Atmospheric Stress Corrosion Cracking of Stainless Steel Rock Climbing Anchors, Part 1

CORROSION ◽  
10.5006/3227 ◽  
2019 ◽  
Vol 75 (10) ◽  
pp. 1255-1271 ◽  
Author(s):  
Jiří Lieberzeit ◽  
Tomáš Prošek ◽  
Alan Jarvis ◽  
Lionel Kiener

Austenitic stainless steels Cr-Ni (Types 304, 304L, 321, and similar) and Cr-Ni-Mo (Types 316, 316L, 316 Ti, and similar) are susceptible to atmospherically-induced stress corrosion cracking (AISCC) at ambient temperatures if hygroscopic salts such as MgCl2 or CaCl2 are present on the surface and the air relative humidity (RH) is in a critical range. This phenomenon has been responsible for incidents of rock climbing anchors breaking under minimal load in seaside areas, putting climbers lives at stake. A systematic failure analysis of anchors collected from various seaside locations throughout the world, namely from Portugal, Azores, Hong Kong, Taiwan, South Africa, and Australia, has been performed. Transgranular AISCC was proven the reason for failures in the majority of investigated anchors made of Type 304L stainless steel. Intergranular cracking due to sensitization by improper welding or heat treatment was also identified as a critical safety issue for both Types 304 and 316 stainless steel types. Comparison of literature data and climatic data from the failure locations suggests that limited washing of deposits in confined zones together with elevated temperature and low RH generated locally by direct sunshine are the key factors of AISCC initiation and ultimately of anchor failure.

2007 ◽  
Vol 353-358 ◽  
pp. 3031-3034
Author(s):  
Rong Rong Zhou ◽  
Jian Ming Gong ◽  
Feng Li ◽  
Shan Tung Tu

Stress corrosion cracking (SCC) of austenitic stainless steel serviced in aggressive environment often occurs in power, petrochemical industry, and leads to premature equipment failure and great economic loss. This paper focuses on the problem of the SCC on the 304L stainless steel nozzle of a hydrogenation reactor, which is caused due to on-line alkali cleaning. Susceptibility for SCC was evaluated by Slow Strain Rate Test (SSRT) for as-rolled and sensitized 304L stainless steel in low concentration sodium hydroxide solution with high temperature. The effects of different strain rates, different concentration of sodium hydroxide and different solution temperatures on SCC were investigated. On the basis of this, the contrast tests were also performed in high temperature pure water. After SSRT, fractograph of the fractured specimens was analyzed by using scanning electron microscopy (SEM).


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