Ordered Nanostructure Catalysts Efficient for NOx Storage/Reduction (NSR) Processes

NOx emissions in the atmosphere can cause various environmental problems, which should be strictly controlled and regulated. Furthermore, because of the limited amount of crude oil resources in the world and severe global warming, the development of fuel-efficient vehicles has long been desired. Accordingly, efficient NOx storage and reduction catalysts have been developed over the decades, called NSR (NOx storage/reduction) catalysts. In the present article, recent advances in NSR catalysts which possess ordered nanostructures will be summarized, including our noble Pt/KNO3/K-titanate nanobelt (KTN), Pt-KNO3/CeO2 and Pt-KNO3/ZrO2 catalysts, as well as nanoporous Ni-phosphate (VSB-5) and Co-substituted VSB-5 catalysts.

Mechanistic insights into a NOx storage-reduction (NSR) catalyst by spatiotemporal operando X-ray absorption spectroscopy

Monitoring the catalytically active state and online mass spectra clarified the fast transient phenomena occurring inside a NSR catalyst.