Optimization of biodiesel production by transesterification of palm oil and evaluation of biodiesel quality

2021 ◽  
Author(s):  
Alex Soly Peter ◽  
Mathews P. Alias ◽  
Mildo P. Iype ◽  
Jerin Jolly ◽  
Vishnu Sankar ◽  
...  
Keyword(s):  
Palm Oil ◽  
Biodiesel Production ◽  
Biodiesel Quality

scholarly journals Advancing biodiesel production from microalgae Spirulina sp. by a simultaneous extraction–transesterification process using palm oil as a co-solvent of methanol

2020 ◽  
Vol 18 (1) ◽  
pp. 833-842
Author(s):  
Yano Surya Pradana ◽  
Resti Nurmala Dewi ◽  
Kanadya Di Livia ◽  
Farida Arisa ◽  
Rochim Bakti Cahyono ◽  
...  
Keyword(s):  
Palm Oil ◽  
Weight Ratio ◽  
Single Stage ◽  
Biodiesel Production ◽  
Molar Ratio ◽  
Potential Candidate ◽  
Simultaneous Extraction ◽  
Stirred Reactor ◽  
Biodiesel Feedstock ◽  
Biodiesel Quality

AbstractMicroalgae have been considered as a potential candidate for biodiesel feedstock. Single-stage simultaneous extraction–transesterification process is proposed for simpler and more effective biodiesel conversion. In this study, the experiment of biodiesel production from microalgae Spirulina sp. was performed in a batch-stirred reactor using palm oil as a co-solvent of methanol and catalyzed by potassium hydroxide at a percentage of 1 wt% (w/w of palm oil). The effects of methanol–palm oil molar ratio, palm oil–microalgae weight ratio, and temperature on biodiesel yield were investigated. The results showed that the best biodiesel yield was 85.28% (99.01% of partial biodiesel yield from palm oil and 16.69% of partial biodiesel yield from dry microalgae), obtained at a methanol–palm oil molar ratio of 10:1, a palm oil–microalgae weight ratio of 5:1, and at a temperature of 60°C. Upon comparison, the overall yield increased by 34.59% (37.73% of partial biodiesel yield from palm oil and 13.00% of partial biodiesel yield from dry microalgae) than that of the two-stage (conventional) method. Single-stage simultaneous extraction–transesterification process also reduced the number of unsaturated fatty acid components in biodiesel that will lower the biodiesel quality.

Calcium Methoxide Synthesis from Quick Lime Using as Solid Catalyst in Refined Palm Oil Biodiesel Production

2013 ◽  
Vol 834-836 ◽  
pp. 550-554 ◽  
Author(s):  
Warakom Suwanthai ◽  
Vittaya Punsuvon ◽  
Pilanee Vaithanomsat
Keyword(s):  
Palm Oil ◽  
Acid Methyl Ester ◽  
Biodiesel Production ◽  
Molar Ratio ◽  
Catalyst Loading ◽  
Solid Catalyst ◽  
Solid Base ◽  
Quick Lime ◽  
X Ray ◽  
Refined Palm Oil

In this research, calcium methoxide was synthesized as solid base catalyst from quick lime for biodiesel production. The catalyst was further characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), attenuated total reflection fourier transform (ATR-FTIR) and Energy-dispersive X-ray spectroscopies (EDX) to evaluate its performance. The transesterification of refined palm oil using calcium methoxide and the process parameters affecting the fatty acid methyl ester (FAME) content such as catalyst concentration, methanol:oil molar ratio and reaction time were investigated. The results showed that the FAME content at 97% was achieved within 3 h using 3 %wt catalyst loading, 12:1 methanol:oil molar ratio and 65 °C reaction temperature. The result of FAME suggested calcium methoxide was the promising solid catalyst for substitution of the conventional liquid catalyst.

scholarly journals Deep Eutectic Solvents Based Choline Chloride for Enzymatic Biodiesel Production from Degumming Palm Oil

2020 ◽  
Vol 32 (4) ◽  
pp. 733-738 ◽  
Author(s):  
R. Manurung ◽  
Taslim ◽  
A.G.A. Siregar
Keyword(s):  
Palm Oil ◽  
Raw Materials ◽  
Choline Chloride ◽  
Deep Eutectic Solvent ◽  
Deep Eutectic Solvents ◽  
Biodiesel Production ◽  
Chloride Salt ◽  
Enzymatic Reactions ◽  
Potential Applications ◽  
Palm Oil Biodiesel

Deep eutectic solvents (DESs) have numerous potential applications as cosolvents. In this study, use of DES as organic solvents for enzymatic biodiesel production from degumming palm oil (DPO) was investigated. Deep eutectic solvent was synthesized using choline chloride salt (ChCl) compounds with glycerol and 1,2-propanediol. Deep eutectic solvent was characterized by viscosity, density, pH and freezing values, which were tested for effectiveness by enzymatic reactions for the production of palm biodiesel with raw materials DPO. Deep eutectic solvent of ChCl and glycerol produced the highest biodiesel yield (98.98%); weight of DES was only 0.5 % of that of the oil. In addition, the use of DES maintained the activity and stability of novozym enzymes, which was assessed as the yield until the 6th usage, which was 95.07 % biodiesel yield compared with the yield without using DES. Hence, using DES, glycerol in enzymatic biodiesel production had high potentiality as an organic solvent for palm oil biodiesel production

scholarly journals Biodiesel Production by Reactive Flash: A Numerical Simulation

2016 ◽  
Vol 2016 ◽  
pp. 1-8 ◽  
Author(s):  
Alejandro Regalado-Méndez ◽  
Sigurd Skogestad ◽  
Reyna Natividad ◽  
Rubí Romero
Keyword(s):  
Numerical Simulation ◽  
Differential Algebraic Equations ◽  
Biodiesel Production ◽  
Algebraic Equations ◽  
Flow Ratio ◽  
Bubble Point ◽  
Biodiesel Quality ◽  
Index 2 ◽  
Globally Stable ◽  
System Approaches

Reactive flash (RF) in biodiesel production has been studied in order to investigate steady-state multiplicities, singularities, and effect of biodiesel quality when the RF system approaches to bubble point. The RF was modeled by an index-2 system of differential algebraic equations, the vapor split (ϕ) was computed by modified Rachford-Rice equation and modified Raoult’s law computed bubble point, and the continuation analysis was tracked on MATCONT. Results of this study show the existence of turning points, leading to a unique bubble point manifold,(xBiodiesel,T)=(0.46,478.41 K), which is a globally stable flashing operation. Also, the results of the simulation in MATLAB® of the dynamic behavior of the RF show that conversion of triglycerides reaches 97% for a residence time of 5.8 minutes and a methanol to triglyceride molar flow ratio of 5 : 1.

Engine Performance Investigations of Palm Oil, Jatropha Oil and Waste Cooking Oil as Alternative Fuel

2015 ◽  
Vol 1113 ◽  
pp. 674-678
Author(s):  
Syarifah Yunus ◽  
Noriah Yusoff ◽  
Muhammad Faiz Fikri Ahmad Khaidzir ◽  
Siti Khadijah Alias ◽  
Freddawati Rashiddy Wong ◽  
...  
Keyword(s):  
Palm Oil ◽  
Engine Performance ◽  
Alternative Fuel ◽  
Waste Cooking Oil ◽  
Biodiesel Production ◽  
Gas Temperature ◽  
Performance Effect ◽  
Cooking Oil ◽  
Exhaust Gas Temperature ◽  
Global Agenda

The continued using of petroleum energy as a sourced for fuel is widely recognized as unsustainable because of the decreasing of supplies while increasing of the demand. Therefore, it becomes a global agenda to develop a renewable, sustainable and alternative fuel to meets with all the demand. Thus, biodiesel seems to be one of the best choices. In Malaysia, the biodiesel used is from edible vegetable oil sources; palm oil. The uses of palm oil as biodiesel production source have been concern because of the competition with food materials. In this study, various types of biodiesel feedstock are being studied and compared with diesel. The purpose of this comparison is to obtain the optimum engine performance of these different types of biodiesel (edible, non-edible, waste cooking oil) on which are more suitable to be used as alternative fuel. The optimum engine performance effect can be obtains by considering the Brake Power (BP), Specific Fuel Consumption (SFC), Exhaust Gas Temperature (EGT) and Brake Thermal Efficiency (BTE).

Characterization of Coal Fly Ash, Bottom Ash and their Possibilities as Catalysts for Biodiesel Production

2021 ◽  
Vol 904 ◽  
pp. 413-418
Author(s):  
Wilasinee Kingkam ◽  
Sasikarn Nuchdang ◽  
Dussadee Rattanaphra
Keyword(s):  
Fly Ash ◽  
Palm Oil ◽  
Power Plants ◽  
Coal Fly Ash ◽  
Bottom Ash ◽  
Biodiesel Production ◽  
Catalyst Loading ◽  
Free Lime ◽  
Operation Conditions ◽  
Class C

Coal fly ash (CFA) and bottom ash (BA) obtained from coal fired power plants in Thailand and local supplier were characterized using XRF, XRD and N2 adsorption-desorption techniques. Their possibilities for conversion of palm oil into biodiesel were investigated. Selected CFA was also modified with lanthanum (La) at different La loading and the influence of La loading on biodiesel conversion was evaluated. The resulted showed that the Class C CFA as contained large amount of CaO (free lime) could catalyze the transesterification to achieve the highest FAME content of 89% under the operation conditions; the reaction temperature of 200 °C, the reaction pressure of 39 bars, the catalyst loading of 5 wt% of oil, the molar of oil to methanol of 1:30 and the stirring speed of 600 rpm for 5 h. The addition of La on the Class C CFA had a negative effect on conversion of palm oil. The FAME content decreased gradually from 89 to 62% with increasing La loading from 0 to 1 wt%.

scholarly journals Performance of novel dielectric barrier discharge reactor for biodiesel production from palm oil and ethanol

2018 ◽  
Vol 67 ◽  
pp. 02010 ◽  
Author(s):  
Sari Dafinah Ramadhani ◽  
Saphira Nurina Fakhri ◽  
Setijo Bismo
Keyword(s):  
Palm Oil ◽  
Performance Test ◽  
Plasma Reactor ◽  
Operating Conditions ◽  
Biodiesel Production ◽  
Molar Ratio ◽  
Synthesis Methods ◽  
Dbd Plasma ◽  
Spiral Coil ◽  
Biodiesel Synthesis

The disadvantages of conventional biodiesel synthesis trigger the birth of new biodiesel synthesis methods using the DBD plasma reactor. The conventional methods with homogeneous and heterogeneous catalysts have significant constraints that the formation of glycerol compounds in large enough quantities that require considerable energy. The aim of present experiment is to design DBD non-thermal plasma reactor coaxial pipe type and to do its performance test in converting biodiesel The feed stock used are palm oil, ethanol, and argon gas as plasma carrier. Such a chemical reactor, this plasma reactor is also influenced by reaction kinetics and hydrodynamic factors. From this research, it can be seen that the optimum feed and gas flowrate being operated is 1.64 and 41.67 mL/s. The plasma reactor is used in the form of a quartz glass tube surrounded by a SS-314 spiral coil as an outer electrode. The applied operating conditions are 1 : 1 molar ratio of methanol/oil, ambient temperature of 28 - 30 °C, and pressure 1 bar. From this performance test, it is found that this plasma reactor can be used to synthesize biodiesel from palm oil and methanol without catalyst, no formation of soap, and minimal byproducts.

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