scholarly journals Progress in Ionic Liquids as Reaction Media, Monomers and Additives in High-Performance Polymers

Author(s):  
Dan He ◽  
Zhengping Liu ◽  
Liyan Huang
2018 ◽  
Vol 20 (11) ◽  
pp. 2481-2485 ◽  
Author(s):  
Francisco G. Cirujano ◽  
Maxime Stalpaert ◽  
Dirk E. De Vos

High performance reusable catalysts and reaction media are evaluated for the green alkylation of indoles with alcohols under mild and solvent-free conditions.


Author(s):  
Sengshiu Chung ◽  
Peggy Cebe

We are studying the crystallization and annealing behavior of high performance polymers, like poly(p-pheny1ene sulfide) PPS, and poly-(etheretherketone), PEEK. Our purpose is to determine whether PPS, which is similar in many ways to PEEK, undergoes reorganization during annealing. In an effort to address the issue of reorganization, we are studying solution grown single crystals of PPS as model materials.Observation of solution grown PPS crystals has been reported. Even from dilute solution, embrionic spherulites and aggregates were formed. We observe that these morphologies result when solutions containing uncrystallized polymer are cooled. To obtain samples of uniform single crystals, we have used two-stage self seeding and solution replacement techniques.


Author(s):  
A. L. Rusanov ◽  
L. G. Komarova ◽  
M. P. Prigozhina ◽  
V. A. Tartakovsky ◽  
S. A. Shevelev ◽  
...  

2020 ◽  
Vol 17 (4) ◽  
pp. 450-464
Author(s):  
Mohammad Javaherian ◽  
Seyyed Jafar Saghanezhad

Dicationic ionic liquids are an emerging group of Ionic Liquids (ILs) that are currently receiving much attention as green reaction media and catalysts. Because of a great number of possible combinations of cations and anions, the physical and chemical properties of dicationic ionic liquids are more tunable and broader than monocationic ILs. Therefore, their unique properties have made them the target of many applied and fundamental researches. Actually, dicationic ionic liquids are more effective and rather fascinating than traditional monocationic ILs. So, due to greater versatility and diversity, their applications in organic synthesis have been extensively grown. In this review, we have focused on the synthesis, characterization and applications of dicationic ionic liquids, especially, in organic synthesis.


2020 ◽  
Vol 27 (6) ◽  
pp. 2195-2202
Author(s):  
El Hadji Ndongo Diaw ◽  
Severine Le Roy ◽  
Gilbert Teyssedre ◽  
Eddy Aubert

2011 ◽  
Vol 217-218 ◽  
pp. 1606-1610
Author(s):  
Dong Jiang ◽  
Xiao Ran Zhang ◽  
Yan Mei Ma ◽  
Cheng You Ma

A series of random polysulfone/polyethersulfone (PSF/PES) copolymers were synthesized by the polycondensation of 4, 4'-isopropylidendiphenol, 4, 4΄-dihyolroxy diphenyl sulfone and 4, 4'-dichlorodiphenyl sulfone in the presence of K2CO3. We obtained a series of copolymers by changing the molar ratio of 4, 4΄-dihyolroxy diphenyl sulfone and 4, 4'-isopropylidendiphenol (it was marked as the ratio of S:A). The copolymers have the similar solubility with polyethersulfone. They also have high glass transition temperatures (Tg: 199°C~229°C) and 5% weight loss temperatures (4, 4'-isopropylidendiphenol: 4, 4΄-dihyolroxy diphenyl sulfone=1:1, Td5=497°C). At the same time the elongation at break is much higher than that of PES, while the tensile strength is a little lower than that of PES.


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