scholarly journals Rapid, paced garnet growth in blueschists from Lu-Hf dating of laser-cut domains combined with trace-element mapping

2021 ◽  
Author(s):  
Lorraine Tual ◽  
Matthijs Smit ◽  
Jamie Cutts ◽  
Ellen Kooijman ◽  
Melanie Kielman-Schmitt ◽  
...  
2021 ◽  
Author(s):  
Lorraine Tual ◽  
Matthijs Smit ◽  
Jamie Cutts ◽  
Ellen Kooijman ◽  
Melanie Kielman-Schmitt ◽  
...  

<p>Unravelling the timing and rate of subduction-zone metamorphism requires linking the composition of petrogenetic indicator minerals in blueschists and eclogites to time. Garnet is a key mineral in this regard, not in the least because it best records P-T conditions and changes therein and can be dated, using either Lu-Hf or Sm-Nd chronology. Bulk-grain garnet ages are the norm and can provide important and precise time constraints on reactions across both facies. Domain dating, i.e., dating of individual growth zones, moves beyond that. Domain dating by combining mechanical micro-milling and Sm-Nd chronology yielded important constraints on garnet-growth and fluid-release rates for blueschists (e.g., Dragovic et al., 2015). Developing this method for Lu-Hf chronology and, importantly, for "common-sized" garnet (≤1 cm) provides an important opportunity to further explore the potential of this approach.</p><p>We combined a low-loss micro-sampling technique in laser cutting with a refined Lu-Hf routine to precisely date multiple growth zones of a sub-cm-sized garnet in a blueschist. The targeted grain from a glaucophane-bearing micaschist from Syros Island, Greece, was chemically characterized by major- and trace-element mapping (EPMA, LA-ICPMS) and five zones were extracted using a laser mill. The three core and inner mantle zones are chemically comparable and identical in age within a 0.1 Myr precision (2σ). The outer two zones are chemically distinct and are resolvably younger (0.2-0.8 Myr). The timing of these two major garnet-growth episodes, together with the variations in trace-element chemistry, constrain important fluid-release reactions, such as chloritoid-breakdown. The data show that the integral history of garnet growth in subduction zones may be extremely short (<1 Myr), but may, even in that short timeframe, consist of multiple short pulses. Garnet-forming reactions clearly are localized and, thus, associated with focussed high-flux fluid flow. Beyond subduction-zone processes, our new protocol for zoned garnet Lu-Hf geochronology of "common-sized" garnet opens possibilities for constraining the causes and rates of garnet growth and in turn, the pace of tectonic processes in general.</p><p> </p><p><sub><em>Dragovic, B., Baxter, E.F. and Caddick, M.J., 2015. Pulsed dehydration and garnet growth during subduction revealed by zoned garnet geochronology and thermodynamic modeling, Sifnos, Greece. Earth and Planetary Science Letters, 413, pp.111-122.</em></sub></p>


2021 ◽  
Author(s):  
Daniela Rubatto ◽  
Lanari Pierre ◽  
Marcel Burger ◽  
Bodo Hattendorf ◽  
Gunnar Schwarz ◽  
...  

<p>Garnet is one of the most robust and ubiquitous minerals that record element zoning during crustal metamorphism. In addition to major element distribution, zoning in trace elements can provide a wealth of information to document the changing conditions of garnet growth and modification. Trace element distribution in garnet grains was mapped in 2D in thin section with laser ablation inductively coupled plasma time of flight mass spectrometry (LA-ICP-TOFMS) and conventional LA-ICP-MS to achieve a lateral resolution of 15-5 µm and limits of detection for the heavy rare earth elements (REE) down to 0.2 µg/g (Rubatto et al. 2020).</p><p>In granulite-facies garnet, major elements show diffusional resetting, whereas trace elements still largely document the growth history. Enrichment of trace elements in the garnet mantle is attributed to the consumption of biotite (V, Cr) and the dissolution of zircon (Zr) and monazite (Y+REE) in the coexisting melt. Lu is notably enriched in the garnet mantle with implications for geochronology. The gradual zoning of Y+HREE between mantle and core is reconcilable with diffusion over ~200 µm in 10 My at temperatures of 750–800°C</p><p>In amphibolite facies garnet, Y+REE trace element zoning closely matches the growth zoning in Ca with no notable diffusive modification. Y+REE zoning is dominated by Rayleigh fractionation in the core and in the outer zones it shows annuli that mark the sporadic breakdown of accessory phases.</p><p>Garnet in eclogite facies samples that underwent fluid-rock interaction show growth zoning in major and trace elements, with local oscillations and sectors. In certain samples, the overall distribution of REE can be reconciled with diffusion-limited uptake. Where garnet displays fluid-related veinlets, visible in major elements, that cross-cut the primary growth zoning, the regular Y+REE and Cr growth zoning is not affected by the veinlets. This indicates that the veinlets did not form by a crack-seal mechanism but are rather related to a selective replacement process.</p><p> </p><p><strong>References </strong></p><p>Rubatto D, Burger M, Lanari P, Hattendorf B, Schwarz G, Neff C, Keresztes Schmidt P, Hermann J, Vho A, Günther D (2020) Identification of growth mechanisms in metamorphic garnet by high-resolution trace element mapping with LA-ICP-TOFMS. Contrib Mineral Petrol 175:61 doi.org/10.1007/s00410-020-01700-5</p>


2019 ◽  
Vol 114 (1) ◽  
pp. 67-92 ◽  
Author(s):  
H. A. Berkenbosch ◽  
C.E.J. de Ronde ◽  
C. G. Ryan ◽  
A. W. McNeill ◽  
D. L. Howard ◽  
...  

Author(s):  
Marta Sánchez de la Torre ◽  
Anikó Angyal ◽  
Zsófia Kertész ◽  
Stéphan Dubernet ◽  
François-Xavier Le Bourdonnec ◽  
...  

2021 ◽  
Author(s):  
Matthijs Smit ◽  
Carl Guilmette ◽  
Melanie Kielman-Schmitt ◽  
Ellen Kooijman ◽  
Erik Scherer ◽  
...  

2009 ◽  
Vol 38 (2) ◽  
pp. 89-94 ◽  
Author(s):  
S. Matsuyama ◽  
M. Shimura ◽  
H. Mimura ◽  
M. Fujii ◽  
H. Yumoto ◽  
...  

1999 ◽  
Vol 5 (S2) ◽  
pp. 630-631
Author(s):  
J. Fournelle ◽  
C. Davidson ◽  
F. Spear ◽  
M. Kohn ◽  
H. Guo

A strength of the modern electron microprobe is its ability to provide 2D compositional information about materials. These images give the ability to observe features that might otherwise pass unseen. Elements at the trace element level are generally ignored due to the high detection limits imposed by mapping under “standard” EMP conditions.Trace element mapping requires beam regulation at high (e.g. 300 nA) to very high (e.g. 3 μA) faraday cup currents, reliable beam and stage control, and suitable samples and mounting media. The ability to operate at high accelerating voltage to maximize Pk2/Bkg is desirable (Robinson and Graham, 1992), although we have encountered column difficulties above 25-30 kV.We are mapping trace and minor elements including Y, Sc, P, Cr, Mn, Ca, in garnets. Fig. 1 shows Y, Sc and Cr maps (Spear and Kohn, 1996; Kohn, Spear and Valley, 1997), and Fig. 2 Y and Sc maps (Cameron, unpub. data), produced with a Cameca SX51.


2020 ◽  
Vol 61 (8) ◽  
Author(s):  
Lukáš Ackerman ◽  
Jana Kotková ◽  
Renata Čopjaková ◽  
Jiří Sláma ◽  
Jakub Trubač ◽  
...  

Abstract The Lu–Hf isotope system and Sr–Nd–Hf–Os isotope systematics of mantle rocks are capable of unravelling the early processes in collision belts, especially in a hot subduction context where the Sm–Nd and U–Pb systems in crustal rocks are prone to resetting owing to high temperatures and interaction with melts during exhumation. To improve models of the Devonian–Carboniferous evolution of the Bohemian Massif, we investigated in detail mafic and ultramafic rocks (eclogite, pyroxenite, and peridotite) from the ultrahigh-pressure and ultrahigh-temperature Kutná Hora Crystalline Complex (KHCC: Úhrov, Bečváry, Doubrava, and Spačice localities). Petrography, multiphase solid inclusions, major and trace element compositions of rocks and minerals, and radiogenic isotopic data document contrasting sources and protoliths as well as effects of subduction-related processes for these rocks. The Úhrov peridotite has a depleted composition corresponding to the suboceanic asthenospheric mantle, whereas Bečváry and Doubrava peridotites represent lithospheric mantle that underwent melt refertilization by basaltic and SiO2-undersaturated melts, respectively. Multiphase solid inclusions enclosed in garnet from Úhrov and Bečváry peridotites represent trapped H2O ± CO2-bearing metasomatizing agents and Fe–Ti-rich melts. The KHCC eclogites either formed by high-pressure crystal accumulation from mantle-derived basaltic melts (Úhrov) or represent a fragment of mid-ocean ridge basalt-like gabbroic cumulate (Spačice) and crustal-derived material (Doubrava) both metamorphosed at high P–T conditions. The Lu–Hf age of 395 ± 23 Ma obtained for the Úhrov peridotite reflects garnet growth related to burial of the asthenospheric mantle during subduction of the oceanic slab. By contrast, Spačice and Doubrava eclogites yield younger Lu–Hf ages of ∼350 and 330 Ma, respectively, representing mixed ages as demonstrated by the strong granulite-facies overprint and trace element zoning in garnet grains. We propose a refined model for the Early Variscan evolution of the Bohemian Massif starting with the subduction of the oceanic crust (Saxothuringian ocean) and associated oceanic asthenospheric mantle (Úhrov) beneath the Teplá–Barrandian at ≥380 Ma, which was responsible for melt refertilization of the associated mantle wedge (Bečváry, Doubrava). This was followed by continental subduction (∼370–360 Ma?) accompanied by the oceanic slab break-off and incorporation of the upwelling asthenospheric mantle into the Moldanubian lithospheric mantle and subsequent coeval exhumation of mantle and crustal rocks at ∼350–330 Ma.


Sign in / Sign up

Export Citation Format

Share Document