Changes in Optical Properties of Azopolymers in an Electric Field

We report the preliminary results obtained for polymers incorporating the azobenzene side-group as an optically active molecule. The reversible change of the thin film absorption is observed when illuminating it with monochromatic linearly polarized light under the applied external DC field. The magnotude of a change depends on the angle between the light polarization and the DC electric field direction.

Stimuli-Responsive Particle-Based Amphiphiles as Active Colloids Prepared by Anisotropic Click Chemistry

Amphiphiles alter the energy of surfaces, but the extent of this feature is typically constant. Smart systems with amphiphilicity as a function of an external, physical trigger are desirable. As a trigger, the exposure to a magnetic field, in particular, is desired because it is not shielded in water. Amphiphiles like surfactants are well known, but the magnetic response of molecules is typically weak. Vice-versa, magnetic particles with strong response to magnetic triggers are fully established in nanoscience, but they are not amphiphilic. In this work colloids with Janus architecture and ultra-small dimensions (25nm) have been prepared by spatial control over the Thiol-Yne click modification of organosilica-magnetite core-shell nanoparticles. The amphiphilic properties of these anisotropically modified particles are proven. Finally, a pronounced and reversible change in interfacial stabilization results from the application of a weak (<<1T) magnetic field.

Stimuli-Responsive Particle-Based Amphiphiles as Active Colloids Prepared by Anisotropic Click Chemistry

Amphiphiles alter the energy of surfaces, but the extent of this feature is typically constant. Smart systems with amphiphilicity as a function of an external, physical trigger are desirable. As a trigger, the exposure to a magnetic field, in particular, is desired because it is not shielded in water. Amphiphiles like surfactants are well known, but the magnetic response of molecules is typically weak. Vice-versa, magnetic particles with strong response to magnetic triggers are fully established in nanoscience, but they are not amphiphilic. In this work colloids with Janus architecture and ultra-small dimensions (25nm) have been prepared by spatial control over the Thiol-Yne click modification of organosilica-magnetite core-shell nanoparticles. The amphiphilic properties of these anisotropically modified particles are proven. Finally, a pronounced and reversible change in interfacial stabilization results from the application of a weak (<<1T) magnetic field.

Photoactivation of CdSe Quantum Nanoplatelet Luminescence-=SUP=-*-=/SUP=-

The impact of irradiation with higher and lower quantum energy than that corresponding to the fundamental absorption band of CdSe nanoplatelets has been studied. We show that the irradiation wavelength and oxygen strongly influence the photoluminescence of nanoplatelets. We demonstrate also that irradiation of CdSe nanoplatelets dry layers leads to a reversible change in their photoluminescence quantum yield. Keywords: semiconductor nanoplatelet, excitonic luminescence, trap states, intermittent irradiation.