Petrography and Geochemistry of Dolomites of Samanasuk Formation, Dara Adam Khel Section, Kohat Ranges, Pakistan

Replacement dolomite occurs in Jurassic Samanasuk Formation in Dara Adam khel area of Kohat ranges, North-Western Himalayas, Pakistan. This study, for the first time, document the process of dolomitization and evolution of strata bound dolomitic bodies. Field investigation, petrography and geochemistry helped in unraveling the formation of several dolomitic bodies. Petrographically dolomites comprises of: (1) medium grain crystalline planer subhedral dolomite (Dol-I); (2) fine grained crystalline anhedral non-planer dolomite rhombs (Dol-II); (3) medium to coarse grained crystalline subhedral-anhedral non-planer dolomite (Dol-III) and coarse to very coarse grained crystalline saddle dolomite cements (SD). The saddle dolomites (SD) postdate the replacement dolomites and precede telogenetic calcite (TC) cements. Stable O and C isotope analysis shows that these dolomites have δ18Ovpdb ranging from -4.09% to -10.4 whereas the δ13Cvpdb ranges from +0.8 to +2.51. Major and trace elements data show that Sr concentrations of 145.5 to 173 ppm; Fe contents of 2198 to 8215 ppm; and Mn contents of 93.5 to 411 ppm. Petrographically replacive dolomites, saddle dolomite, and δ18Ovpdb values depicts neomorphism of replacement dolomites that were formed earlier were exposed to late dolomitizing fluids. As a result of basin uplift during the Himalayan orogeny in Eocene time, dolomitization event was stopped through occurrence of meteoric water. The Main Boundary Thrust (MBT) and its splays were most likely essential conduits that channelized dolomitizing fluids from siliciclastic rocks that were buried deeply into the Jurassic carbonates rocks, leading to more extreme dolomitization.

Substrate type and palaeodepth do not affect the Middle Jurassic taxonomic diversity of crinoids

Crinoids are largely considered as good indicators for determining environmental conditions. They are robust proxies for inferring changes in salinity and sedimentation rate and for inferring substrate type. Some crinoid groups (e.g., certain comatulids, cyrtocrinids, millericrinids) have a depth preference, thus, making them useful for palaeodepth estimation. The hypotheses that crinoid distribution is substrate-dependent (rock type) or palaeodepth-dependent is tested here based on (a) archival Bathonian-Callovian (Middle Jurassic) crinoid occurrences from Poland and (b) newer finds from five boreholes from eastern Poland. Qualitative data suggests that isocrinids and cyclocrinids occur in both carbonate and siliciclastic rocks. The cyrtocrinids and roveacrinids occur within carbonate rocks, whereas the comatulids are exclusive to siliciclastics. In terms of palaeodepth, most crinoid groups dominate in shallow environments with the sole exception of cyrtocrinids, that are ubiquitous and occur in both shallow (near shore and shallow marine) and slightly deeper (deeper sublittoral to open shelf) settings. The occurrences of the cosmopolitan taxa, Chariocrinus andreae and Balanocrinus subteres (isocrinids), is independent of both substrate type and palaeodepth. Quantitative analyses (Analysis Of Variance; ANOVA) based on substrate type, i.e., substrate-dependency (claystones, sandstones and limestones), and palaeodepth i.e., palaeodepth-dependency (near shore, shallow-marine, mid-ramp and offshore), corroborate qualitative results. Statistical analysis suggest that the distribution of crinoids shows a strong substrate-dependency but not for palaeodepth, although very weak significance (low p value) is noted for near shore and shallow marine settings and crinoid distribution.

Stratigraphic and structural control over permeability distribution in poorly consolidated siliciclastic rocks

Permeability models are very relevant for the characterization of oil systems. However, limitations related to the resolution of seismic data make it difficult to identify subseismic, sedimentary, and tectonic structures, which can significantly impact the flow pattern. This study analyzed the spatial variability of permeability according to stratigraphic and structural geology control to propose a useful model for poorly consolidated, fractured, and faulted siliciclastic reservoirs. In an outcrop analogue to this type of reservoir, air permeability was measured in 3 orthogonal directions at 24 points, spaced 2 m apart.The models were obtained by sequential Gaussian simulation (SGS) after statistical data treatment. The models were validated to ensure the consistency of the generated scenarios. Permeability values showed a positive asymmetric distribution and reduced medians toward tectonic structures. The fitted semivariogram model was exponential, with higher spatial continuity in the horizontal flow direction and lower in the vertical one. The permeability models emphasized the importance of considering subseismic structures in the flow analysis of reservoirs since they have proven to play a significant role in the permeability distribution in the outcrop assessed.

Metal Sources in the Proterozoic Vazante-Paracatu Sediment-Hosted Zn District, Brazil: Constraints from Pb Isotope Compositions of Meta-Siliciclastic Units

ABSTRACT Different types of sediment-hosted whole-rock Pb isotope (206Pb/204Pb, 207Pb/204Pb, 208Pb/204Pb) compositions were determined from phyllites, carbonaceous phyllites (>1% TOC), and meta-litharenites belonging to the Serra do Garrote Formation, which is part of the Proterozoic Vazante Group, Brazil. Results were integrated with lithogeochemistry in order to identify the Pb isotopic signature of Zn enrichment (up to 0.24 wt.% Zn) associated with meta-siliciclastic-hosted sulfide mineralization that formed prior to the Brasiliano Orogeny (850 to 550 Ma) in order to (1) understand the nature of siliciclastic sediment sources, (2) identify possible metal sources in pre-orogenic meta-siliciclastic-hosted Zn mineralization, and (3) evaluate the genetic links between the Zn enrichment in the relatively reduced phyllite package, and different styles of syn-orogenic Zn ± Pb mineralization (hypogene Zn-silicate and Zn-Pb sulfide) in overlying dolomitic carbonates throughout the Vazante-Paracatu Zn District, Brazil. The whole-rock 206Pb/204Pb and 207Pb/204Pb isotope ratios of meta-siliciclastic rocks plot as positively sloping, sub-parallel arrays with radiogenic, upper continental crust compositions, which could represent a detrital contribution from at least two upper continental crust sources. However, the 206Pb/204Pb versus 207Pb/204Pb isotope system does not distinguish between Zn-enriched samples and un-mineralized samples. In the whole-rock 206Pb/204Pb–208Pb/204Pb plot, Zn-enriched samples form a flat trend of lower 208Pb/204Pb values (38.3 to 39.5) compared to the Zn-poor ones that follow common upper crustal trends. Zinc-enriched samples have low whole-rock Th/U values (<4) and higher whole-rock U concentrations compared to unmineralized samples. These support the hypothesis that U (± Pb) was added by pre-orogenic metalliferous fluids, which were in turn derived from underlying Paleoproterozoic and Archean basement rocks. Due to U addition, the original whole-rock thorogenic and uranogenic Pb isotope systems were decoupled in mineralized samples. Pre-orogenic metalliferous fluids have similar present-day first-order characteristics, including: (1) relatively high U/Pb and (2) low Th/U values, when compared to galena in the major carbonate-hosted Zn ± Pb deposits (Vazante, Morro Agudo, Ambrosia, Fagundes) in the Vazante Group. These results support the hypothesis that Zn-rich layers and veins in mineralized carbonaceous phyllites could be linked to the same origins as carbonate-hosted mineral deposits throughout the Vazante Basin, but further data are warranted. We suggest that the tectonic evolution of the Vazante Basin saw multiple phases of Zn-rich mineralization over protracted time periods from around 1200 to 550 Ma.

Lacustrine Slope-Related Soft-Sediment Deformation Structures in the Cretaceous Gyeokpori Formation, Buan Area, SW Korea, and Volcanism-Induced Seismic Shocks as Their Possible Trigger

The Gyeokpori Formation in the Buan volcanic area primarily contains siliciclastic rocks interbedded with volcanoclastics. These sediments are characterized by a variety of soft-sediment deformation structures (SSDS). The SSDS in the Gyeokpori Formation are embedded in poorly sorted conglomerates; slump folds are also present in the formation. The deformation mechanisms and triggers causing the deformation are not yet clear. In the present study, the trigger of the SSDS in the Gyeokpori Formation was investigated using facies analysis. This included evaluation of the reworking process of both cohesive and non-cohesive sediments. The analysis indicates that the SSDS are directly or indirectly associated with the alternation of conglomerates and mud layers with clasts. These layers underwent non-cohesive and cohesive deformation, respectively, which promoted SSDS formation. The slump folds were controlled by the extent of cohesive and non-cohesive deformation experienced by the sediment layers in the slope environment. The SSDS deformation style and morphology differ, particularly in the case of reworking by slump activity. This study contributes to the understanding of lacustrine slope-related soft-sediment deformation structures.

Stratigraphy of the Khuvsgul Group, Mongolia

The Khuvsgul Group (Khuvsgul Province, Mongolia) is a Late Neoproterozoic to Cambrian carbonate-dominated succession that includes minor glacial diamictite and one of the largest known ore-grade phosphate deposits in the world. These strata, which have experienced low-grade metamorphism, are exposed in the Khoridol-Saridag Range on the western margin of Lake Khuvsgul. Since 2017, new geologic mapping and field studies have been conducted in the Khuvsgul region. During the course of this work, it has become necessary to restructure the stratigraphic framework of the Khuvsgul Group in order to better facilitate geologic mapping, stratigraphic observations, and regional correlations. We have divided the lower Khuvsgul Group into four distinct formations spanning the Cryogenian and Ediacaran, each of which encompass strata associated with the Sturtian glaciation, Cryogenian non-glacial interlude, Marinoan glaciation, and basal Ediacaran transgression respectively. The phosphorites of the Khuvsgul Group are now included within a new distinct formation, while the overlying Cambrian carbonates and siliciclastic rocks have been further subdivided to streamline mapping and correlation efforts. The stratigraphic framework outlined below will simplify identification and differentiation of Khuvsgul Group rocks in the field and provide a foundation for the interpretation of Khuvsgul Group strata within the context of the changing climatic, tectonic, and paleoenvironmental conditions of the late Neoproterozoic and early Cambrian.

Preliminary Map Showing Quaternary Geology of the Franklin 7.5-Minute Quadrangle, Indiana

The Franklin 7.5-minute quadrangle is situated near the maximum limit of Wisconsin Episode glacial deposits insoutheastern Johnson County. Till of Wisconsin Episode age (Trafalgar Formation) dominates the surficial geology of thequadrangle. Areas of Wisconsin Episode outwash (Atherton Formation) are found in the Sugar Creek, Youngs Creek, andHurricane Creek valleys and within former meltwater pathways not occupied by modern streams. Kame deposits (sand andgravel) are found in the northern half of the quadrangle and are part of a larger kame complex present in central JohnsonCounty. Holocene (post-glacial) alluvium is found in the valleys of Sugar, Youngs, Nineveh, Buckhart, and Ray Creeks andtributaries. Unconsolidated sediment thickness generally increases from southwest to northeast across the quadrangle, fromless than 15 ft along the southwestern margin of the quadrangle to over 200 ft thick in the far northeastern corner of thequadrangle. This transition of bedrock topography represents the buried northern end of the Knobstone Escarpment. Twosignificant bedrock paleovalleys exist in the quadrangle, one in the south-central part of the quadrangle which parallels theburied Knobstone Escarpment and one in the northeast corner of the quadrangle which is part of a large bedrock valleyextending north into Marion County. The Quaternary sediments in the western half of the quadrangle are underlain byMississippian Borden Group siliciclastic rocks. In the eastern half of the quadrangle, the Devonian New Albany Shale andMuscatatuck Group carbonate rocks subcrop under thick Quaternary sediment cover. The Wisconsin Episode maximumlimit is located within one mile south of the southern boundary of the quadrangle. Radiocarbon ages from the adjacentTrafalgar 7.5-minute quadrangle indicate the Laurentide Ice Sheet reached its maximum extent just after 23,700 years ago. Asecond glacial limit, marked by the Crawfordsville Moraine in the adjacent Trafalgar 7.5-minute quadrangle,crosses the southern end of the Franklin 7.5-minute quadrangle, albeit diffuse. The Crawfordsville Moraine represents thelimit of a readvance which occurred 21,700 years ago. This preliminary geologic map is an interim geologic map product thatdocuments progress in mapping the Quaternary geology of Johnson County, Indiana. The lithologic classification of theQuaternary units of Indiana was used in assigning map units.

Biostratigraphy and paleoenvironment of Maastrichtian foraminiferal assemblages from a succession located NW of Tuxtla Gutiérrez, Chiapas (SE Mexico)

During the Maastrichtian, two lithostratigraphic units were deposited in the central Chiapas region; the Ocozocoautla and Angostura formations. The first unit crops out northwest of the city of Tuxtla Gutiérrez in central Chiapas. It is a complex lithological unit mainly composed of siliciclastic rocks interbedded with limestone. Overlying it, the Angostura limestone is recognized. This study focuses on a taxonomic study of the larger benthic and planktic foraminifera from both formations in order to assign age and to infer the paleoenviroment. The Ocozocoautla Formation includes an association of benthic as well as significant planktic foraminifera. Based on the microfossils stratigraphic distribution, two biozones were defined: the Pseudorbitoides rutteni–Ayalaina rutteni Assemblage Zone of earliest Maastrichtian and the upper part of the Gansserina gansseri Interval Zone of early Maastrichtian. The Angostura Formation contains dasycladacean algae and larger foraminifera considered as important age markers in shallow-water environments. Two foraminiferal interval zones were defined, Praechubbina breviclaustra Interval Zone of early late Maastrichtian and Chubbina jamaicensis Total Range Zone of late to latest Maastrichian age. The microfacies (grainstone, wackestone–packstone, wackestone) as well as the foraminiferal assemblage enable the paleoenvironment to be reconstructed, suggesting a deposit that developed in an open-water marine setting with moderate to high energy, characterized by benthic and planktic foraminifera in the Ocozocoautla Formation, while in the Angostura Formation a shallow-water marine protected environment is inferred. The paleobiogeographical distribution of the assemblage from both the Ocozocoautla and Angostura formations mostly contains endemic benthic foraminifera of the Caribbean Province and other few Tethysian forms of the Angostura Formation.