Linear Carbon Chain Growth Reactions of Ruthenium Carbide Complexes

2021 ◽  
Vol 79 (12) ◽  
pp. 1136-1143
Author(s):  
Shin Takemoto ◽  
Hiroyuki Matsuzaka
Keyword(s):  
Carbon Chain ◽  
Chain Growth ◽  
Linear Carbon Chain

Carbon Chain Growth by Sequential Reactions of CO and CO2 with a Transition Metal Carbonyl Complex

2018 ◽  
Author(s):  
Richard Kong ◽  
Mark Crimmin
Keyword(s):  
Transition Metal ◽  
Metal Carbonyl ◽  
Carbon Chain ◽  
Chain Growth ◽  
Carbonyl Complex ◽  
Fischer Tropsch ◽  
Carbon Chains ◽  
Sequential Coupling ◽  
Energy Economy ◽  
Sequential Reactions

<i>The formation of carbon chains by the coupling of COx (X = 1 or 2) units on transition metals is a fundamental step relevant to Fischer-Tropsch catalysis. Fischer-Tropsch catalysis produces energy dense liquid hydrocarbons from synthesis gas (CO and H2) and has been a mainstay of the energy economy since its discovery nearly a century ago. Despite detailed studies aimed at elucidating the steps of catalysis, experimental evidence for chain growth (Cn to Cn+1 ; n > 2) from the reaction of CO with metal complexes is unprecedented. In this paper, we show that carbon chains can be grown from sequential reactions of CO or CO2 with a transition metal carbonyl complex. By exploiting the cooperative effect of transition and main group metals, we document the first example of chain propagation from sequential coupling of CO units (C1 to C3 to C4), along with the first example of incorporation of CO2 into the growing carbon chain.</i><br>

Carbon chain growth reaction of synthesis of lower olefins from syngas on Fe-Co catalyst

2020 ◽  
Vol 504 ◽  
pp. 144211
Author(s):  
Yingzhe Yu ◽  
Jie Zhang ◽  
Hao Lei ◽  
Minhua Zhang
Keyword(s):  
Carbon Chain ◽  
Chain Growth ◽  
Co Catalyst ◽  
Lower Olefins ◽  
Growth Reaction

Carbon chain growth by formyl coupling over the Cu/γ-AlOOH(001) surface in syngas conversion

2019 ◽  
Vol 21 (1) ◽  
pp. 148-159 ◽  
Author(s):  
Hui Bai ◽  
Mengmeng Ma ◽  
Bing Bai ◽  
Haojie Cao ◽  
Lin Zhang ◽  
...  
Keyword(s):  
Carbon Chain ◽  
Ethanol Conversion ◽  
Chain Growth ◽  
Syngas Conversion

Carbon chain growth in syngas-to-ethanol conversion over the Cu/γ-AlOOH(001) surface is mainly ascribed to formyl coupling.

Anionic Carbon Chain Growth in Reactions of ${{\rm{C}}}_{2}^{-}$, ${{\rm{C}}}_{4}^{-}$, ${{\rm{C}}}_{6}^{-}$, C2H−, C4H−, and C6H− with C2H2

2019 ◽  
Vol 878 (2) ◽  
pp. 162 ◽  
Author(s):  
Björn Bastian ◽  
Tim Michaelsen ◽  
Jennifer Meyer ◽  
Roland Wester
Keyword(s):  
Carbon Chain ◽  
Chain Growth

Density functional study of the metallization of a linear carbon chain inside single wall carbon nanotubes

Carbon ◽  
2010 ◽  
Vol 48 (14) ◽  
pp. 4057-4062 ◽  
Author(s):  
A. Tapia ◽  
L. Aguilera ◽  
C. Cab ◽  
R.A. Medina-Esquivel ◽  
R. de Coss ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Density Functional ◽  
Carbon Chain ◽  
Functional Study ◽  
Single Wall Carbon Nanotubes ◽  
Density Functional Study ◽  
Single Wall Carbon ◽  
Linear Carbon Chain

scholarly journals Colopsinols D and E, New Polyhydroxyl Linear Carbon Chain Compounds from Marine Dinoflagellate Amphidinium sp.

2000 ◽  
Vol 48 (10) ◽  
pp. 1447-1451 ◽  
Author(s):  
Takaaki KUBOTA ◽  
Masashi TSUDA ◽  
Miho TAKAHASHI ◽  
Masami ISHIBASHI ◽  
Seiko OKA ◽  
...  
Keyword(s):  
Carbon Chain ◽  
Marine Dinoflagellate ◽  
Chain Compounds ◽  
Linear Carbon Chain
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