Development of Functional Polymer as Oil-Well Cement Retarder

2015 ◽  
Vol 814 ◽  
pp. 191-198 ◽  
Author(s):  
Xiu Jian Xia ◽  
Jin Tang Guo ◽  
Shuo Qiong Liu ◽  
Jian Zhou Jin ◽  
Yong Jin Yu ◽  
...  
Keyword(s):  
High Temperature ◽  
Ultrasonic Method ◽  
Strength Development ◽  
Cement Stone ◽  
Oil Well ◽  
Cement Slurry ◽  
Oil Well Cement ◽  
Cement Retarder ◽  
The Stability ◽  
Well Cement

In this study, a novel polymer retarder DRH-200LG was synthesized to solve the problems of retarding failure, strong dispersivity under high temperature and adverse impact on the strength development of cement stone. The composition of the polymer was confirmed by IR, and its thermal stability was proved by DSC, TG analysis and thermal treatment at 200 °C. Furthermore, the stability and strength development of cement slurry was evaluated by the comparative consistency method and ultrasonic method, respectively. The results show that DRH-200LG has good high temperature-resistance and retarding performance, presenting favourable influence on the stability and strength development of cement slurry. DRH-200LG shows a good application prospect in the cementation of deep & ultra-deep wells. And it has some guiding significance in the research and innovation of a novel polymer used as oil well cement retarder.

Performance Evaluation of Polycarboxylic Acid Dispersant for Oil Well Cementing

2020 ◽  
Vol 993 ◽  
pp. 1341-1350
Author(s):  
Xiu Jian Xia ◽  
Yong Jin Yu ◽  
Jian Zhou Jin ◽  
Shuo Qiong Liu ◽  
Ming Xu ◽  
...  
Keyword(s):  
High Temperature ◽  
Salt Resistance ◽  
Strength Development ◽  
Fluid Loss ◽  
Oil Well ◽  
Polycarboxylic Acid ◽  
Cement Slurry ◽  
Deep Wells ◽  
Oil Well Cement ◽  
Well Cement

The conventional oil-well cement dispersant has the characteristics of poor dispersion at high temperature, poor compatibility with other additives, and environmental pollution during the production process. In this article, with ultra-early strong polyether monomer, acrylic acid, 2-acrylamine-2-methylpropyl sulfonic acid, sodium methacrylate as copolymer monomers, an environmentally friendly polycarboxylic acid dispersant, DRPC-1L, was prepared by the aqueous solution free-radical polymerization. The chemical composition and thermal stability of the synthetic copolymer were characterized by FTIR and TGA techniques. The evaluation results show that DRPC-1L has a wide temperature range (30~210 °C), good salt-resistance and dispersing effect. It can significantly improve the rheological performance of cement slurry, and it is well matched with oil-well cement additives such as fluid loss agent, retarder and so on. Moreover, it is beneficial to the mechanical strength development of set cement, especially the early compressive strength. It can also inhibit the abnormal gelation phenomenon of cement slurry, flash set, that occurs during high temperature thickening experiments, which plays an important role in enhancing the comprehensive performance of cement slurry. Consequently, the novel polycarboxylic acid dispersant has good application prospects in deep and ultra-deep wells cementing.

Research Status of Synthetic Oil Well Cement Retarder

2020 ◽  
Vol 14 ◽  
Author(s):  
Guo Zihan ◽  
Liu Ziyang ◽  
Liao Kai ◽  
Yang Xianghui
Keyword(s):  
Great Influence ◽  
Large Temperature ◽  
Strength Development ◽  
Cement Stone ◽  
Oil Well ◽  
Research Status ◽  
Synthetic Oil ◽  
Oil Well Cement ◽  
Cement Retarder ◽  
Well Cement

: Oil well cement retarder is an additive that can extend time for thickening cement slurry, which can ensure the safety of cement. At present, the oil well cement retarder is mainly composed of synthetic materials, which are mainly divided into three major categories: compound polymer, AMPS polymer and non-AMPS. In this paper, the research status of synthetic oil well cement retarder in recent years is reviewed, and its shortcomings and development trends are analyzed. It is pointed out that the shortage of synthetic retarder mainly lies in problems, including large temperature sensitivity, small temperature application range, abnormal thickening curve, great influence on high temperature settlement stability and cement stone strength development. The development direction of oil well cement retarder is mainly focused on developing intelligent retarder and degradable retarder to meet the cementing needs of oilfields and ensure cementing effect increasing steadily.

Development and Change of Compressive Strength for Class G Oil Well Cement under High Temperature

2014 ◽  
Vol 941-944 ◽  
pp. 1441-1444 ◽  
Author(s):  
Jing Fu Zhang ◽  
Kai Liu ◽  
Rui Xue Hou ◽  
Bo Wang ◽  
Jin Long Yang
Keyword(s):  
Compressive Strength ◽  
High Temperature ◽  
Initial Period ◽  
Strength Development ◽  
Oil Well ◽  
Curing Time ◽  
Cement Slurry ◽  
Critical Temperatures ◽  
Oil Well Cement ◽  
Well Cement

The compressive strength of oil well cement would be damaged by high temperature in deep oil wells, which was caused by the obvious change of the components and microstructure of cement hydration products. The adaptability of common oil well cement for cementing under higher temperatures was confined by above reasons. Characteristics of development and change of compressive strength of Class G oil well cement were studied under different temperatures by using Static Gel Strength Analyzer and High Temperature-High Pressure curing chamber. The influence law of temperature and silica sands on compressive strength was analyzed. The results showed that the critical temperatures at which the compressive strength begun to decline were about 110°C and 150°C respectively; The compressive strength increased with curing time during the initial period and would reduced after it reached a certain value when temperature exceeded 110°C; For cement with silica sands, the compressive strength development trend was in the shape of two-stage form with increase of curing time within the range of 110~150°C, but for 160~200°C temperature range the development form was in the shape of single stage; The reasonable amounts of silica sands which would be added to cement slurry to enhance the compressive strength of hardening paste were determined to be 30%~40%.

scholarly journals Synergistic Effect of Latex Powder and Rubber on the Properties of Oil Well Cement-Based Composites

2018 ◽  
Vol 2018 ◽  
pp. 1-9 ◽  
Author(s):  
Jianjian Song ◽  
Mingbiao Xu ◽  
Weihong Liu ◽  
Xiaoliang Wang ◽  
Yumeng Wu
Keyword(s):  
Synergistic Effect ◽  
External Load ◽  
Oil And Gas ◽  
Fluid Loss ◽  
Cement Stone ◽  
Oil Well ◽  
Cement Slurry ◽  
Sem Images ◽  
Oil Well Cement ◽  
Well Cement

The brittleness and the poor resistance to external load of oil well cement impede the development of oil and gas wells. To overcome these deficiencies, latex powder or rubber and their hybrid combinations were used to modify the oil well cement. The conventional properties, mechanical properties, and scanning electron microscopy (SEM) images of the modified cement were analyzed. In comparison with latex powder-incorporated cement and rubber-incorporated cement, a significant improvement of fluid loss, flexural strength, impact strength, and elasticity of the cement slurry was observed when using the hybrid combinations of 3 wt.% latex powder and 2 wt.% rubber, although this synergistic effect was not remarkable on the compressive strength and the thickening time. These evidences arose from the synergism between latex powder and rubber leading to the formation of a three-dimensional network structure and a flexible structure which subsequently improved the elasticity and toughness of cement stone. The improved elastic matrix has a buffering effect on external impact when the cement stone is subjected to an external load.

Mechanical Properties and Mechanism of Graphite Oxide Reinforced Oil Well Cement

2016 ◽  
Vol 847 ◽  
pp. 445-450 ◽  
Author(s):  
Ming Li ◽  
Fei Meng ◽  
Xiao Yang Guo
Keyword(s):  
Mechanical Properties ◽  
Graphite Oxide ◽  
Complex Stress ◽  
Fluid Loss ◽  
Cement Stone ◽  
Oil Well ◽  
Cement Slurry ◽  
Oil Well Cement ◽  
Reinforced Cement ◽  
Well Cement

The effect of graphite oxide (GO) on the mechanical properties of oil well cement was experimentally studied, in view of the zonal isolation failure due to the brittleness. The microstructure of cement stone was observed by SEM, and the mechanism of graphite oxide reinforced cement stone was also investigated. The result illustrates that the mechanical properties of cement was improved significantly due to the addition of GO. When the GO dosage was 0.05%, the compressive strength, flexural toughness, and splitting tensile strength of cement paste at 7 day age were increased by 61.32%, 15.46% and 145.34% respectively. GO had no bad effect on the application properties of cement slurry, and the stability of the slurry was favorable. Besides, GO could reduce the fluid loss of cement slurry. When GO reinforced cement stone undergoes damage under complex stress, if damage occurs within graphite oxide layer, chemical bonds of GO layers must have been broken, and the force between the layers of GO must be overcome when interlaminar peeling happens, which will lead large amounts of energy consumption as well. The mechanical properties of the cement stone were enhanced by the above two aspects. The research results can provide a theoretical reference for solving the brittle fracture of oil well cement stone.

scholarly journals Hybrid Effect of Wollastonite Fiber and Carbon Fiber on the Mechanical Properties of Oil Well Cement Pastes

2020 ◽  
Vol 2020 ◽  
pp. 1-9
Author(s):  
Jianglin Zhu ◽  
Jiangxiong Wei ◽  
Qijun Yu ◽  
Mingbiao Xu ◽  
Yuwei Luo
Keyword(s):  
Mechanical Properties ◽  
Compressive Strength ◽  
Carbon Fiber ◽  
Impact Strength ◽  
Flexural Strength ◽  
Cement Stone ◽  
Oil Well ◽  
Cement Slurry ◽  
Oil Well Cement ◽  
Well Cement

Oil well cement is a type of natural brittle material that cannot be used directly in cementing operations. Fiber is a type of material that can effectively improve the strength and toughness of cement stone, and hybrid fiber materials can more effectively improve the performance of a cement sample. To overcome the natural defects of oil well cement, the new mineral fiber, i.e., wollastonite fiber, and common carbon fiber were used in oil well cement, and the micromorphology, mechanical properties, and stress-strain behavior of the cement were evaluated. The experimental results show that carbon fiber and wollastonite fiber are randomly distributed in the cement paste. The mechanical properties of the cement paste are improved by bridging and pulling out. The compressive strength, flexural strength, and impact strength of cement stone containing only carbon fiber or wollastonite fiber are higher than those of the pure cement, but too many fibers are not conducive to the development of mechanical properties. A mixture of 0.3% carbon fiber with 6% wollastonite fiber in oil well cement slurry results in a greater increase in compressive strength, flexural strength, and impact strength. In addition, compared with blank cement stone, the strain of the mixed cement stone increases substantially, and the elastic modulus decreases by 37.8%. The experimental results supply technical support for the design of a high-performance cement slurry system.

Synthesis and Properties of Dispersive Type High Temperature Filtrate Reducer Used in Oil Well Cement

2013 ◽  
Vol 734-737 ◽  
pp. 2136-2140
Author(s):  
Di Hui Ma ◽  
Zhen Wei ◽  
Zong Gang Wang
Keyword(s):  
High Temperature ◽  
Rheological Property ◽  
Mass Fraction ◽  
Salt Resistance ◽  
Fluid Loss ◽  
Oil Well ◽  
Cement Slurry ◽  
Oil Well Cement ◽  
Cement Strength ◽  
Well Cement

The advanced dispersive type high temperature filtrate reducer used in oil well cement was synthesized with 2-acryloyl-2-methyl-propyl sulfonic (AMPS) , N, N-dimethylacrylamide (DMAA) and organic acids. When the mass fraction of synthetic filtrate reducer was 1%, the filter loss of the cement slurry was 30ml/30min at 120 °C and 49ml/30min at 150°C respectively, and the cement strength was 25MPa after 24 hours, and the rheological property of the cement slurry was well when the mass fraction of synthetic filtrate reducer was 2%, and liquidity factor was 0.85, and the consistency was 0.43. The results showed that the filtrate reducer had good dispersity and could control the fluid loss efficiently, and the ability of resistance to high temperature and salt resistance was good.

Sign in / Sign up

Export Citation Format

Share Document