Organic matter characteristics of a rapidly eroding permafrost cliff in NE Siberia (Lena Delta, Laptev Sea region)

Organic carbon (OC) stored in Arctic permafrost represents one of Earth’s largest and most vulnerable terrestrial carbon pools. Amplified climate warming across the Arctic results in widespread permafrost thaw. Permafrost deposits exposed at river cliffs and coasts are particularly susceptible to thawing processes. Accelerating erosion of terrestrial permafrost along shorelines leads to increased transfer of organic matter (OM) to nearshore waters. However, the amount of terrestrial permafrost carbon and nitrogen as well as the OM quality in these deposits are still poorly quantified. Here, we characterise the sources and the quality of OM supplied to the Lena River at a rapidly eroding permafrost river shoreline cliff in the eastern part of the delta (Sobo-Sise Island). Our multi-proxy approach captures bulk elemental, molecular geochemical and carbon isotopic analyses of late Pleistocene Yedoma permafrost and Holocene cover deposits, discontinuously spanning the last ~52 ka. We show that the ancient permafrost exposed in the Sobo-Sise cliff has a high organic carbon content (mean of about 5 wt%).We found that the OM quality, which we define as the intrinsic potential to further transformation, decomposition, and mineralization, is also high as inferred by the lipid biomarker inventory. The oldest sediments stem from Marine Isotope Stage (MIS) 3 interstadial deposits (dated to 52 to 28 cal kyr BP) and is overlaid by Last Glacial MIS 2 (dated to 28 to 15 cal ka BP) and Holocene MIS 1 (dated to 7–0 cal ka BP) deposits. The relatively high average chain length (ACL) index of n-alkanes along the cliff profile indicates a predominant contribution of vascular plants to the OM composition. The elevated ratio of iso and anteiso-branched FAs relative to long chain (C ≥ 20) n-FAs in the interstadial MIS 3 and the interglacial MIS 1 deposits, suggests stronger microbial activity and consequently higher input of bacterial biomass during these climatically warmer periods. The overall high carbon preference index (CPI) and higher plant fatty acid (HPFA) values as well as high C / N ratios point to a good quality of the preserved OM and thus to a high potential of the OM for decomposition upon thaw. A decrease of HPFA values downwards along the profile probably indicates a relatively stronger OM decomposition in the oldest (MIS 3) deposits of the cliff. The characterisation of OM from eroding permafrost leads to a better assessment of the greenhouse gas potential of the OC released into river and nearshore waters in future, which is important to understand the consequences of a warming climate in Arctic environments on the global carbon cycle.

Middle Stone Age Bifacial Technology and Pressure Flaking at the MIS 3 Site of Toumboura III, Eastern Senegal

Over the past decade, the increasing wealth of new archaeological data on the Middle Stone Age (MSA) in Senegal and Mali has broadened our understanding of West Africa’s contributions to cultural developments. Within the West African sequence, the phase of Marine Isotope Stage 3 (MIS 3, ca. 59-24 ka) yielded so far the best known and extensive archaeological information. The site of Toumboura III encompasses an occupation dated by optically stimulated luminescence (OSL) to between 40 ± 3 ka and 30 ± 3 ka. It provides the largest, well-dated, and stratified lithic assemblage in West Africa for the MSA and sheds light on an unprecedented cultural expression for this period, adding to the notable diversity of the late MSA in this region. We conducted a technological analysis of the lithic components following the chaîne opératoire approach. The lithic assemblage features a prevalence of bifacial technology and the exploitation of flakes as blanks for tool production. The craftspeople manufactured distinct types of bifacial tools, including small bifacial points shaped by pressure technique. The new data from Toumboura III demonstrate behavioral patterns that are entirely new in the region. By revealing behavioral innovations and technological particularities, these results on the techno-cultural dynamics during the MIS 3 phase of the MSA enhance our understanding of the complex Pleistocene population history in this part of Africa.

The Ice-Rich Permafrost Sequences as a Paleoenvironmental Archive for the Kara Sea Region (Western Arctic)

The Kara Sea coast and part of the shelf are characterized by wide presence of the ice-rich permafrost sequences containing massive tabular ground ice (MTGI) and ice wedges (IW). The investigations of distribution, morphology and isotopic composition of MTGI and IW allows paleoenvironmental reconstructions for Late Pleistocene and Holocene period in the Kara Sea Region. This work summarizes result of long-term research of ice-rich permafrost at eight key sites located in the Yamal, Gydan, Taimyr Peninsulas, and Sibiryakov Island. We identified several types of ground ice in the coastal sediments and summarized data on their isotopic and geochemical composition, and methane content. We summarized the available data on particle size distribution, ice chemical composition, including organic carbon content, and age of the enclosing ice sediments. The results show that Quaternary sediments of the region accumulated during MIS 5 – MIS 1 and generally consisted of two main stratigraphic parts. Ice-rich polygenetic continental sediments with syngenetic and epigenetic IW represent the upper part of geological sections (10–15 m). The IW formed in two stages: in the Late Pleistocene (MIS 3 – MIS 2) and in the Holocene cold periods. Oxygen isotope composition of IW formed during MIS 3 – MIS 2 is on average 6‰ lower than that of the Holocene IW. The saline clay with rare sand layers of the lower part of geological sections, formed in marine and shallow shelf anaerobic conditions. MTGI present in the lower part of the sections. The MTGI formed under epigenetic freezing of marine sediments immediately after sea regression and syngenetic freezing of marine sediments in the tidal zone and in the conditions of shallow sea.

Was there a glacial outburst flood in the Torngat Mountains during Marine Isotope Stage 3?

We report previously unpublished evidence for a Marine Isotope Stage 3 (MIS 3; 60–26 ka) glacial outburst flood in the Torngat Mountains (northern Quebec/Labrador, Canada). We present 10Be cosmogenic exposure ages from legacy fieldwork for a glacial lake shoreline with evidence for outburst flooding in the Torngat Mountains, with a minimum age of 36 ± 3 ka (we consider the most likely age, corrected for burial, to be ~56 ± 3 ka). This shoreline position and age can potentially constrain the Laurentide Ice Sheet margin in the Torngat Mountains. This region, considered a site of glacial inception, has no published dated geologic constraints for high-elevation MIS 3 ice margins. We estimate the freshwater flux associated with the inferred glacial outburst flood using high-resolution digital elevation maps corrected for glacial isostatic adjustment. Using assumptions about the ice-dammed locations we find that a freshwater flood volume of 1.14 × 1012 m3 could have entered the Hudson Strait. This glacial outburst flood volume could have contributed to surface ocean freshening to cause a measurable meltwater signal in δ18O records, but would not necessarily have been associated with substantial ice rafted debris. Future work is required to refine estimates of the size and timing of such a glacial outburst flood. Nevertheless, we outline testable hypotheses about the Laurentide Ice Sheet and glacial outburst floods, including possible implications for Heinrich events and glacial inception in North America, that can be assessed with additional fieldwork and cosmogenic measurements.

Stratigraphy And Paleolithic Landscapes of the Beganchik Site at the Kama-Volga Confluence

The Beganchik locality is a stratigraphic sequence of loessic deposits, pedogenic horizons and Paleolithic occupations located at the Kama-Volga confluence. The sequence is exposed on a bluff formed on the west side of an erosional remnant between the Kuybyshev Reservoir and the former channel of the Aktay River. Although the site is known for its Terminal Paleolithic-Mesolithic occupations of the Pleistocene-Holocene transition, evidence of older occupations and remains of fauna has been identified. Our research team identified evidence of human presence associated with a pedogenic horizon of MIS 3 age. Two AMS radiocarbon ages from a hearth produced ages around 47 000 years BP. Pollen and phytoliths from two soils horizons, including the one associated with the hearths indicate a steppe environment coincident with the formation of correlative soils elsewhere in the Russian Plain.

New Evidence of MIS 3 Relative Sea Level Changes from the Messina Strait, Calabria (Italy)

Investigation of sea-level positions during the highly-dynamic Marine Isotope Stage 3 (MIS 3: 29–61 kyrs BP) proves difficult because: (i) in stable and subsiding areas, coeval coastal sediments are currently submerged at depths of few to several tens of meters below the present sea level; (ii) in uplifting areas, the preservation of geomorphic features and sedimentary records is limited due to the erosion occurred during the Last Glacial Maximum (LGM) with sea level at a depth of −130 m, followed by marine transgression that determined the development of ravinement surfaces. This study discusses previous research in the Mediterranean and elsewhere, and describes new fossiliferous marine deposits overlaying the metamorphic bedrock at Cannitello (Calabria, Italy). Radiocarbon ages of marine shells (about 43 kyrs cal BP) indicate that these deposits, presently between 28 and 30 m above sea level, formed during MIS 3.1. Elevation correction of the Cannitello outcrops (considered in an intermediate-to-far-field position with respect to the ice sheet) with the local vertical tectonic rate and Glacial Isostatic Adjustment (GIA) rate allows the proposal of a revision of the eustatic depth for this highstand. Our results are consistent with recently proposed estimates based on a novel ice sheet modelling technique.

The Potential of Tufa as a Tool for Paleoenvironmental Research—A Study of Tufa from the Zrmanja River Canyon, Croatia

Tufa is a fresh-water surface calcium carbonate deposit precipitated at or near ambient temperature, and commonly contains the remains of macro- and microphytes. Many Holocene tufas are found along the Zrmanja River, Dalmatian karst, Croatia. In this work we present radiocarbon dating results of older tufa that was found for the first time at the Zrmanja River near the Village of Sanaderi. Tufa outcrops were observed at different levels, between the river bed and up to 26 m above its present level. Radiocarbon dating of the carbonate fraction revealed ages from modern, at the river bed, up to 40 kBP ~20 m above its present level. These ages fit well with the hypothesis that the Zrmanja River had a previous surface connection with the Krka River, and changed its flow direction toward the Novigrad Sea approximately 40 kBP (Marine Isotope Stage 3). Radiocarbon AMS dating of tufa organic residue yielded a maximum conventional age of 17 kBP for the highest outcrop position indicating probable penetration of younger organic material to hollow tufa structures, as confirmed by radiocarbon analyses of humin extracted from the samples. Stable carbon isotope composition (δ13C) of the carbonate fraction of (−10.4 ± 0.6)‰ and (−9.7 ± 0.8)‰ for the Holocene and the older samples, respectively, indicate the autochthonous origin of the carbonate. The δ13C values of (−30.5 ± 0.3)‰ and (−29.6 ± 0.6)‰ for organic residue, having ages <500 BP and >5000 BP, respectively, suggest a unique carbon source for photosynthesis, mainly atmospheric CO2, with an indication of the Suess effect in δ13C during last centuries. The oxygen isotopic composition (δ18O) agrees well with deposition of tufa samples in two stages, the Holocene (−8.02 ± 0.72‰) and “old” (mainly MIS 3 and the beginning of MIS 2) (−6.89 ± 0.34‰), suggesting a ~4 °C lower temperature in MIS 3 compared to the current one.