Carbonaceous Adsorbent Derived from Sulfur-Impregnated Heavy Oil Ash and Its Lead Removal Ability from Aqueous Solution

A novel carbonaceous adsorbent was prepared from sulfur-impregnated heavy oil ash via pyrolysis using potassium sulfide (K2S) solution, and its ability to remove lead (Pb2+) from aqueous solutions was examined. It was compared with an adsorbent synthesized by conventional pyrolysis using potassium hydroxide (KOH) solution. Specifically, the raw ash was immersed in 1 M K2S solution or 1 M KOH solution for 1 day and subsequently heated at 100–1000 °C in a nitrogen (N2) atmosphere. After heating for 1 h, the solid was naturally cooled in N2 atmosphere, and subsequently washed and dried to yield the product. Regardless of the pyrolysis temperature, the product generated using K2S (Product-K2S) has a higher sulfur content than that obtained using KOH (Product-KOH). Moreover, Product-K2S has a higher lead removal ability than Product-KOH, whereas the specific surface area of the former is smaller than that of the latter. Product-K2S obtained at 300 °C (Product-K2S-300) achieves the highest lead adsorption and a high selective lead removal from a ternary Pb2+–Cu2+–Zn2+ solution. The equilibrium capacity of Product-K2S-300 was found to fit the Langmuir model better than the Freundlich model, and its calculated maximum adsorption capacity is 0.54 mmol/g. From the ternary Pb2+–Cu2+–Zn2+ solution, the order of adsorption by Product-K2S-300 is Pb2+ > Cu2+ > Zn2+, and the removal of Pb2+ and Cu2+ increases as the pH of the solution increases.

Ring-opening/annulation reaction of cyclopropyl ethanols: concise access to thiophene aldehydes via C–S bond formation

The synthesis of thiophene aldehydes from easily available cyclopropyl ethanol derivatives and potassium sulfide has been developed.

A catalyst-free and additive-free method for the synthesis of benzothiazolethiones from o-iodoanilines, DMSO and potassium sulfide

Under catalyst-free and additive-free conditions, a novel, convenient, environment-friendly method for the synthesis of benzothiazolethiones from o-iodoanilines, K2S and DMSO has been developed.

Green carbon disulfide surrogateviaa combination of potassium sulfide and chloroform for benzothiazine-thione and benzothiazole-thione construction

An efficient and green carbon disulfide surrogateviafacile combination of potassium sulfide and chloroform has been developed.

Copper-catalyzed synthesis of 2-acylbenzo[b]thiophenes from 3-(2-iodophenyl)-1-arylpropan-1-ones and potassium sulfide under aerobic conditions

A method was developed for the synthesis of 2-acylbenzo[b]thiophenes via a copper-catalyzed sulfuration of 3-(2-iodophenyl)-1-arylpropan-1-ones with K2S.

Copper-catalyzed highly selective synthesis of 2-benzyl- and 2-benzylidene-substituted benzo[b]thiazinones from 2-iodophenylcinnamamides and potassium sulfide

DBU as a switch could control the selectivity of the formation of 2-benzyl-substituted benzo[b]thiazinones and 2-benzylidenebenzo[b]thiazinones.