alcoholic bard and whey of milk. Preliminary polyvinyl acetate was combined with binder mixing water at a temperature above 55ºC to obtain a readily soluble polymer emulsion. Dispersion was carried out with a rotary-pulsation apparatus at a pressure of 0.5-1.0 MPa and a rotor speed of ~1200 rpm. In the same apparatus the complex modifier was produced. The offered technology of production of a complex modifier seems to be the most effective for composite aerated concrete. It made it possible to reduce water absorption and capillary suction of composite aerated concrete by an average of 25% and 45%, respectively. Moreover, different combinations of fly ash, polymer and modifier made it possible to achieve optimal values of thermal conductivity, compressive strength and frost resistance of composite aerated concrete.

Ultrafast transfer strength of reinforced concrete sleepers by Using complex additives

The influence of superplasticizers-polycarboxylates and their complex additives withaccelerants - electrolytes and dispersion of calcium hydroxylates on the early strength of concretefor concrete of concrete sleepers has been studied. It was found that the use of superplasticizerspolycarboxylates can improve the early strength of the concrete after heat treatment, but eachadditive must be checked for consistency with the cement used. Approx Complex additives withaccelerators in conditions of natural hardening ensure an increase in the early strength of concrete,but some of them, which accelerate natural hardening, can reduce the strength after WWTP and mustbe checked before use. Electron-microscopic examinations of the structure of cement stone withadditives were carried out and it was found that the additive of only policarboxylate does not changethe structure of hydration products. Complex additives lead to formation of additional number ofcrystalline hydrates of AFm- and/or AFt-phases. The scheme of development of the cement hardeningprocess and the initial stage of cement hardening without or with additives has been developed. Bymeans of which the highest accelerating effect of the complex addition of polycarboxylate andcalcium hydroxylate dispersions was established by experimental investigations, Dispersion particlesincrease surface area where crystallization (condensation) of cement hydration products takes placeand ensures faster filling of spaces between cement particles (mineral additives) with them, fillers)with establishment of lances with electro-heterogeneous contacts. As a result of potentiodynamic andmicroscopic investigations it was established that the tested additives in the dosages do not causecorrosion effect on the steel reinforcement bars. Transmission strength values of 32 MPa for sleepersafter 24 years of hardening under low-heat regime and after 2 days of natural hardening have beenachieved. The formula for economic efficiency of using additives to reduce the energy intensity ofproduction of concrete sleepers has been proposed.

Rheological characteristics of the binder for foam concrete with a complex of mineral modifiers

The paper considers the effect of mineral additives on the rheological characteristics of a binder for foam concrete. The compositions in the study were divided into two groups: based on nanostructured binder (NB) and based on cement. For the compositions of the first group portland cement is proposed as a modifying additive,for the compositions of the second group NB and anhydrite were used as modifying additives. It has been shown that the introduction of cement into NB increases the viscosity due to an increase in the concentration of large-sized particles, while the combined use of nanostructured binder and anhydrite as modifiers of the cement system helps to reduce the viscosity of the cement mortar and increase its mobility, which reduces the amount of mixing water. From a technological point of view, this will make it possible to obtain materials with a rational pore structure by optimizing porosity processes.

The Influence of Cement Type on the Properties of Plastering Mortars Modified with Cellulose Ether Admixture

In this article, the effect of cement type on selected properties of plastering mortars containing a cellulose ether admixture was studied. In the research, commercial CEM I Portland cement, CEM II and CEM III, differing in the type and amount of mineral additives, and cement class, were used as binders. Tests of consistency, bulk density, water retention value (WRV), mechanical properties and calorimetric tests were performed. It was proved that the type of cement had no effect on water retention, which is regulated by the cellulose ether. All mortars modified with the admixture were characterized by WRV of about 99%. High water retention is closely related to the action of the cellulose ether admixture. As a result of the research, the possibility of using cement with additives as components of plasters was confirmed. However, attention should be paid to the consistency, mechanical properties of the tested mortars and changes in the pastes during the hydration process. Different effects of additives resulted from increasing or decreasing the consistency of mortars; the flow was in the range from 155 mm to 169 mm. Considering the compressive strength, all plasters can be classified as category III or IV, because the mortars attained the strength required by the standard, of at least 3.5 MPa. The processes of hydration of pastes were carried out with different intensity. In conclusion, the obtained results indicate the possibility of using CEM II and CEM III cements to produce plastering mortars, without changing the effect of water retention.

Research of the mineral additives influence on aggregative stability of foam concrete mixture

An effective method for increasing the aggregate stability of non-autoclave heat-insulating foam concrete is proposed. This material is prepared using a two-stage technology on a turbulent-type installation. An increase in the stability of the foam in the mortar mixture by 9.5-23% has been established. An increase in the viscosity of the foam concrete mixture by 13.5% was revealed. Wollastonite and diopside are actively involved in the formation of a stable structure of foam concrete and are structurally modifying centers. The introduction of mineral additives contributes to the formation of a homogeneous stable structure of non-autoclave foam concrete. Thus, an increase in the stability of the cellular system in the technology of non-autoclave cement-ash foam concrete is possible due to the control of the processes of structure formation when using dispersed mineral additives of wollastonite and diopside. Due to the structural-modifying effect of additives as crystallization centers for neoplasms, a more complete hydration of the cement and a strong contact of the additives with the cement stone should be ensured

Effect of electrolytes with multicharged cations on the strength of stone made of a modified mixed air binder

The possibility of obtaining mixed air binder of high strength and water resistance by using active mineral additives has been considered. In this work, the gypsum binder has been replaced by a combination of hydrated lime with active additives - metakaolin and granulated slag. The ratio effect of the silica component to the binder on the compressive strength of the stone was studied. According to the results of X-ray phase analysis, the presence of tobermorite-like calcium hydrosilicates and the absence of hydrate lime phase were diagnosed in the stone. The influence of electrolyte additives - salts with three-charged cations - on stone hardening kinetics is shown. Increase in the compressive strength of 28-day-old stone from the modified mixed air binder by 5% with the introduction of 1% of the binder mass aluminum sulfate in the mixing water was established. The use of FeCl3 solution for mixing the modified mixed air binder leads to a decrease in the compressive strength of the 28-day-old stone. The mixing of the modified mixed air binder with Al2(SO4)3 solution reduces the time of setting.