Secondary Austenite Precipitation during the Welding of Duplex Stainless Steels

2016 ◽  
Vol 869 ◽  
pp. 562-566
Author(s):  
Sandro de Alencar Pires ◽  
Marcos Flavio de Campos ◽  
C.J. Marcelo ◽  
Carlos Roberto Xavier

In this work a multipass welding procedure was carried out on a 2205 Duplex stainless steels (DDS) plate. Due to the reheating cycle caused by the adopted procedure, it has favored the precipitation of secondary austenite at the weldment microstructure, besides of encouraging the grain growth at the heat affected zone (HAZ).

1997 ◽  
Vol 36 (7) ◽  
pp. 775-781 ◽  
Author(s):  
Mann Joo Huh ◽  
Sang Beom Kim ◽  
Kyung Wook Paik ◽  
Young Gil Kim

2015 ◽  
Vol 160 (9) ◽  
pp. 413-418 ◽  
Author(s):  
Axel Corolleur ◽  
Amélie Fanica ◽  
Gilles Passot

2010 ◽  
Vol 15 (4) ◽  
pp. 336-343 ◽  
Author(s):  
Demian J. Kotecki

Duplex stainless steels (DSS, including super duplex stainless steels {SDSS}) have proven to be very useful engineering materials, albeit with somewhat different welding requirements than those of the more familiar austenitic stainless steels. Despite a generally good track record in welding of duplex stainless steels, certain pitfalls have been encountered with enough frequency that they deserve review. Inappropriate base metal specification often leads to unsuitable heat affected zone (HAZ) properties. Autogenous fusion zones are also of concern. This issue centers around nitrogen limits. The most frequently encountered is applying the UNS S31803 composition for 2205 DSS, instead of the S32205 composition. Inappropriate welding heat input arises most frequently with SDSS. While 0.5 to 1.5 kJ/mm is a normal heat input recommendation for SDSS, either a root pass or many small beads towards the low end of this heat input range tends to result in precipitation and/or secondary austenite formation in weld metal subjected to repeated thermal cycles from multiple weld passes. Inappropriate PWHT occurs when the enhanced nickel filler metals (typically 9% Ni) are used. DSS are not normally given PWHT, but extensive forming of heads, for example, or repair welding of castings, may require a postweld anneal. Specifications such as ASTM A790 and A890 call for annealing at 1040ºC minimum, and the fabricator tends to use temperatures close to that minimum. However, the enhanced nickel filler metals require higher temperatures to dissolve sigma phase that forms during heating to the annealing temperature.


2013 ◽  
Vol 794 ◽  
pp. 257-273
Author(s):  
Damian J. Kotecki

This lecture presents the authors personal views on the landmark events that have strongly affected the welding of stainless steels over their lifetime. Although 1913 is commonly recognized as the birth of stainless steels with the commercialization of the martensitic alloy of Harry Brearly and the austenitic alloy of Eduard Maurer and Benno Straus, the story can be considered to begin as long ago as 1797 with the discovery of chromium by Klaproth and Vauquelin, and the observation by Vauquelin in 1798 that chromium resists acids surprisingly well. From the 1870s onwards, corrosion resisting properties of iron-chromium alloys were known. One might mark the first iron-chromium-nickel constitution diagram of Maurer and Strauss in 1920 as a major landmark in the science of welding of stainless steels. Their diagram evolved until the outbreak of World War II in Europe in 1939, and nominally austenitic stainless steel weld metals, containing ferrite that provided crack resistance, were extensively employed for armor welding during the war, based on their diagram. Improved diagrams for use in weld filler metal design and dissimilar welding were developed by Schaeffler (1947-1949), DeLong (1956-1973) and the Welding Research Council (1988 and 1992). Until about 1970, there was a major cost difference between low carbon austenitic stainless steels and those austenitic stainless steels of 0.04% carbon and more because the low carbon grades had to be produced using expensive low carbon ferro-chromium. Welding caused heat affected zone sensitization of the higher carbon alloys, which meant that they had to be solution annealed and quenched to obtain good corrosion resistance. In 1955, Krivsky invented the argon-oxygen decarburization process for refining stainless steels, which allowed low carbon alloys to be produced using high carbon ferro-chromium. AOD became widely used by 1970 in the industrialized countries and the cost penalty for low carbon stainless steel grades virtually vanished, as did the need to anneal and quench stainless steel weldments. Widespread use of AOD refining of stainless steels brought with it an unexpected welding problem. Automatic welding procedures for orbital gas tungsten arc welding of stainless steel tubing for power plant construction had been in place for many years and provided 100% penetration welds consistently. However, during the 1970s, inconsistent penetration began to appear in such welds, and numerous researchers sought the cause. The 1982 publication of Heiple and Roper pinpointed the cause as a reversal of the surface tension gradient as a function of temperature on the weld pool surface when weld pool sulfur became very low. The AOD refining process was largely responsible for the very low sulfur base metals that resulted in incomplete penetration. The first duplex ferritic-austenitic stainless steel was developed in 1933 by Avesta in Sweden. Duplex stainless steels were long considered unweldable unless solution annealed, due to excessive ferrite in the weld heat-affected zone. However, in 1971, Joslyn Steel began introducing nitrogen into the AOD refining of stainless steels, and the duplex stainless steel producers noticed. Ogawa and Koseki in 1989 demonstrated the dramatic effect of nitrogen additions on enhanced weldability of duplex stainless steels, and these are widely welded today without the need to anneal. Although earlier commercial embodiments of small diameter gas-shielded flux cored stainless steel welding electrodes were produced, the 1982 patent of Godai and colleagues became the basis for widespread market acceptance of these electrodes from many producers. The key to the patent was addition of a small amount of bismuth oxide which resulted in very attractive slag detachment. Electrodes based on this patent quickly came to dominate the flux cored stainless steel market. Then a primary steam line, welded with these electrodes, ruptured unexpectedly in a Japanese power plant. Investigations published in 1997 by Nishimoto et al and Toyoda et al, among others, pinpointed the cause as about 200 ppm of bismuth retained in the weld metal which led to reheat cracking along grain boundaries where the Bi segregated. Bismuth-free electrode designs were quickly developed for high temperature service, while the bismuth-containing designs remain popular today for service not involving high temperatures.


1984 ◽  
Vol 70 (15) ◽  
pp. 2025-2032 ◽  
Author(s):  
Masayuki ABE ◽  
Akira HIURA ◽  
Kiyohito ISHIDA ◽  
Taiji NISHIZAWA

2018 ◽  
Vol 930 ◽  
pp. 317-321
Author(s):  
José Adilson de Castro ◽  
Gláucio Soares da Fonseca ◽  
D.S.S. Almeida ◽  
L.C.R. Lopes ◽  
C.R. Xavier ◽  
...  

The thermal properties of the super duplex stainless steels are strongly affected by the thermal history when welding procedure are applied leading to substantial changes on the mechanical properties of the welding region. The controlled dual phase microstructure (ferrite and austenite) guarantee excellent mechanical properties such as mechanical strength and corrosion resistance, in addition to small thermal expansion coefficient and high thermal conductivity. In this research a model able to predict the thermal history of the welding pieces coupled with local mechanical properties developed during welding procedure is developed. The model was verified by measured temperature profile and used to predict local properties such as grain size evolution, hardness and mechanical strength. An inverse method was implemented to obtain the parameters fitting for the grain growth evolution, hardness and yielding strength compatible with the final microstructure and grain size measured using SEM images and stereological techniques.


2013 ◽  
Vol 82 (6) ◽  
pp. 435-438
Author(s):  
Yusuke OIKAWA ◽  
Shinji TSUGE ◽  
Haruhiko KAJIMURA ◽  
Hiroshige INOUE

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