scholarly journals Evaluation of properties, processes and modes of acid-base conditions on sod-podzolic soils

2021 ◽  
Vol 1 (43) ◽  
pp. 10-10
Author(s):  
Alexander Saakian ◽  
◽  

The paper offers an assessment of the acid-base state of soils, accounting for the interrelationships of properties, processes and modes. The information content of the assessment of the fractional composition of acid-base systems, the kinetics of the processes, the suspension effect, the buffer capacity in different pH ranges, the depositing ability of soils to ions that determine their acid-base state is shown. The optimal indicators of the acid-base state of soils are estimated using the feedback principles: introduction of elements into the soil suspension - analysis of the response of plants developing on this suspension by the parameters of photosynthesis - search for the extremum. It is shown that the change in soil acidity is largely due to the processes of complex formation, the effects of protonation and hydrate formation of complexes of organic ligands and polyvalent cations. The expediency of using water-soluble organic substances of decomposing plant residues to increase the solubility of CaCO3 and purposefully change the exchange constants H+, Fe2+, Mn2+, A13+ from the Soil Absorption Complex to the Ca2+ ion is shown. Shown that increased sod soil formation process leads to a migration of Ca, Mg, and K to the arable layer from underlying layers. Ca, Mg and K also transition from a non-exchange state to the exchange state that allows for an increase in the time between repeated rounds of liming of sod-podzolic soils. Keywords: SOIL ACIDITY, SOIL PROPERTIES PROCESSES AND MODES

2017 ◽  
Vol 21 (09) ◽  
pp. 611-621
Author(s):  
Hirofumi Konno ◽  
Jun Takeda

The synthesis, acid-base properties, and kinetics of Cu[Formula: see text] incorporation into water-soluble highly substituted porphyrins were studied. The basicity increased and the stepwise acid-base equilibrium was clarified by increasing the number of phenyl groups at the [Formula: see text] position, and the basicity of a dodeca-substituted porphyrin increased with the ionic strength. The metalation reaction of the dodeca-substituted porphyrin with Cu[Formula: see text] in aqueous solution revealed a biphasic absorbance change at 453 nm. Plots of [Formula: see text] or[Formula: see text] vs. the Cu[Formula: see text] concentration and of log ([Formula: see text] or[Formula: see text]/[Formula: see text] 0) vs. the ionic strength show that [Formula: see text] is dependent on the Cu[Formula: see text] concentration and ionic strength, while [Formula: see text] is independent of these parameters. These results confirm the stepwise metalation mechanism and the existence of an intermediate in aqueous solution, which is indicated by the biphasic absorbance change at 453 nm.


Author(s):  
Cornelius B. Bavoh ◽  
Bhajan Lal ◽  
Joel Ben-Awuah ◽  
Muhammad Saad Khan ◽  
Grace Ofori-Sarpong

2009 ◽  
Vol 23 (7) ◽  
pp. 3711-3715 ◽  
Author(s):  
Seong-Pil Kang ◽  
Yutaek Seo ◽  
Wonho Jang

1994 ◽  
Vol 715 (1 Natural Gas H) ◽  
pp. 561-563 ◽  
Author(s):  
CAROLYN A. KOH ◽  
ERICH A. MÜLLER ◽  
JOHN A. ZOLLWEG ◽  
KEITH E. GUBBINS ◽  
JEFFREY L. SAVIDGE

2012 ◽  
Vol 12 (21) ◽  
pp. 10239-10255 ◽  
Author(s):  
L. T. Padró ◽  
R. H. Moore ◽  
X. Zhang ◽  
N. Rastogi ◽  
R. J. Weber ◽  
...  

Abstract. Aerosol composition and mixing state near anthropogenic sources can be highly variable and can challenge predictions of cloud condensation nuclei (CCN). The impacts of chemical composition on CCN activation kinetics is also an important, but largely unknown, aspect of cloud droplet formation. Towards this, we present in-situ size-resolved CCN measurements carried out during the 2008 summertime August Mini Intensive Gas and Aerosol Study (AMIGAS) campaign in Atlanta, GA. Aerosol chemical composition was measured by two particle-into-liquid samplers measuring water-soluble inorganic ions and total water-soluble organic carbon. Size-resolved CCN data were collected using the Scanning Mobility CCN Analysis (SMCA) method and were used to obtain characteristic aerosol hygroscopicity distributions, whose breadth reflects the aerosol compositional variability and mixing state. Knowledge of aerosol mixing state is important for accurate predictions of CCN concentrations and that the influence of an externally-mixed, CCN-active aerosol fraction varies with size from 31% for particle diameters less than 40 nm to 93% for accumulation mode aerosol during the day. Assuming size-dependent aerosol mixing state and size-invariant chemical composition decreases the average CCN concentration overprediction (for all but one mixing state and chemical composition scenario considered) from over 190–240% to less than 20%. CCN activity is parameterized using a single hygroscopicity parameter, κ, which averages to 0.16 ± 0.07 for 80 nm particles and exhibits considerable variability (from 0.03 to 0.48) throughout the study period. Particles in the 60–100 nm range exhibited similar hygroscopicity, with a κ range for 60 nm between 0.06–0.076 (mean of 0.18 ± 0.09). Smaller particles (40 nm) had on average greater κ, with a range of 0.20–0.92 (mean of 0.3 ± 0.12). Analysis of the droplet activation kinetics of the aerosol sampled suggests that most of the CCN activate as rapidly as calibration aerosol, suggesting that aerosol composition exhibits a minor (if any) impact on CCN activation kinetics.


1965 ◽  
Vol 69 (6) ◽  
pp. 2044-2059 ◽  
Author(s):  
Norman M. Trieff ◽  
Benson R. Sundheim

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