scholarly journals Ionic Liquid as Green Solvent for Ring-Opening Graft Polymerizaion of ε-Caprolactone onto Hemicelluloses

10.5772/59679 ◽  
2015 ◽  
Author(s):  
X.Q. Zhang ◽  
M.J. Chen ◽  
H.H. Wang ◽  
X.X. Wen ◽  
C.F. Liu ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Ring Opening ◽  
Green Solvent

scholarly journals Ring Opening in Epoxy, Propoxy Carbazole with Various Amines Using Ionic Liquid as Green Solvent

2014 ◽  
Vol 2 (3) ◽  
pp. 40-52
Author(s):  
G V R Sharma ◽  
M. Veerraghava Reddy ◽  
G. Omprakash ◽  
K. Tatendra Reddy
Keyword(s):  
Ionic Liquid ◽  
Ring Opening ◽  
Green Solvent

scholarly journals Task specific ionic liquid as solvent, catalyst and reagent for regioselective ring opening of epoxides in water

2019 ◽  
Vol 12 (8) ◽  
pp. 2098-2103 ◽  
Author(s):  
Eshagh Rezaee Nezhad ◽  
Sami Sajjadifar ◽  
Fariba Heidarizadeh ◽  
Saaid Karimian
Keyword(s):  
Ionic Liquid ◽  
Ring Opening ◽  
Ring Opening Of Epoxides ◽  
Task Specific Ionic Liquid

A Simple N-Substitution of Pyrrole and Indole Using Basic Ionic Liquid [BmIm][OH] as Catalyst and Green Solvent

Heterocycles ◽  
2009 ◽  
Vol 78 (8) ◽  
pp. 2013 ◽  
Author(s):  
Zhang-Gao Le ◽  
Tao Zhong ◽  
Zong-Bo Xie ◽  
Jian-Ping Xu
Keyword(s):  
Ionic Liquid ◽  
Green Solvent ◽  
Basic Ionic Liquid

scholarly journals Effects of Immobilized Ionic Liquid on Properties of Biodegradable Polycaprolactone/LDH Nanocomposites Prepared by In Situ Polymerization and Melt-Blending Techniques

Nanomaterials ◽  
2020 ◽  
Vol 10 (5) ◽  
pp. 969
Author(s):  
Sonia Bujok ◽  
Jiří Hodan ◽  
Hynek Beneš
Keyword(s):  
Ionic Liquid ◽  
Water Vapor ◽  
Ring Opening ◽  
In Situ Polymerization ◽  
High Capacity ◽  
Barrier Properties ◽  
Melt Blending ◽  
Water Vapor Barrier ◽  
Double Hydroxides

The high capacity of calcinated layered double hydroxides (LDH) to immobilize various active molecules together with their inherent gas/vapor impermeability make these nanoparticles highly promising to be applied as nanofillers for biodegradable polyester packaging. Herein, trihexyl(tetradecyl)phosphonium decanoate ionic liquid (IL) was immobilized on the surface of calcinated LDH. Thus, the synthesized nanoparticles were used for the preparation of polycaprolactone (PCL)/LDH nanocomposites. Two different methods of nanocomposite preparation were used and compared: microwave-assisted in situ ring opening polymerization (ROP) of ε-caprolactone (εCL) and melt-blending. The in situ ROP of εCL in the presence of LDH nanoparticles with the immobilized IL led to homogenous nanofiller dispersion in the PCL matrix promoting formation of large PCL crystallites, which resulted in the improved mechanical, thermal and gas/water vapor barrier properties of the final nanocomposite. The surface-bonded IL thus acted as nanofiller surfactant, compatibilizer, as well as thermal stabilizer of the PCL/LDH nanocomposites. Contrary to that, the melt-blending caused a partial degradation of the immobilized IL and led to the production of PCL nanocomposites with a heterogenous nanofiller dispersion having inferior mechanical and gas/water vapor barrier properties.

scholarly journals Correction: Epoxide ring-opening reaction promoted by ionic liquid reactivity: interplay of experimental and theoretical studies

2019 ◽  
Vol 9 (22) ◽  
pp. 6532-6532
Author(s):  
Shengxin Chen ◽  
Guixiang Zeng ◽  
Yingwei Li ◽  
Bin He ◽  
Ruixia Liu ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Ring Opening ◽  
Epoxide Ring ◽  
Theoretical Studies ◽  
Epoxide Ring Opening ◽  
Ring Opening Reaction ◽  
Experimental And Theoretical Studies

Correction for ‘Epoxide ring-opening reaction promoted by ionic liquid reactivity: interplay of experimental and theoretical studies’ by Shengxin Chen et al., Catal. Sci. Technol., 2019, DOI: 10.1039/c9cy00953a.

Dispute over designating an ionic liquid as a green solvent

2015 ◽  
Vol 273 ◽  
pp. 668 ◽  
Author(s):  
Swapnil L. Fegade ◽  
Jason P. Trembly
Keyword(s):  
Ionic Liquid ◽  
Green Solvent

Novel generation of nano-structured supramolecular solvents based on an ionic liquid as a green solvent for microextraction of some synthetic food dyes

2018 ◽  
Vol 42 (23) ◽  
pp. 19252-19259 ◽  
Author(s):  
Qamar Salamat ◽  
Yadollah Yamini ◽  
Morteza Moradi ◽  
Meghdad Karimi ◽  
Mahsa Nazraz
Keyword(s):  
Ionic Liquid ◽  
Environmentally Friendly ◽  
Green Solvent ◽  
Food Dyes

A new, fast, and environmentally friendly supra molecular solvent was introduced for extraction of three synthetic food dyes in foodstuff samples.

Organotin-bridged ionic liquid as a solvent-free, leaching-resistive catalyst for ring opening polymerization of ε-caprolactone

2019 ◽  
Vol 43 (15) ◽  
pp. 5872-5878 ◽  
Author(s):  
Asmaa Bouyahya ◽  
Sébastien Balieu ◽  
Redouane Beniazza ◽  
Mustapha Raihane ◽  
Abdelkrim El Kadib ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Solvent Free ◽  
Biologically Relevant ◽  
The Way

An easy synthesis provides a monoalkyltin trichloride grafted onto an ionic liquid. The catalyst paves the way to nontoxic biologically relevant materials.

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