Semi-Intrinsic Luminescence in Marine Organisms

Light emission is widespread in the oceans, with over three quarters of all observed marine species exhibiting bioluminescence. Several organisms such as the copepod Metridia pacifica and the ostracod Vargula hilgendorfii have been proven to synthesise their luciferin and luciferase to facilitate light emission. However, many luminescent species lack the capability to do this and instead it is possible that they acquire some of the components for their luminescence through predation or filter feeding on organisms that produce luciferins or precursors to these molecules. This has resulted in many organisms using certain luciferins, such as coelenterazine, as their substrate without possessing a clear mechanism to synthesise these. This chapter will review several examples of these semi-intrinsic luminescent systems and how the substrates and enzymes can be obtained for these reactions. Moreover, it will look at why particular luciferins, such as coelenterazine, are more widespread and utilised in this manner compared to other substrates.

Intrinsic luminescence blinking from plasmonic nanojunctions

Plasmonic nanojunctions, consisting of adjacent metal structures with nanometre gaps, can support localised plasmon resonances that boost light matter interactions and concentrate electromagnetic fields at the nanoscale. In this regime, the optical response of the system is governed by poorly understood dynamical phenomena at the frontier between the bulk, molecular and atomic scales. Here, we report ubiquitous spectral fluctuations in the intrinsic light emission from photo-excited gold nanojunctions, which we attribute to the light-induced formation of domain boundaries and quantum-confined emitters inside the noble metal. Our data suggest that photoexcited carriers and gold adatom - molecule interactions play key roles in triggering luminescence blinking. Surprisingly, this internal restructuring of the metal has no measurable impact on the Raman signal and scattering spectrum of the plasmonic cavity. Our findings demonstrate that metal luminescence offers a valuable proxy to investigate atomic fluctuations in plasmonic cavities, complementary to other optical and electrical techniques.

Clustering-triggered Emission of Poly(vinyl) Alcohol

Numerous polymers without traditional chromophores show novel fluorescent properties and wide application prospect. This concept is referred to as non-traditional intrinsic luminescence (NTIL). Most polymers show aggregation-induced emission (AIE) characteristics....

Non-Traditional Intrinsic Luminescence from Non-Conjugated Polymer Dots: Designing a Hybrid Biomaterial

Herein, an eco-friendly and facile synthesis of the nitrogen-contain non-conjugated polymer dots (NCPD) with optimal blue emission is reported from the biopolymer β-glucan in a peptide-polysaccharide linkage (namely NH2-β-glucan). The...