scholarly journals The study of viscosity-temperature dependence and activation energy for palm oil and soybean oil

2019 ◽  
Vol 25 (2) ◽  
pp. 209-217 ◽  
Author(s):  
E Ike
Keyword(s):  
Soybean Oil ◽  
Palm Oil ◽  
Fluid Transport ◽  
Physicochemical Analysis ◽  
Biodiesel Production ◽  
Equation Modeling ◽  
Activation Temperature ◽  
Electric Voltage ◽  
Exponential Factor ◽  
Precise Knowledge

In fluid transport, precise knowledge or estimation of fluids behaviour is very necessary, for mass flow and heat transfer computations. In this study, physicochemical analysis of palm oil and soybean oil were conducted, in addition to an equation modeling the relationship between the energy (Ea) and the pre-exponential factor (A). Later, two other parameters; the Arrhenius temperature (T) and Arrhenius activation temperature (T*) were introduced to buttress the veracity of the model used. The model is very useful in engineering since it would make for the estimation of the missing parameter value and its derivatives. The goodness of the result is strongly reinforced by the regression coefficient. The results indicate that the model which best fits the major defining parameters are logarithmic in nature. All the parameters studied showed that the two oil samples are good feedstock for biodiesel production and confirms their relevance in electric voltage transformers.Keywords: Physicochemical, Viscosity, Arrhenius Parameters, Equation Modeling, Temperature, Vegetable Oil

USE OF NORTHERN ECOTYPE SOYBEANS FOR BIOFUEL PRODUCTION

2020 ◽  
pp. 22-30
Author(s):  
SERGEY N. DEVYANIN ◽  
◽  
VLADIMIR A. MARKOV ◽  
ALEKSANDR G. LEVSHIN ◽  
TAMARA P. KOBOZEVA ◽  
...  
Keyword(s):  
Diesel Engine ◽  
Soybean Oil ◽  
Diesel Fuel ◽  
Experimental Studies ◽  
Motor Fuel ◽  
Biodiesel Production ◽  
Biofuel Production ◽  
Exhaust Gases ◽  
Oil Productivity ◽  
Toxic Components

The paper presents the results of long-term research on the oil productivity and chemical composition of soybean oil of the Northern ecotype varieties in the Central Non-Black Earth Region. The authors consider its possible use for biodiesel production. Experiments on growing soybeans were carried out on the experimental fi eld of Russian State Agrarian University –Moscow Timiryazev Agricultural Academy (2008-2019) on recognized ultra-early ripening varieties of the Northern ecotype Mageva, Svetlaya, Okskaya (ripeness group 000). Tests were set and the research results were analyzed using standard approved methods. It has been shown that in conditions of high latitudes (57°N), limited thermal resources of the Non-Chernozem zone of Russia (the sum of active temperatures of the growing season not exceeding 2000°С), the yield and productivity of soybeans depend on the variety and moisture supply. Over the years, the average yield of soybeans amounted to 1.94 … 2.62 t/ha, oil productivity – 388 … 544 kg/ha, oil content – 19…20%, the content of oleic and linoleic fatty acids in oil – 60%, and their output from seeds harvested – 300 kg/ha. It has been established that as soybean oil and diesel fuel have similar properties,they can be mixed by conventional methods in any proportions and form stable blends that can be stored for a long time. Experimental studies on the use of soybean oil for biodiesel production were carried out on a D-245 diesel engine (4 ChN11/12.5). The concentrations of toxic components (CO, CHx, and NOx) in the diesel exhaust gases were determined using the SAE-7532 gas analyzer. The smoke content of the exhaust gases was measured with an MK-3 Hartridge opacimeter. It has been experimentally established that the transfer of a diesel engine from diesel fuel to a blend of 80% diesel fuel and 20% lubrication oil leads to a change in the integral emissions per test cycle: nitrogen oxides in 0.81 times, carbon monoxide in 0.89 times and unburned hydrocarbons in 0.91 times, i.e. when biodiesel as used as a motor fuel in a serial diesel engine, emissions of all gaseous toxic components are reduced. The study has confi rmed the expediency of using soybeans of the Northern ecotype for biofuel production.

Optimization of biodiesel production by transesterification of palm oil and evaluation of biodiesel quality

2021 ◽  
Author(s):  
Alex Soly Peter ◽  
Mathews P. Alias ◽  
Mildo P. Iype ◽  
Jerin Jolly ◽  
Vishnu Sankar ◽  
...  
Keyword(s):  
Palm Oil ◽  
Biodiesel Production ◽  
Biodiesel Quality

Calcium Methoxide Synthesis from Quick Lime Using as Solid Catalyst in Refined Palm Oil Biodiesel Production

2013 ◽  
Vol 834-836 ◽  
pp. 550-554 ◽  
Author(s):  
Warakom Suwanthai ◽  
Vittaya Punsuvon ◽  
Pilanee Vaithanomsat
Keyword(s):  
Palm Oil ◽  
Acid Methyl Ester ◽  
Biodiesel Production ◽  
Molar Ratio ◽  
Catalyst Loading ◽  
Solid Catalyst ◽  
Solid Base ◽  
Quick Lime ◽  
X Ray ◽  
Refined Palm Oil

In this research, calcium methoxide was synthesized as solid base catalyst from quick lime for biodiesel production. The catalyst was further characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), attenuated total reflection fourier transform (ATR-FTIR) and Energy-dispersive X-ray spectroscopies (EDX) to evaluate its performance. The transesterification of refined palm oil using calcium methoxide and the process parameters affecting the fatty acid methyl ester (FAME) content such as catalyst concentration, methanol:oil molar ratio and reaction time were investigated. The results showed that the FAME content at 97% was achieved within 3 h using 3 %wt catalyst loading, 12:1 methanol:oil molar ratio and 65 °C reaction temperature. The result of FAME suggested calcium methoxide was the promising solid catalyst for substitution of the conventional liquid catalyst.

scholarly journals Deep Eutectic Solvents Based Choline Chloride for Enzymatic Biodiesel Production from Degumming Palm Oil

2020 ◽  
Vol 32 (4) ◽  
pp. 733-738 ◽  
Author(s):  
R. Manurung ◽  
Taslim ◽  
A.G.A. Siregar
Keyword(s):  
Palm Oil ◽  
Raw Materials ◽  
Choline Chloride ◽  
Deep Eutectic Solvent ◽  
Deep Eutectic Solvents ◽  
Biodiesel Production ◽  
Chloride Salt ◽  
Enzymatic Reactions ◽  
Potential Applications ◽  
Palm Oil Biodiesel

Deep eutectic solvents (DESs) have numerous potential applications as cosolvents. In this study, use of DES as organic solvents for enzymatic biodiesel production from degumming palm oil (DPO) was investigated. Deep eutectic solvent was synthesized using choline chloride salt (ChCl) compounds with glycerol and 1,2-propanediol. Deep eutectic solvent was characterized by viscosity, density, pH and freezing values, which were tested for effectiveness by enzymatic reactions for the production of palm biodiesel with raw materials DPO. Deep eutectic solvent of ChCl and glycerol produced the highest biodiesel yield (98.98%); weight of DES was only 0.5 % of that of the oil. In addition, the use of DES maintained the activity and stability of novozym enzymes, which was assessed as the yield until the 6th usage, which was 95.07 % biodiesel yield compared with the yield without using DES. Hence, using DES, glycerol in enzymatic biodiesel production had high potentiality as an organic solvent for palm oil biodiesel production

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