First-principles calculations for Gilbert damping constant at finite temperature

We propose a first-principles calculation method for the Gilbert damping constants α at finite temperatures. α is described by the torque correlation model in which the electronic structure is computed by the tight-binding linear muffin-tin orbital method. We include the finite-temperature effect as the transverse spin fluctuation in the disordered local moment picture within the coherent potential approximation. Applying the present method to bcc-Fe and L10-FePt, we demonstrate these temperature-dependent α. By comparing our calculated results with experimental results, we find the calculated values are less than half of the experimental values, reflecting the characteristics of the torque correlation model.

Superconductivity in Octagraphene

This article reviews the basic theoretical aspects of octagraphene, an one-atom-thick allotrope of carbon, with unusual two-dimensional (2D) Fermi nesting, hoping to contribute to the new family of quantum materials. Octagraphene has an almost strongest sp 2 hybrid bond similar to graphene, and has the similar electronic band structure as iron-based superconductors, which makes it possible to realize high-temperature superconductivity. We have compared various possible mechanisms of superconductivity, including the unconventional s ± superconductivity based on spin fluctuation and conventional superconductivity based on electron-phonon coupling. Theoretical studies have shown that octagraphene has relatively high structural stability. Although many 2D carbon materials with C 4 carbon ring and C 8 carbon ring structures have been reported, it is still challenging to realize the octagraphene with pure square-octagon structure experimentally. This material holds hope to realize new 2D high-temperature superconductivity.

The Thermopower and Resistivity of Nearly Magnetic Dilute Alloys

<p>In some nearly magnetic dilute alloys, in which the host and impurity are transition metals of similar electronic structure, the thermopower is observed to form a "giant" peak at about the spin fluctuation temperature Tsf deduced from resistivity measurements. Two explanations for these peaks have been postulated: the first is that the peaks are a diffusion thermopower component involving scattering off localized spin fluctuations (LSF) at the impurity sites; the second is that they are an LSF drag effect. We examine the thermopower and resistively of two nearly magnetic alloy systems: Rh(Fe) and Pt(Ni). In the first part of this thesis we describe measurements of the low temperature thermopower and resistivity of several Rh(Fe) alloys to clarify discrepancies in previous measurements and we show, by using a modified Nordheim-Gorter analysis, that the observed thermopower peaks are a diffusion and not a drag effect. In the second part of the thesis we describe measurements of the low temperature thermopower and resistivity of Pt (Ni), for which no previous data had been available. The Pt(Ni) samples are manufactured as thin, evaporated films on glass substrates. However, due to the difficulty encountered in controlling the very high residual resistivity of these samples, we are not able to draw definite conclusions regarding either the thermopower or the resistivity.</p>

The Thermopower and Resistivity of Nearly Magnetic Dilute Alloys

<p>In some nearly magnetic dilute alloys, in which the host and impurity are transition metals of similar electronic structure, the thermopower is observed to form a "giant" peak at about the spin fluctuation temperature Tsf deduced from resistivity measurements. Two explanations for these peaks have been postulated: the first is that the peaks are a diffusion thermopower component involving scattering off localized spin fluctuations (LSF) at the impurity sites; the second is that they are an LSF drag effect. We examine the thermopower and resistively of two nearly magnetic alloy systems: Rh(Fe) and Pt(Ni). In the first part of this thesis we describe measurements of the low temperature thermopower and resistivity of several Rh(Fe) alloys to clarify discrepancies in previous measurements and we show, by using a modified Nordheim-Gorter analysis, that the observed thermopower peaks are a diffusion and not a drag effect. In the second part of the thesis we describe measurements of the low temperature thermopower and resistivity of Pt (Ni), for which no previous data had been available. The Pt(Ni) samples are manufactured as thin, evaporated films on glass substrates. However, due to the difficulty encountered in controlling the very high residual resistivity of these samples, we are not able to draw definite conclusions regarding either the thermopower or the resistivity.</p>