Visible-Light-Mediated Transformation of Nitrogen-Containing Compounds Based on Single Electron Transfer

The phenolate anion was developed as a new photocatalyst with strong reduction potentials (−3.16 V vs. SCE) to reduction of aryl halides to aryl radicals through single electron transfer.

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ChemInform Abstract: Chemo-, Regio-, and Stereoselective Trifluoromethylation of Styrenes via Visible Light-Driven Single-Electron Transfer (SET) and Triplet-Triplet Energy Transfer (TTET) Processes.

ChemInform ◽

10.1002/chin.201516063 ◽

2015 ◽

Vol 46 (16) ◽

pp. no-no

Author(s):

Qing-Yu Lin ◽

Xiu-Hua Xu ◽

Feng-Ling Qing

Keyword(s):

Electron Transfer ◽

Energy Transfer ◽

Visible Light ◽

Single Electron ◽

Single Electron Transfer ◽

Triplet Energy ◽

Visible Light Driven ◽

Triplet Energy Transfer

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Recent application of visible-light induced radicals in C–S bond formation

RSC Advances ◽

10.1039/d0ra03086d ◽

2020 ◽

Vol 10 (34) ◽

pp. 20046-20056 ◽

Cited By ~ 2

Author(s):

Vishal Srivastava ◽

Pravin K. Singh ◽

Arjita Srivastava ◽

Praveen P. Singh

Keyword(s):

Electron Transfer ◽

Visible Light ◽

Organic Compounds ◽

High Efficiency ◽

Bond Formation ◽

Single Electron ◽

Single Electron Transfer ◽

Recent Application

The sulphur centered radicals, produced from various organic compounds, in high efficiency by single-electron-transfer (SET) oxidation.

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Visible Light-Promoted Photocatalytic C-5 Carboxylation of 8-Aminoquinoline Amides and Sulfonamides via a Single Electron Transfer Pathway

The Journal of Organic Chemistry ◽

10.1021/acs.joc.9b00942 ◽

2019 ◽

Vol 84 (16) ◽

pp. 9869-9896 ◽

Cited By ~ 7

Author(s):

Chiranjit Sen ◽

Tapan Sahoo ◽

Harshvardhan Singh ◽

Eringathodi Suresh ◽

Subhash Chandra Ghosh

Keyword(s):

Electron Transfer ◽

Visible Light ◽

Single Electron ◽

Single Electron Transfer ◽

Electron Transfer Pathway

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Visible-light-induced phenylchalcogenyl-oxygenation of allenes having aryl or electron withdrawing substituents with ambient air as a sole oxidant

Organic & Biomolecular Chemistry ◽

10.1039/c6ob02033j ◽

2016 ◽

Vol 14 (48) ◽

pp. 11415-11425 ◽

Cited By ~ 7

Author(s):

Gullapalli Kumaraswamy ◽

Swargam Vijaykumar ◽

Kukkadapu Ankamma ◽

Vykunthapu Narayanarao

Keyword(s):

Electron Transfer ◽

Visible Light ◽

Transfer Process ◽

Stereoselective Synthesis ◽

Ambient Air ◽

Single Electron ◽

Single Electron Transfer ◽

Electron Transfer Process ◽

Electron Withdrawing Substituents

The stereoselective synthesis of α-phenylselenyl- or telluryl β-aryl acrylaldehydes/ketones from aryl allenes/1,3-diarylallene by an oxidative photo-induced single electron transfer process using benign ambient air as a sole oxidant was achieved.

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Single electron transfer-based peptide/protein bioconjugations driven by biocompatible energy input

Communications Chemistry ◽

10.1038/s42004-020-00413-x ◽

2020 ◽

Vol 3 (1) ◽

Author(s):

Yue Weng ◽

Chunlan Song ◽

Chien-Wei Chiang ◽

Aiwen Lei

Keyword(s):

Electron Transfer ◽

Visible Light ◽

Energy Input ◽

Limited Range ◽

Single Electron ◽

Single Electron Transfer ◽

Electrochemical Catalysis ◽

Future Developments ◽

Recent Developments ◽

Modified Peptides

AbstractBioconjugation reactions play a central facilitating role in engendering modified peptides and proteins. Early progress in this area was inhibited by challenges such as the limited range of substrates and the relatively poor biocompatibility of bioconjugation reagents. However, the recent developments in visible-light induced photoredox catalysis and electrochemical catalysis reactions have permitted significant novel reactivities to be developed in the field of synthetic and bioconjugation chemistry. This perspective describes recent advances in the use of biocompatible energy input for the modification of peptides and proteins mainly, via the single electron transfer (SET) process, as well as key future developments in this area.

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