A comparative microstructural and phase analysis of titanium aluminide samples obtained by SHS method in shells from a highly exothermic thermite mixture and an equimolar mixture of Nickel and aluminum is carried out. The energy of exothermic reactions of the shells allows heating the charge on the basis of titanium and aluminum and starting the SHS reaction in it. In the sinter sample in the Ni-Al shell, the reaction of titanium aluminide synthesis was not complete; the samples have a high-porous structure with small frame inclusions of intermetallides. In the synthesis of samples in the shell of the thermite mixture obtained alloy, optimal porosity and structure. The main phase in the samples obtained in different modes is titanium aluminide, also in both samples there are inclusions enriched in titanium (Ti3Al, Ti2Al phases), while the phase analysis did not reveal the presence of the initial components of the charge.