sulfate complex
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Author(s):  
Bhisham Narayan Singh ◽  
Vivek Veeresh ◽  
Sarada Prasanna Mallick ◽  
Shivam Sinha ◽  
Amit Rastogi ◽  
...  

2020 ◽  
Vol 73 (6) ◽  
pp. 511
Author(s):  
Graham A. Bowmaker ◽  
Yang Kim ◽  
Brian W. Skelton ◽  
Alexandre N. Sobolev ◽  
Allan H. White

Single crystal X-ray structure determinations have been executed for several title compounds of the mononuclear form [LMX2], namely [(bpy)ZnX2], X=Cl, Br; [(phen)ZnX2], X=Cl, Br, I (bpy=2,2′-bipyridine; phen=1,10-phenanthroline). Also reported are the crystal structures of ZnSO4/bpy/H2O (1:1:5) (≡ [(bpy)Zn(OH2)4](SO4)·H2O) and Zn(NO3)2/bpy/H2O (1:1:3) (≡ [(bpy)Zn(OH2)3(ONO2)](NO3)). The sulfate complex completes the array [LM(OH2)4]2+, L=bpy, phen, M=Zn, Cd, while the nitrate is the first nitrate example for [LM(OH2)3(OX)](+) (OX=ONO2, OSO3). In all examples of the sulfate and nitrate forms here and previously defined, the metal atoms are six-coordinate, with any anionic donors lying in axial coordination sites (i.e. M–O (quasi-) normal to the LM plane). The structures of [LHg(SCN)2] (L=phen, tpy) (tpy=2,2′:6′,2′-terpyridine), [(tpy)(CdBr2], and [Zn(tpy)2](NO3)2·2H2O are also recorded.


2019 ◽  
Vol 14 (1) ◽  
pp. 40-51 ◽  
Author(s):  
Zar Chi Soe ◽  
Bijay Kumar Poudel ◽  
Hanh Thuy Nguyen ◽  
Raj Kumar Thapa ◽  
Wenquan Ou ◽  
...  

2018 ◽  
Vol 107 (12) ◽  
pp. 3134-3142 ◽  
Author(s):  
Linfeng Wu ◽  
Wu Chen ◽  
Feng Li ◽  
Brian R. Morrow ◽  
Franklin Garcia-Godoy ◽  
...  

2018 ◽  
Vol 51 (11) ◽  
pp. 970-974 ◽  
Author(s):  
E. A. Shakhno ◽  
T. A. Savitskaya ◽  
D. D. Grinshpan ◽  
T. G. Pokrovskaya ◽  
V. I. Yakushev ◽  
...  

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