scholarly journals Major processes of the dissolved cobalt cycle in the North and equatorial Pacific Ocean

2021 ◽  
Author(s):  
Rebecca Chmiel ◽  
Nathan Lanning ◽  
Allison Laubach ◽  
Jong-Mi Lee ◽  
Jessica Fitzsimmons ◽  
...  

Abstract. Over the past decade, the GEOTRACES and wider trace metal geochemical community have made substantial contributions towards constraining the marine cobalt (Co) cycle and its major biogeochemical processes. However, few Co speciation studies have been conducted in the North and equatorial Pacific Ocean, a vast portion of the world’s oceans by volume and an important endmember of deep thermohaline circulation. Dissolved Co (dCo) samples, including total dissolved and labile Co, were measured at-sea during the GEOTRACES Pacific meridional transect (GP15) along the 152° W longitudinal from 56° N to 20° S. Along this transect, upper ocean dCo was linearly correlated to dissolved phosphate (slope = 82 ± 2 µM:M) due to phytoplankton uptake and remineralization. As depth increased, dCo concentrations became increasingly decoupled from phosphate concentrations due to co-scavenging with manganese oxide particles in the mesopelagic. The transect revealed an organically-bound coastal source of dCo to the Alaskan Stream associated with low salinity waters. An intermediate-depth hydrothermal flux of dCo was observed off the Hawaiian coast at the Loihi Seamount, and the elevated dCo was correlated to estimated xs3He at and above the vent site; however, the Loihi Seamount likely did not represent a major source of Co to the Pacific basin. Elevated concentrations of dCo within oxygen minimum zones (OMZs) in the equatorial North and South Pacific were consistent with the suppression of oxidative scavenging, and we estimate that future deoxygenation could increase the OMZ dCo inventory by 13–28 % over the next century. In North Pacific Deep Water (NPDW), a fraction of elevated ligand-bound dCo appeared protected from scavenging by the high biogenic particle flux in the North Pacific basin. This finding is counter to previous expectations of low dCo concentrations in the deep Pacific due to scavenging over thermohaline circulation. Compared to a Co global biogeochemical model, the observed transect displayed more extreme inventories and fluxes of dCo than predicted by the model, suggesting a highly dynamic Pacific Co cycle.

2020 ◽  
Author(s):  
Baolan wu ◽  
Xiaopei lin ◽  
Lisan yu

<p><strong>The North Pacific Subtropical Mode Water (mode water hereafter) is a vertically homogeneous thermocline water mass, occupying the entire subtropical Western Pacific Ocean. By transporting mass, heat and nutrients from the surface into the subsurface ocean, it provides memory of climate variability and is a potential source of predictability. Previous studies attributed decadal variability of the mode water mean temperature to the Pacific Decadal Oscillation (PDO). Using available observations and reanalysis data, here we show that decadal to multi-decadal variability of the mode water mean temperature is controlled by the Atlantic Multi-Decadal Variability (AMV) instead. During an AMV positive phase, warm sea surface temperatures (SSTs) in the north Atlantic Ocean weaken the subtropical North</strong> <strong>Pacific westerlies, and the anomalous easterlies in the subtropical west Pacific drive an anomalous northward Ekman transport of warm water into the mode water formation area. </strong><strong>This increases the mode water temperature through subduction</strong><strong>, driving variability of the upper-layer ocean heat content and fish catches in the Northwestern Pacific. This mechanism is supported by a long pre-industrial model simulation with multiple AMV cycles and by a Pacemaker model experiment, in which the AMV forcing alone is shown to drive the variability of the mode water. Our finding suggests that the AMV is an important driver for decadal climate and ecosystem variability and provides memory for prediction in the Pacific Ocean.</strong></p>


1993 ◽  
Vol 50 (12) ◽  
pp. 2608-2625 ◽  
Author(s):  
William G. Pearcy ◽  
Joseph P. Fisher ◽  
Mary M. Yoklavich

Abundances of Pacific pomfret (Brama japonica), an epipelagic fish of the North Pacific Ocean, were estimated from gillnet catches during the summers of 1978–1989. Two size modes were common: small pomfret <1 yr old, and large fish ages 1–6. Large and small fish moved northward as temperatures increased, but large fish migrated farther north, often into the cool, low-salinity waters of the Central Subarctic Pacific. Lengths of small fish were positively correlated with latitude and negatively correlated with summer surface temperature. Interannual variations in the latitude of catches correlated with surface temperatures. Large catches were made in the eastern Gulf of Alaska (51–55°N) but modes of small pomfret were absent here, and large fish were rare at these latitudes farther to the west. Pomfret grow rapidly during their first two years of life. They are pectoral fin swimmers that swim continuously. They prey largely on gonatid squids in the region of the Subarctic Current in the Gulf of Alaska during summer. No evidence was found for aggregations on a scale ≤1 km. Differences in the incidence of tapeworm, spawning seasons, and size distributions suggest the possibility of discrete populations in the North Pacific Ocean.


1985 ◽  
Vol 23 (3) ◽  
pp. 403-416 ◽  
Author(s):  
Karen Rabek ◽  
Michael T. Ledbetter ◽  
Douglas F. Williams

Tephra in 31 piston cores from the western Gulf of Mexico and 7 piston cores from the equatorial Pacific were analyzed by electron microprobe. Six ash layers in the western Gulf of Mexico were easily distinguished by TiO2, FeO, and CaO contents and correlated by geochemistry in order to determine the distribution pattern for each ash layer. Correlation by geochemistry is an easier, more accurate method than biostratigraphic correlation; some of the tephras were miscorrelated by biostratigraphy. The six tephras were dated by geochemical identification in a piston core with oxygen-isotope stratigraphy and the ages are Y5 (30,000 yr B.P.), Y6 (65,000 yr B.P.), Y8 (84,000 yr B.P.), X2 (110,000 yr B.P.), W1 (136,000 yr B.P.), and W2 (185,000 yr B.P.). Data from this study corroborated correlations of the Y8 tephra in the western Gulf of Mexico with the D layer in the eastern equatorial Pacific Ocean. None of the other five layers in the Gulf of Mexico, however, were found in the Pacific Ocean. The limited distribution of the Y5, Y6, X2, and W2 ash layers close to Mexico indicates possible sources in Mexico. Tephra from the late Pleistocene La Primavera pumice in Mexico, however, does not correlate with the marine tephra.


2020 ◽  
Vol 17 (3) ◽  
pp. 813-831
Author(s):  
Lothar Stramma ◽  
Sunke Schmidtko ◽  
Steven J. Bograd ◽  
Tsuneo Ono ◽  
Tetjana Ross ◽  
...  

Abstract. A strong oxygen-deficient layer is located in the upper layers of the tropical Pacific Ocean and deeper in the North Pacific. Processes related to climate change (upper-ocean warming, reduced ventilation) are expected to change ocean oxygen and nutrient inventories. In most ocean basins, a decrease in oxygen (“deoxygenation”) and an increase in nutrients have been observed in subsurface layers. Deoxygenation trends are not linear and there could be multiple influences on oxygen and nutrient trends and variability. Here oxygen and nutrient time series since 1950 in the Pacific Ocean were investigated at 50 to 300 m depth, as this layer provides critical pelagic habitat for biological communities. In addition to trends related to ocean warming the oxygen and nutrient trends show a strong influence of the Pacific Decadal Oscillation (PDO) in the tropical and the eastern Pacific, and the North Pacific Gyre Oscillation (NPGO) in particular in the North Pacific. In the Oyashio Region the PDO, the NPGO, the North Pacific Index (NPI) and an 18.6-year nodal tidal cycle overlay the long-term trend. In most eastern Pacific regions oxygen increases and nutrients decrease in the 50 to 300 m layer during the negative PDO phase, with opposite trends during the positive PDO phase. The PDO index encapsulates the major mode of sea surface temperature variability in the Pacific, and oxygen and nutrients trends throughout the basin can be described in the context of the PDO phases. El Niño and La Niña years often influence the oxygen and nutrient distribution during the event in the eastern tropical Pacific but do not have a multi-year influence on the trends.


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