scholarly journals RESEARCH OF POSSIBILITY OF USING CHEMICAL METHOD OF FINE METAL PARTICLES REDUCTION FOR BACTERICIDAL SORBENTS PRODUCTION

2020 ◽  
Vol 63 (3) ◽  
pp. 46-53
Author(s):  
Еlena A. Farberova ◽  
Anastasia Yu. Katysheva ◽  
Elena A. Tingaeva ◽  
Sergey A. Smirnov ◽  
Andrey G. Starostin
Keyword(s):  
Ascorbic Acid ◽  
Specific Surface ◽  
Porous Structure ◽  
Active Carbon ◽  
Metal Particles ◽  
Carbon Fabric ◽  
Copper Particles ◽  
Bactericidal Properties ◽  
Fine Metal Particles ◽  
Fine Copper

The present paper is concerned with a research of sorption and bactericidal properties of the fine metal particles applied on the surface of active carbon fabric by chemical sedimentation method. The ascorbic acid and natrium borane were used in the study process as metals, copper and silver reducing agents. Influence of reducer and fine metal nature onto the porous structure, as well as bactericidal and sorption characteristics of obtained fibrous sorbent samples are shown. It is determined that use of ascorbic acid for synthesis of copper and silver fine particles on the active carbon fabrics surface leads to the considerable decrease in a specific surface and volumes of meso - and micropores of the obtained sorbent in comparison with initial active carbon fabric. When using the natrium borane as reducer of fine copper particles the decrease in a specific surface and volumes of sorption pores is also observed. However, when using the natrium borane, the active carbon fabric samples modified with silver particles or with their composition with fine copper particles, had the higher values of porous structure main characteristics in comparison with the initial active carbon fabric. The nature of distribution of fine metal particles at the active carbon fabric surface was investigated by the electronic microscopy method. It was found that during the chemical reduction process the particles of fine copper attached to active carbon fabric fibers, being almost evenly distributed at all surface of fabric. Particles of silver were located as crystal congestions along fibers. Sorption and bactericidal properties of the received samples of modified active carbon fabrics are investigated. Their high sensitivity to microorganism cells which remains during a long storage period is demonstrated. Herewith, the active carbon fabric, modified with particles of fine copper and silver, keeps high sorption properties.

scholarly journals High MB Solution Degradation Efficiency of FeSiBZr Amorphous Ribbon with Surface Tunnels

Materials ◽  
2020 ◽  
Vol 13 (17) ◽  
pp. 3694 ◽  
Author(s):  
Qi Chen ◽  
Zhicheng Yan ◽  
Hao Zhang ◽  
Lai-Chang Zhang ◽  
Haijian Ma ◽  
...  
Keyword(s):  
Specific Surface ◽  
Porous Structure ◽  
Surface Area ◽  
Free Volume ◽  
Specific Surface Area ◽  
Degradation Rate ◽  
High Efficiency ◽  
Amorphous Ribbon ◽  
Degradation Efficiency ◽  
Characteristic Distance

The as spun amorphous (Fe78Si9B13)99.5Zr0.5 (Zr0.5) and (Fe78Si9B13)99Zr1 (Zr1) ribbons having a Fenton-like reaction are proved to bear a good degradation performance in organic dye wastewater treatment for the first time by evaluating their degradation efficiency in methylene blue (MB) solution. Compared to the widely studied (Fe78Si9B13)100Zr0 (Zr0) amorphous ribbon for degradation, with increasing cZr (Zr atomic content), the as-spun Zr0, Zr0.5 and Zr1 amorphous ribbons have gradually increased degradation rate of MB solution. According to δc (characteristic distance) of as-spun Zr0, Zr0.5 and Zr1 ribbons, the free volume in Zr1 ribbon is higher Zr0 and Zr0.5 ribbons. In the reaction process, the Zr1 ribbon surface formed the 3D nano-porous structure with specific surface area higher than the cotton floc structure formed by Zr0 ribbon and coarse porous structure formed by Zr0.5 ribbon. The Zr1 ribbon’s high free volume and high specific surface area make its degradation rate of MB solution higher than that of Zr0 and Zr0.5 ribbons. This work not only provides a new method to remedying the organic dyes wastewater with high efficiency and low-cost, but also improves an application prospect of Fe-based glassy alloys.

scholarly journals Tribofilms Produced by Supply of Fine Metal Particles in Vacuum

2011 ◽  
Vol 6 (1) ◽  
pp. 50-54
Author(s):  
Hirotaka Kato ◽  
Akihiro Takimi ◽  
Minoru Umemoto
Keyword(s):  
Metal Particles ◽  
Fine Metal Particles

scholarly journals Synthesis of Au-decorated three-phase-mixed TiO2/phosphate modified active carbon nanocomposites as easily-recycled efficient photocatalysts for degrading high-concentration 2,4-DCP

RSC Advances ◽  
2019 ◽  
Vol 9 (66) ◽  
pp. 38414-38421 ◽  
Author(s):  
Sharafat Ali ◽  
Zhijun Li ◽  
Wajid Ali ◽  
Ziqing Zhang ◽  
Mingzhuo Wei ◽  
...  
Keyword(s):  
Specific Surface ◽  
Surface Area ◽  
Specific Surface Area ◽  
Active Carbon ◽  
Charge Separation ◽  
High Concentration ◽  
Carbon Nanocomposites ◽  
Three Phase

Au decorated three-phase-mixed nanosized TiO2 coupled with phosphate-treated AC as recyclable nanocomposite photocatalysts exhibit excellent photoactivity for degrading high-concentration 2, 4-DCP, mainly due to the improved charge separation and specific surface area.

Fabrication of an N-doped mesoporous bio-carbon electrocatalyst efficient in Zn–air batteries by an in situ gas-foaming strategy

2019 ◽  
Vol 55 (100) ◽  
pp. 15117-15120 ◽  
Author(s):  
Hong Wang ◽  
Wei Li ◽  
Zhiwei Zhu ◽  
Yijuan Wang ◽  
Pan Li ◽  
...  
Keyword(s):  
Specific Surface ◽  
Porous Structure ◽  
Surface Area ◽  
Specific Surface Area ◽  
Electrocatalytic Activity ◽  
High Specific Surface Area ◽  
Carbon Catalyst ◽  
Gas Foaming

An N-doped bio-carbon catalyst with a hierarchical interconnected macro/meso-porous structure and high specific surface area exhibited significantly enhanced electrocatalytic activity.

Preparation of nanocrystalline copper by electrodeposition

1997 ◽  
Vol 12 (10) ◽  
pp. 2719-2724 ◽  
Author(s):  
S. Bandyopadhyay ◽  
D. Chakravorty
Keyword(s):  
Mie Theory ◽  
Composite Films ◽  
Dip Coating ◽  
Metal Particles ◽  
Electrodeposition Process ◽  
Copper Particles ◽  
Glass Slides ◽  
Polystyrene Matrix ◽  
Dip Coating Technique ◽  
Absorption Characteristics

Copper particles of sizes in the range 3.1 to 11.4 nm have been grown within gel compositions of the system CuO–SiO2 by an electrodeposition process applying voltages varying from 5 to 15 V. Composite films of these metal particles dispersed in a polystyrene matrix have been prepared on Corning No. 7059 glass slides by a dip-coating technique and their optical absorption characteristics have been delineated. The spectra show maxima at wavelengths in the range 380 to 470 nm, depending on the particle size. The results have been analyzed using the Mie theory. The electrical conductivity as extracted from this analysis is found to have reasonable correspondence with data reported earlier for copper nanoparticles in glass-ceramic systems.

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