Fabrication of Cu2SnS3solar cells by screen-printing and high-pressure sintering process

2014 ◽  
Vol 53 (5S1) ◽  
pp. 05FW01 ◽  
Author(s):  
Takeshi Nomura ◽  
Tsuyoshi Maeda ◽  
Takahiro Wada
Author(s):  
E. F. Koch

Because of the extremely rigid lattice structure of diamond, generating new dislocations or moving existing dislocations in diamond by applying mechanical stress at ambient temperature is very difficult. Analysis of portions of diamonds deformed under bending stress at elevated temperature has shown that diamond deforms plastically under suitable conditions and that its primary slip systems are on the ﹛111﹜ planes. Plastic deformation in diamond is more commonly observed during the high temperature - high pressure sintering process used to make diamond compacts. The pressure and temperature conditions in the sintering presses are sufficiently high that many diamond grains in the sintered compact show deformed microtructures.In this report commercially available polycrystalline diamond discs for rock cutting applications were analyzed to study the deformation substructures in the diamond grains using transmission electron microscopy. An individual diamond particle can be plastically deformed in a high pressure apparatus at high temperature, but it is nearly impossible to prepare such a particle for TEM observation, since any medium in which the diamond is mounted wears away faster than the diamond during ion milling and the diamond is lost.


2006 ◽  
Vol 518 ◽  
pp. 189-194 ◽  
Author(s):  
A. Bykov ◽  
G. Oleynik ◽  
A. Ragulya ◽  
I. Timofeeva ◽  
L. Klochkov ◽  
...  

The high pressure sintering process of nanocrystalline diamond powder was studied. The influence of the liquid phase on the base of boron oxide was analyzed. The mechanism of cooperative-diffusive coalescence, which acts during sintering of ultradisperse diamond powders, is proposed.


2013 ◽  
Vol 1538 ◽  
pp. 179-183 ◽  
Author(s):  
Feng Gao ◽  
Tsuyoshi Maeda ◽  
Takahiro Wada

ABSTRACTWe fabricated Cu2ZnSn(SxSe1-x)4 (CZTSSe) solar cells by a printing and high-pressure sintering (PHS) process. First, the CZTSSe solid solution powders were synthesized by heating the elemental mixtures at 550oC for 5 h in an N2 gas atmosphere. We fabricated CZTSSe films by a printing and high-pressure sintering (PHS) process. The obtained dense CZTSSe film was post-annealed at 550oC for 10 min under an N2 +5% H2S gas atmosphere. We fabricated CZTSSe solar cells with the device structure of Ag/ITO/i-ZnO/CdS/CZTSSe/Mo/soda-lime glass. The CZTSSe solar cell showed an efficiency of 2.1%, with Voc of 272 mV, Jsc of 18.0 mA/cm2 and FF of 0.44.


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