Performance recovery of plasma actuators in wet conditions

Plasma actuators have been extensively studied for flow control applications. While these studies have been traditionally focused on characterizing their performances as flow control devices, the performance of plasma actuators under adverse conditions like light rain remains to be less explored. This paper seeks to study the effects of water adhesion from droplets directly sprayed on to a plasma actuator using thrust recovery as the performance metric. It was found in all tests that wet actuators quickly recover plasma glow, before gradually regaining performance comparable to the dry actuator. The measured thrust for the wet actuator after 5 seconds of operation recovered by 46% and 42% of the thrust of the dry actuator for 50.0-62.5 g/m2 and 125-150 g/m2 of sprayed water droplets, respectively. At 22.5 kVpp and 14 kHz, the highest thrust recovery was recorded at 84% of that of the dry actuator after 80 seconds of operation. For 17.5 kVpp and 14 kHz the wet thrust recovered by 79%, while for 22.5 kVpp and 10 kHz the wet thrust recovered by 68% of their dry counterpart in 80 seconds. For 17.5 kVpp and 14 kHz, the thrust almost fully recovered in comparison to the dry actuator after about 290 seconds of operation. These results indicate that both applied voltage and operating frequency plays a critical role in the performance recovery while the latter may have a stronger influence. Performance recovery for a wet serpentine shaped plasma actuator is also included for general applicability. The power data in all cases show that wet actuators consume more power which with time gradually approach the dry actuator power data. This because during the initial stages of operation, the rolling mean current of the wet actuator is higher than the dry actuator even though the ionization spikes of dry actuator is stronger.

Electrolyte Takeover Strategy for Performance Recovery in Polysulfide-Permanganate Flow Batteries

The abundance of active material precursors for a polysulfide-permanganate flow battery makes it a compelling chemistry for large-scale, and potentially long-duration (>10 hours), grid electricity storage. Precipitation, arising from either reactant crossover or electrolyte side reactions, decrease cell efficiencies during charge/discharge cycling. Regardless of the abundance and low cost of active materials, a system without high cyclability cannot meet grid electricity storage economic targets for applications that cycle regularly. Precipitated species can be removed, and reactor performance restored, by using an electrolyte takeover process, or ETP. Two ETP methods are investigated. One ETP uses the negative electrolyte, an alkaline polysulfide (pS) solution, as takeover solution, and another uses dilute acidic peroxide (DAP) as the takeover solution. Both ETPs maintain functional cell operation within an acceptable performance range over >1000 hours and >200 cycles, a duration over which cells that do not undergo ETPs clog and fail. The DAP ETP proves especially effective and limits irrecoverable voltage efficiency fade below 0.02%/cycle. These ETPs, either individually, or in combination, can enable the requisite cyclability for practical polysulfide-permanganate flow battery systems.

Simultaneous Determination of Ergot Alkaloids in Swine and Dairy Feeds Using Ultra High-Performance Liquid Chromatography-Tandem Mass Spectrometry

Ergot alkaloids (EAs) are mycotoxins mainly produced by the fungus Claviceps purpurea. EAs are known to affect the nervous system and to be vasoconstrictors in humans and animals. This work presents recent advances in swine and dairy feeds regarding 11 major EAs, namely ergometrine, ergosine, ergotamine, ergocornine, ergocryptine, ergocristine, ergosinine, ergotaminine, ergocorninine, ergocryptinine, and ergocristinine. A reliable, sensitive, and accurate multiple mycotoxin method, based on extraction with a Mycosep 150 multifunctional column prior to analysis using UHPLC-MS/MS, was validated using samples of swine feed (100) and dairy feed (100) for the 11 targeted EAs. Based on the obtained validation results, this method showed good performance recovery and inter-day and intra-day precision that are in accordance with standard criteria to ensure reliable occurrence data on EA contaminants. More than 49% of the swine feed samples were contaminated with EAs, especially ergocryptine(-ine) (40%) and ergosine (-ine) and ergotamine (-ine) (37%). However, many of the 11 EAs were not detectable in any swine feed samples. In addition, there were contaminated (positive) dairy feed samples, especially for ergocryptine (-ine) (50%), ergosine (-ine) (48%), ergotamine (-ine), and ergocristine (-ine) (49%). The mycotoxin levels in the feed samples in this study almost complied with the European Union regulations.