Comparison between Carbon Nanotube-Based, Graphite-Based, and Rice Hull Carbon-Based Electrodes with Rice Hull Silica as Catalyst for Electrochemical Detection of Copper

2018 ◽  
Vol 775 ◽  
pp. 283-288
Author(s):  
Leandre Emile D. Apostol ◽  
Jose Victor O. Sacueza ◽  
John Paul Klien Zeus S. Visaya ◽  
Franz Kevin B. Manalo ◽  
Emmanuel A. Florido

This study aimed to determine the copper ion-sensing ability of a carbon nanotube (CNT)-based sensor with carbonized rice hull (CRH) as catalyst. The 50:50 CNT-CRH electrode was compared to 100% graphite, 100% CRH, 100% CNT, 50:50 graphite-CRH, and 70:30 graphite-CRH electrodes. Copper chloride (CuCl2) concentrations of 0.01M, 0.02M, 0.03M, 0.04M, 0.04M, 0.05M, 0.06, 0.07M, 0.08M, 0.09M, and 0.1M were used to test the response of the electrodes. Five trials were done for each concentration. The 50:50 CNT-CRH electrode exhibited good sensor characteristics such as high sensitivity, low resolution, and high correlation in concentration-voltage relationship. Electrical characterization using three-electrode system showed a linear relationship between the concentrations and voltage response. The 50:50 CNT-CRH electrode exhibited a sensitivity of 0.0619 V/0.01M or 9.7 mV/100ppm and a resolution of 10 ppm/1mV. The electrode also exhibited a high correlation R2 value of 0.933.

2018 ◽  
Author(s):  
Peter De Wolf ◽  
Zhuangqun Huang ◽  
Bede Pittenger

Abstract Methods are available to measure conductivity, charge, surface potential, carrier density, piezo-electric and other electrical properties with nanometer scale resolution. One of these methods, scanning microwave impedance microscopy (sMIM), has gained interest due to its capability to measure the full impedance (capacitance and resistive part) with high sensitivity and high spatial resolution. This paper introduces a novel data-cube approach that combines sMIM imaging and sMIM point spectroscopy, producing an integrated and complete 3D data set. This approach replaces the subjective approach of guessing locations of interest (for single point spectroscopy) with a big data approach resulting in higher dimensional data that can be sliced along any axis or plane and is conducive to principal component analysis or other machine learning approaches to data reduction. The data-cube approach is also applicable to other AFM-based electrical characterization modes.


2012 ◽  
Vol 2012 ◽  
pp. 1-15 ◽  
Author(s):  
Waris Obitayo ◽  
Tao Liu

The use of carbon nanotubes for piezoresistive strain sensors has acquired significant attention due to its unique electromechanical properties. In this comprehensive review paper, we discussed some important aspects of carbon nanotubes for strain sensing at both the nanoscale and macroscale. Carbon nanotubes undergo changes in their band structures when subjected to mechanical deformations. This phenomenon makes them applicable for strain sensing applications. This paper signifies the type of carbon nanotubes best suitable for piezoresistive strain sensors. The electrical resistivities of carbon nanotube thin film increase linearly with strain, making it an ideal material for a piezoresistive strain sensor. Carbon nanotube composite films, which are usually fabricated by mixing small amounts of single-walled or multiwalled carbon nanotubes with selected polymers, have shown promising characteristics of piezoresistive strain sensors. Studies also show that carbon nanotubes display a stable and predictable voltage response as a function of temperature.


2010 ◽  
Vol 11 (5-6) ◽  
pp. 405-410 ◽  
Author(s):  
Charlie Koechlin ◽  
Sylvain Maine ◽  
Stéphanie Rennesson ◽  
Riad Haidar ◽  
Brigitte Trétout ◽  
...  

Author(s):  
Feng Gao ◽  
Jianmin Qu ◽  
Matthew Yao

The carbon nanotube (CNT) is becoming a promising candidate as electrical interconnects in nanoscale electronics. This paper reports the electronic structure and the electrical conducting properties at the interface between an open-end single wall CNT (SWCNT) and various metal electrodes, such as Al, Au, Cu, and Pd. A simulation cell consisting of an SWCNT with each end connected to the metal electrode was constructed. A voltage bias is prescribed between the left- and right-electrodes to compute the electronic conductance. Due to the electronic structure, the electron density and local density of states (LDOS) are calculated to reveal the interaction behavior at the interfaces. The first-principle quantum mechanical density functional and non-equilibrium Green’s function (NEGF) approaches are adopted to compute the transport coefficient. After that, the voltage-current relation is calculated using the Landauer-Buttiker formalism. The results show that electrons are conducted through the electrode/CNT/electrode two-probe system. The contact electronic resistance is calculated by averaging the values in the low voltage bias regime (0.0–0.1 V), in which the voltage–current relationship is found to be linear. And the electrical contact conductance of electrode/CNT/electrode system show the electrode-type dependent, however, the amplitude for different electrodes is of the same order.


2019 ◽  
Vol 1053 ◽  
pp. 155-161 ◽  
Author(s):  
Yu Cui ◽  
Xuewei Wang ◽  
Qi Zhang ◽  
Hao Zhang ◽  
Huahua Li ◽  
...  

2006 ◽  
Vol 120 (1) ◽  
pp. 298-304 ◽  
Author(s):  
YeoHeung Yun ◽  
Vesselin Shanov ◽  
Mark J. Schulz ◽  
Zhongyun Dong ◽  
Abdul Jazieh ◽  
...  

2012 ◽  
Vol 14 (3) ◽  
pp. 613-624 ◽  
Author(s):  
Joon Hyub Kim ◽  
Jun-Yong Lee ◽  
Joon-Hyung Jin ◽  
Chan Won Park ◽  
Cheol Jin Lee ◽  
...  

2018 ◽  
Vol 34 (4) ◽  
pp. 395-395 ◽  
Author(s):  
Ryo KATO
Keyword(s):  

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