Polariton Ring Currents and Circular Dichroism of Mg-porphyrin in a Chiral Cavity

By placing a Mg-porphyrin molecule in a chiral optical cavity, time reversal symmetry is broken, thus generating polariton ring currents even with linearly polarized light. These currents induce a circular...

Cobalt porphyrin intercalation into zirconium phosphate layers for electrochemical water oxidation

A cobalt porphyrin molecule, namely CoTcPP (TcPP = the dianion of meso-tetra(4-carboxyphenyl)porphyrin), is intercalated into zirconium phosphate (ZrP) layers as an effective way to heterogenize a porphyrin-based molecular electrocatalyst.

Molecular self-assembly of porphyrin and BODIPY chromophores connected with diphenylalanine moieties

In this study, a series of diphenylalanine tetra-substituted porphyrin derivatives were synthesized and their self-assembly ability was extensively studied. Apart from investigating the impact of incorporating many peptide moieties onto a porphyrin molecule; another perspective was investigated as well, namely the connection of two different chromophore entities (porphyrin and BODIPY) onto the same diphenylalanine molecule. Interestingly, various supra-molecular nanostructures were observed depending on the solvent mixture as well as the protecting group of the peptides, namely spheres, plaques and fibrils. The obtained self-assemblies were studied via UV-vis absorption and emission spectroscopies. Mainly red shifting was observed, indicating the formation of [Formula: see text]-aggregates in the self-assembled state. However, in one case a blue shifted UV-vis spectrum was obtained suggesting the formation of [Formula: see text]-type aggregates. Concerning the porphyrin-diphenylalanine-BODIPY derivative, additional fluorescence studies were performed in order to examine a possible interaction between the two chromophores in the excited state. Indeed, the emission measurements indicated that upon photo-excitation of the BODIPY entity, a very efficient energy or electron transfer process takes place from the BODIPY molecule to the porphyrin macrocycle.