scholarly journals Electrolyte Takeover Strategy for Performance Recovery in Polysulfide-Permanganate Flow Batteries

2021 ◽  
Author(s):  
James D. Saraidaridis ◽  
Zhiwei Yang
Keyword(s):  
Large Scale ◽  
Low Cost ◽  
Active Material ◽  
Side Reactions ◽  
Reactor Performance ◽  
Flow Battery ◽  
Active Materials ◽  
Electricity Storage ◽  
Long Duration ◽  
Performance Recovery

Abstract The abundance of active material precursors for a polysulfide-permanganate flow battery makes it a compelling chemistry for large-scale, and potentially long-duration (>10 hours), grid electricity storage. Precipitation, arising from either reactant crossover or electrolyte side reactions, decrease cell efficiencies during charge/discharge cycling. Regardless of the abundance and low cost of active materials, a system without high cyclability cannot meet grid electricity storage economic targets for applications that cycle regularly. Precipitated species can be removed, and reactor performance restored, by using an electrolyte takeover process, or ETP. Two ETP methods are investigated. One ETP uses the negative electrolyte, an alkaline polysulfide (pS) solution, as takeover solution, and another uses dilute acidic peroxide (DAP) as the takeover solution. Both ETPs maintain functional cell operation within an acceptable performance range over >1000 hours and >200 cycles, a duration over which cells that do not undergo ETPs clog and fail. The DAP ETP proves especially effective and limits irrecoverable voltage efficiency fade below 0.02%/cycle. These ETPs, either individually, or in combination, can enable the requisite cyclability for practical polysulfide-permanganate flow battery systems.

Low-Cost Flow Battery Active Materials for Long Duration Storage

2021 ◽  
Vol MA2021-01 (3) ◽  
pp. 214-214
Author(s):  
James D Saraidaridis ◽  
Robert M. Darling ◽  
Tim C Davenport ◽  
Zhiwei Yang
Keyword(s):  
Low Cost ◽  
Flow Battery ◽  
Active Materials ◽  
Long Duration ◽  
Cost Flow

scholarly journals An Aqueous, Electrode-Decoupled Redox-Flow Battery for Long Duration Energy Storage

2021 ◽  
Author(s):  
Vijay Ramani ◽  
Shrihari Sankarasubramanian ◽  
Yunzhu Zhang ◽  
Cheng He ◽  
Thomas Gregory
Keyword(s):  
Energy Storage ◽  
Large Scale ◽  
Low Cost ◽  
Capacity Fade ◽  
Redox Flow Battery ◽  
Flow Battery ◽  
Load Following ◽  
Arbitrage Opportunities ◽  
Long Duration ◽  
Exchange Membrane

Abstract Redox-flow batteries (RFBs) enable large-scale energy storage at low cost due to the independent scaling of device power and energy, thereby unlocking energy arbitrage opportunities and providing a pathway to grid stability and resiliency. Herein we demonstrate an “electrode-decoupled” redox-flow battery (ED-RFB) with titanium and cerium elemental actives that has a clear pathway to achieve a levelized cost of storage (LCOS) of ca $0.025/kWh-cycle. A key enabling technology is our highly perm-selective modified poly(ether ketone)-based anion exchange membrane (AEM) that ensures long term separation of Ti and Ce species and enables capacity-fade-free cycling over 1300 hours of operation. Further, our Ti-Ce ED-RFB exhibits negligible capacity fade when the actives are charged to 90% state of charge (SOC), stored for close to 100-hours and then discharged, rendering it viable for long duration (load-following) grid-scale energy storage applications. Herein we introduce the Ti-Ce ED-RFB as a novel, low-cost long duration energy storage (LDES) system.

scholarly journals Interfacial Manipulation via In-Situ Grown ZnSe Overlayer toward Highly Reversible Zn Metal Anodes

2021 ◽  
Author(s):  
Xianzhong Yang ◽  
Chao Li ◽  
Zhongti Sun ◽  
Shuai Yang ◽  
Zixiong Shi ◽  
...  
Keyword(s):  
Large Scale ◽  
Coulombic Efficiency ◽  
Low Cost ◽  
Chemical Vapor ◽  
Side Reactions ◽  
Water Penetration ◽  
Metal Anode ◽  
Zn Anode ◽  
Manipulation Strategy

Abstract Zn metal anode has garnered growing scientific and industrial interest owing to its appropriate redox potential, low cost and good safety. Nevertheless, the instability of Zn metal, caused by dendrite formation, hydrogen evolution and side reactions, gives rise to poor electrochemical stability and unsatisfactory cycling life, greatly hampering large-scale utilization. Herein, an in-situ grown ZnSe layer with controllable thickness is crafted over one side of commercial Zn foil via chemical vapor deposition, aiming to achieve optimized interfacial manipulation between aqueous electrolyte/Zn anode. Thus-derived ZnSe overlayer not only prevents water penetration and restricts Zn2+ two-dimensional diffusion, but also homogenizes the electric field at the interface and facilitates favorable (002) plane growth of Zn. As a result, dendrite-free and homogeneous Zn deposition is obtained; side reactions are concurrently inhibited. In consequence, a high Coulombic efficiency of 99.2% and high cyclic stability for 860 cycles at 1.0 mA cm–2 in symmetrical cells is harvested. Meanwhile, when paired with V2O5 cathode, assembled full cell achieves an outstanding initial capacity (200 mAh g–1) and elongated lifespan (a capacity retention of 84% after 1000 cycles) at 5.0 A g–1. Our highly reversible Zn anode enabled by the interfacial manipulation strategy is anticipated to satisfy the demand of industrial and commercial use.

Tuning Ferrous Coordination Structure Enables a Highly Reversible Fe Anode for Long-life All-iron Flow Batteries

2021 ◽  
Author(s):  
Yuxi Song ◽  
Kaiyue Zhang ◽  
Xiangrong Li ◽  
Chuanwei Yan ◽  
Qinghua Liu ◽  
...  
Keyword(s):  
Energy Storage ◽  
Large Scale ◽  
Low Cost ◽  
Flow Battery ◽  
Coordination Structure ◽  
Promising Alternative ◽  
Flow Batteries ◽  
Energy Storage Applications ◽  
Long Life ◽  
Hydrolysis Of

Aqueous all-iron flow battery is a promising alternative for large-scale energy storage applications due to low cost and high safety. However, inferior Fe plating/stripping reversibility and hydrolysis of Fe2+ at...

Manganese phosphoxide/Ni5P4 hybrids as an anode material for high energy density and rate potassium-ion storage

2021 ◽  
Author(s):  
Sen Yang ◽  
Ting Li ◽  
Yiwei Tan
Keyword(s):  
Energy Density ◽  
Lithium Ion Batteries ◽  
Large Scale ◽  
Low Cost ◽  
Lithium Ion ◽  
High Energy ◽  
Potassium Ion ◽  
High Energy Density ◽  
Active Materials ◽  
Ion Storage

Potassium-ion batteries (PIBs) that serve as low-cost and large-scale secondary batteries are regarded as promising alternatives and supplement to lithium-ion batteries. Hybrid active materials can be featured with the synergistic...

Bis(4′-tert-butylbiphenyl-4-yl)aniline (BBA)-substituted A3B zinc porphyrin as light harvesting material for conversion of light energy to electricity

2020 ◽  
Vol 24 (10) ◽  
pp. 1189-1197
Author(s):  
Naresh Duvva ◽  
Suneel Gangada ◽  
Raghu Chitta ◽  
Lingamallu Giribabu
Keyword(s):  
Solar Cells ◽  
Large Scale ◽  
Light Harvesting ◽  
Low Cost ◽  
Active Material ◽  
Dye Sensitized Solar Cells ◽  
Spectroscopic Techniques ◽  
Solar Panels ◽  
Zinc Porphyrin ◽  
Sensitized Solar Cells

Limited synthetic steps via low-cost starting materials are needed to develop large-scale light-active materials for efficient solar cells. Here, novel bis(4[Formula: see text]-tert-butylbiphenyl-4-yl)aniline (BBA) based A3B zinc porphyrin (GB) is synthesized and applied as a light harvesting/electron injection material in dye-sensitized solar cells. The GB sensitizer was characterized by various spectroscopic techniques and the optimized device shows [Formula: see text] of 10.98 ± 0.37 mA/cm2 and power conversion efficiency (PCE) of 3.34 ± 0.26%. In addition, performance is enhanced up to ∼3.9% by the addition of co-adsorbent 3a,7a-dihydroxy-5b-cholic acid (chenodeoxycholic acid, CDCA) to minimize [Formula: see text]-[Formula: see text] staking of the planar porphyrin macrocycles. These results demonstrate that novel broad-absorbing light-active material (GB) could be used for indoor solar panels.

scholarly journals Sodium Induced Morphological Changes of Carbon Coated TiO2 Anatase Nanoparticles – High-Performance Materials for Na-Ion Batteries

MRS Advances ◽  
2020 ◽  
Vol 5 (43) ◽  
pp. 2221-2229
Author(s):  
G. Greco ◽  
S. Passerini
Keyword(s):  
Large Scale ◽  
Morphological Changes ◽  
Low Cost ◽  
Cell Structure ◽  
Active Material ◽  
Lithium Ion ◽  
Composite Electrodes ◽  
Carbon Coated ◽  
Anatase Nanoparticles ◽  
First Time

AbstractThe most promising candidate as an everyday alternative to lithium-ion batteries (LIBs) are sodium-ion batteries (NIBs). This is not only due to Na abundance, but also because the main principles and cell structure are very similar to LIBs. Due to these benefits, NIBs are expected to be used in applications related to large-scale energy storage systems and other applications not requiring top-performance in terms of volumetric capacity. One important issue that has hindered the large scale application of NIBs is the anode material. Graphite and silicon, which have been widely applied as anodes in NIBs, do not show great performance. Hard carbons look very promising in terms of their abundance and low cost, but they tend to suffer from instability, in particular over the long term. In this work we explore a carbon-coated TiO2 nanoparticle system that looks very promising in terms of stability, abundance, low-cost, and most importantly that safety of the cell, since it does not suffer from potential sodium plating during cycling. Maintaining a nano-size and consistent morphology of the active material is a crucial parameter for maintaining a well-functioning cell upon cycling. In this work we applied Anomalous Small Angle X-Ray Scattering (ASAXS) for the first time at the Ti K-edge of TiO2 anatase nanoparticles on different cycled composite electrodes in order to have a complete morphological overview of the modifications induced by sodiation and desodiation. This work also demonstrates for the first time that the nanosize of the TiO2 is maintained upon cycling, which is in agreement with the electrochemical stability.

scholarly journals Large-Scale Pumped Thermal Electricity Storages—Converting Energy Using Shallow Lined Rock Caverns, Carbon Dioxide and Underground Pumped-Hydro

2019 ◽  
Vol 9 (19) ◽  
pp. 4150 ◽  
Author(s):  
Pascal Lalanne ◽  
Paul Byrne
Keyword(s):  
Large Scale ◽  
Low Cost ◽  
District Heating ◽  
Energy Transition ◽  
Heating And Cooling ◽  
Long Duration ◽  
Low Emission ◽  
Rock Cavern ◽  
Lined Rock Cavern ◽  
Thermal Stores

A fast-paced energy transition needs a higher penetration of renewables, of heating and cooling in the worldwide energy mix. With three novelties 1-of using shallow high-pressure LRC (Lined Rock Cavern) excavated close to storage needs, 2-of using a slow-moving CO2 piston applying steady pressure on the hydro part of UPHES (Underground Pumped Hydro Energy Storage) and 3-of relying on inexpensive thermal stores for long-duration storage, CO2 UPHES coupled with PTES (Pumped Thermal Electricity Storage) could become, at expected Capex cost of only 20 USD/kWh electrical, a game-changer by allowing the complete integration of intermittent renewable sources. Moreover, even though this early conceptual work requires validation by simulation and experimentation, CO2 UPHES as well as UPHES-PTES hybrid storage could also allow a low-cost and low-emission integration of intermittent renewables with future district heating and cooling networks.

scholarly journals A Low-Cost Neutral Aqueous Redox Flow Battery with Dendrite-Free Tin Anode

2021 ◽  
Author(s):  
Hui Chen ◽  
Zhongjie Wang ◽  
Shirui Zhang ◽  
Ming Cheng ◽  
fuyu chen ◽  
...  
Keyword(s):  
Low Cost ◽  
Supporting Electrolyte ◽  
High Energy ◽  
Flow Cell ◽  
Commercial Application ◽  
Storage Device ◽  
Flow Battery ◽  
Active Materials ◽  
Positive Side ◽  
Cycling Performances

Abstract A neutral aqueous tin-based flow battery is proposed by employing Sn2+/Sn as active materials for the negative side, [Fe(CN)6]3-/ Fe(CN)6]4- as active materials for the positive side, and potassium chloride as the supporting electrolyte, and its overall performances and cost for capacity unit are investigated. Cyclic voltammetry is performed and shows that the Sn2+/Sn has outstanding electrochemical behavior. The charging-discharging tests are conducted with the optimized electrolyte composition of 0.2 M [Fe(CN)6]3- and 3 M KCl. It is shown that the flow cell can reach a high energy efficiency of 80% at 10 mA cm-2 and be stably operated at 40 mA cm-2. The 120-cycling test shows that the flow cell can be of superior cycling performances, benefitting from the dendrite-free property of tin. Finally, cost analysis further confirms its competitiveness in price, offering a promising future for commercial application. This work not only forms a promising energy storage device with dendrite-free and low-cost benefits, but also provide a deep insight into its overall behavior, which is highly beneficial to the full understanding and further advancement of the proposed neutral tin-iron flow battery.

scholarly journals Synthesis of polypeptides via bioinspired polymerization of in situ purified N-carboxyanhydrides

2019 ◽  
Vol 116 (22) ◽  
pp. 10658-10663 ◽  
Author(s):  
Ziyuan Song ◽  
Hailin Fu ◽  
Jiang Wang ◽  
Jingshu Hui ◽  
Tianrui Xue ◽  
...  
Keyword(s):  
Large Scale ◽  
Low Cost ◽  
Local Environment ◽  
Side Reactions ◽  
Scale Production ◽  
Competing Species ◽  
Natural Protein ◽  
Large Scale Production ◽  
Synthetic Polypeptides

Ribozymes synthesize proteins in a highly regulated local environment to minimize side reactions caused by various competing species. In contrast, it is challenging to prepare synthetic polypeptides from the polymerization of N-carboxyanhydrides (NCAs) in the presence of water and impurities, which induce monomer degradations and chain terminations, respectively. Inspired by natural protein synthesis, we herein report the preparation of well-defined polypeptides in the presence of competing species, by using a water/dichloromethane biphasic system with macroinitiators anchored at the interface. The impurities are extracted into the aqueous phase in situ, and the localized macroinitiators allow for NCA polymerization at a rate which outpaces water-induced side reactions. Our polymerization strategy streamlines the process from amino acids toward high molecular weight polypeptides with low dispersity by circumventing the tedious NCA purification and the demands for air-free conditions, enabling low-cost, large-scale production of polypeptides that has potential to change the paradigm of polypeptide-based biomaterials.

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