By analyzing the risk assessment methods of roof accidents at home and abroad, this paper summarizes the research status of risk assessment in this area, and analyzes the significance of risk assessment of mine roof accidents. The risk identification of roadway collapse accident is carried out from four aspects -- human, material, environment, and management, and the risk evaluation index system is established, including human unsafe behavior, material unsafe state, management factors and environmental factors. On this basis, the weight of index set is determined by grey relation analysis, and the fuzzy comprehensive evaluation model is obtained by combining the fuzzy comprehensive evaluation method. Taking a coal mine as an example, this paper makes an empirical study of risk assessment and puts forward corresponding countermeasures according to the results of comprehensive assessment. The results show that the safety level of the mine is very safe, so it is feasible to use the grey fuzzy comprehensive evaluation method to evaluate the safety of the mine, which can provide reference for the same kind of mine.