A new local meteoric water line for Inuvik (NT, Canada)

The paper presents a new local meteoric water line (LMWL) of stable oxygen and hydrogen isotopes in precipitation from Inuvik in the western Canadian Arctic. Data were obtained over 37 months between August 2015 and August 2018 resulting in 134 measurements of the isotopic composition of both types of precipitation, snow and rain. For 33 months of the sampling period each month is represented at least two times from different years. The new LMWL from Inuvik is characterized by a slope of 7.39 and an intercept of −6.70 and fills a data gap in the western Arctic, where isotopic composition data of precipitation are scarce and stem predominantly from before the year 1990. Regional studies of meteorology, hydrology, environmental geochemistry and paleoclimate will likely benefit from the new Inuvik LMWL. Data are available on the PANGAEA repository under https://doi.org/10.1594/PANGAEA.935027 (Fritz et al., 2021).

Seasonal and Inter-Annual Variations of Stable Isotopic Characteristics of Rainfall and Cave Water in Shennong Cave, Southeast China, and Its Paleoclimatic Implication

Speleothem calcite stable oxygen isotope (δ18OC) is one of the most widely used proxies in paleoclimate research, and understanding its seasonal-annual variability is very significant for palaeoclimate reconstruction. Five-year precipitation and karst cave water from 2016 to 2021 were monitored in Shennong cave, Jiangxi Province, Southeast China. The local meteoric water line (LMWL) is δD = 8.20 × δ18O + 13.34, which is similar to the global meteoric water line. The stable hydrogen and oxygen isotope (δD and δ18O) characteristics of precipitation and cave water were studied. δ18O and δD of precipitation and cave water show obvious seasonal variations. Lower precipitation δ18O and δD generally occur during summer and autumn compared with higher δ18O and δD values during winter and spring. Meanwhile, low precipitation δ18O values do not only appear in June–July when precipitation is the highest of the year but also appear in August–September when precipitation is limited. The back-trajectory analysis of monsoon precipitation moisture sources shows that the moisture uptake regions vary little on inter-annual scales; the water vapor of rainfall in June–July comes from the South China Sea and the Bay of Bengal, while the moisture source in August–September is mainly from the West Pacific and local area. The El Niño-Southern Oscillation is an important factor affecting the value of δ18O by modulating the percentage of summer monsoon precipitation in the annual precipitation and moisture source. The relationship between amount-weighted monthly mean precipitation δ18O and Niño-3.4 index shows that the East Asian summer monsoon (EASM) intensifies during La Niña phases, resulting in more precipitation in monsoon season (May to September, MJJAS) and lower δ18O values, and vice versa during El Niño phases.

Temporal variations of stable isotopes in precipitation from Yungui Plateau: Insights from moisture source and rainout effect

Long-term continuous monitoring of precipitation isotopes has great potential to advance our understanding of hydrometeorological processes that determine stable isotope variability in the monsoon regions. This study presents 4–year daily precipitation isotopes from Yungui Plateau in southwestern China that is influenced by Indian summer monsoon and East Asian monsoon. The local meteoric water line (LMWL, δ2H=8.12 δ18O+11.2) was firstly established at the Tengchong (TC) site, which was close to the global meteoric water line (GMWL, δ2H=8 δ18O+10) indicating little secondary sub–cloud evaporation in the falling rain. Precipitation δ18O values exhibited significant inverse relationships with precipitation amount (r = −0.42), air temperature (r = −0.43), and relative humidity (r = −0.41) with lower correlation coefficients throughout the entire period, which indicated that precipitation isotopic variability in TC could not be well explained by the local meteorological factors but influenced by other combined factors of regional precipitation amount and upstream rainout. Precipitation δ18O values showed a clear V–shaped trend throughout the observation period, characterized by higher δ18O values during the pre–monsoon period whereas lower values during the post–monsoon period. This seasonal variation of precipitation δ18O values was associated with the seasonal movement of the Intertropical convergence zone and seasonal changes in moisture transport. Combined with backward trajectory analysis, precipitation δ18O values were estimated by a Rayleigh distillation model showing that upstream rainout processes from Bay of Bengal (BoB) towards land (Myanmar), and recycling moisture over land were key factors affecting the isotopic compositions of the TC precipitation. These findings could enhance our understanding of atmospheric dynamics and moisture source in the monsoon regions and will potentially facilitate the interpretation of numerous isotopic proxy records from this region.

A new local meteoric water line for Inuvik (NT, Canada)

The paper presents a new local meteoric water line (LMWL) of precipitation stable oxygen and hydrogen isotopes from Inuvik in the Western Canadian Arctic. Data were obtained over 37 months between August 2015 and August 2018 resulting in 134 measurements of the isotopic composition of both types of precipitation, snow and rain. For 33 months of the sampling period each month is represented at least two times from different years. The new LMWL from Inuvik is characterized by a slope of 7.39 and an intercept of –6.70, and fills a data gap in the Western Arctic where isotopic composition data of precipitation are scarce and stem predominantly from before the year 1990. Regional studies of meteorology, hydrology, environmental geochemistry and paleoclimate will likely benefit from the new Inuvik LMWL.

Study on the isotopic compositionof rainwater in Long Khanh city,Southeast of the Mekong Delta region

The 2H/1H and 18O/16O isotope ratios in rainwater bring a lot of information about the fractionation of water molecules in the hydrosphere. The relationship between the isotope ratios of rainwater in an area characterised by the local meteoric water line, which is known as a reliable reference value for studies related to the identification of the recharge source of groundwater and climate change investigations. This study aims to establish a local meteoric water line in Long Khanh city (LK LMWL) in the period of 2020-2021, which is considered as a basis for research on the origin of groundwater in the area of Long Khanh city and subsequent studies on the origin of groundwater in the Southeast of the Mekong Delta region and the Dong Nai river basin. Results show that δ2H in rainwater ranges from -73.64 to 0.36 (‰ VSMOW) with an average value of -49.74‰ (n=19) and that figure of δ18O ranges from -10.91 to -1.59 (‰ VSMOW) with a mean of -7.68‰ (n=19). Due to the amount and specific meteorological conditions of the region, δ2H and δ18O in rainwater are enriched in the dry season but deplete in the rainy season. The LK LMWL follows a model of δ2H=(7.89±0.38)xδ18O + (10.28±2.93) (R2=0.96, n=19), which shows that the isotopic composition of δ18O in rainwater is more enriched than the isotopic composition of δ2H. The deuterium excess (d-excess) of rainwater in the region is found to be 10.28±2.93‰, which is comparable to those for the global scale of 10‰.

Last glacial millennial-scale hydro-climate and temperature changes in Puerto Rico constrained by speleothem fluid inclusion δ¹⁸O and δ²H values

We present speleothem fluid inclusion δ18Of and δ2Hf values from Larga Cave, Puerto Rico, that covers the interval between 46.2 to 15.3 ka before present on millennial scale, including the Last Glacial Maximum (LGM) and several stadial and interstadial cycles. The dataset can be divided in two main clusters of stable isotope compositions of the fluid inclusion water with respect to the global meteoric water line which coincide with strong variations in the water content of the stalagmite. In particular, this clustering is found to be climate related, where the first cluster comprises samples from cold and dry periods, such as Heinrich and Greenland stadials, as well as parts of the LGM, which exhibit very high δ18Of and δ2Hf values. We interpret this enrichment as caused by evaporation inside the cave due to enhanced cave ventilation during these colder and drier times. In contrast, in most samples corresponding to warmer and wetter Greenland interstadials, but also for some from Heinrich Stadial 2 and 3, the δ18Of and δ2Hf values plot on the meteoric water line and modification of fluid inclusion water due to “in-cave” evaporation is found negligible. Consequently, variations of last glacial hydro-climate and temperature in the western tropical Atlantic can be constrained. In general, δ18Of values from fluid inclusions are up to 3 ‰ higher than those of modern drip water, which is interpreted as a weaker atmospheric convective activity during the last glacial period. In addition, reconstructed temperatures suggest an average cooling of c. 3 °C during the LGM compared to modern cave temperature. During Heinrich Stadials 2 and 3, reconstructed cave temperatures yield an additional cooling of 2.9 ± 2.6 °C and 4.4 ± 0.6 °C, respectively. Higher δ18Of values of these samples further suggest that the drip water was dominated by orographic rainfall and/or cold fronts, along with weak or even absent convective activity. In contrast, during interstadial phases, reconstructed temperatures reached nearly modern values, and convective activity was comparable or only slightly weaker than today.

National Stable Isotope Baseline for Precipitation in Malawi to Underpin Integrated Water Resources Management

With the resurgence of water-isotope tracing applications for Integrated Water Resource Management in developing countries, establishing a stable isotopic baseline is necessary. Developing countries, including Malawi, continue to struggle with the generation of consistent and long-term isotopic datasets due to non-existent or inadequate in-country water-isotope capacity. Malawi has made significant advances in its quest to establish a stable isotopic baseline through the establishment of the Malawi Network of Isotope in Precipitation. This study provides the first results for the isotopic characterization of precipitation in Malawi with a view to reinforcing understanding of the country’s hydrological cycle. Error-in-variables regression defined a Local Meteoric Water Line as δ2H = 8.0 (±0.3) δ18O + 13.0 (±2.0) using stable isotopic records of 37 monthly samples from 5 stations between 2014 and 2019. Local precipitation (isotopic composition) is consistent with global precipitation expectations, its condensation-forming process occurring under equilibrium conditions and a higher intercept (d-excess) above the 10‰ for Global Meteoric Water Line, implying that air moisture recycling significantly influences local precipitation. Wider variations observed in local precipitation isotopic signatures are largely attributed to different moisture-bearing systems and diverse geographic factors across the country. Additional stations are recommended to improve spatial coverage that, together with longer temporal records, may help understanding and resolving uncertainties such as the altitude effect. This pioneering study is expected to facilitate Malawi’s ambition to achieve integrated use and improved protection of its surface water and groundwater resources in response to mounting climate change, growing population and land-development concerns.

Stable Isotopic Variability of Daily Precipitation from Yungui Plateau of Southwest China: Insights from Moisture Source and Rainout Effect

Long-term continuous monitoring of precipitation isotopes has great potential to advance our understanding of mechanisms that determine stable isotope variability in hydrological processes of monsoon regions. This study presents a 4-year daily data set of precipitation isotopes from Yungui Plateau of southwest China, influenced by southwest monsoon and East Asian monsoon. The local meteoric water line [LMWL, δ2H=8.12 (±0.04) δ18O+11.2(±0.4)] was established at the Tengchong (TC) site, which was similar to the global meteoric water line (GMWL, δ2H=8 δ18O+10) indicating little secondary sub-cloud evaporation in the falling rain. Precipitation δ18O exhibited significant inverse relationships with precipitation amount (r = -0.42) and air temperature (r = -0.43) throughout the entire period, which indicated that precipitation isotopic variability largely depended on the local meteorological conditions. Precipitation δ18O values are characterized by remarkably seasonal variability: In the summer monsoon period, moisture sources primarily originated from BoB source towards TC site experiencing local moisture recycling over land. The air masses were derived from the northern region of Africa and East Asia with the longest transporting distance and cyclonic activity over the source region in the Fall-winter period characterized with the depleted δ18O values. Precipitation δ18O at the TC site was estimated by a Rayleigh fractionation model considering rainout over BoB and land (Myanmar) during the vapor advection, and local recycling processes consistent with the observed precipitation δ18O values. These findings enhance our understanding of hydrological cycle in the Southwest monsoon regions and will potentially facilitate the interpretation of numerous isotopic proxy records from this region.

Geochemical characterisation of the thermo-mineral waters of Greece

Geothermal areas of Greece are located in regions affected by recent volcanism and in continental basins characterised by elevated heat flow. Many of them are found along the coast, and thus, water is often saline due to marine intrusion. In the current study, we present about 300 unpublished and literature data from thermal and cold mineral waters collected along Greece. Samples were analysed for major ions, Li, SiO2 and isotopes in water. Measured temperatures range from 6.5 to 98 °C, pH from 1.96 to 11.98, while Total Dissolved Solutes (TDS) from 0.22 to 51 g/L. Waters were subdivided into four main groups: (1) thermal; (2) cold; (3) acidic (pH < 5); and (4) hyperalkaline (pH > 11). On statistical basis, thermal waters were subdivided into subgroups according to both their temperature [warm (< 29 °C), hypothermal (29–48 °C), thermal (48–75 °C) and hyperthermal (> 75 °C)] and TDS [low salinity (< 4 g/L), brackish (4–30 g/L) and saline (> 30 g/L)]. Cold waters were subdivided based on their pCO2 [low (< 0.05 atm), medium (0.05–0.85 atm) and high (> 0.85 atm)]. δ18O–H2O ranges from − 12.7 to + 2.7‰ versus SMOW, while δ2H–H2O from − 91 to + 12‰ versus SMOW being generally comprised between the Global Meteoric Water Line and the East Mediterranean Meteoric Water Line. Positive δ18O shifts with respect to the former are mostly related to mixing with seawater, while only for a few samples these shifts point to high-temperature water–rock interaction processes. Only a few thermal waters gave reliable geothermometric estimates, suggesting reservoir temperatures between 80 and 260 °C.

Characteristics and moisture sources of the stable isotopes in precipitation in the monsoon marginal region of north-central China

The stable hydrogen and oxygen isotopes in precipitation (δD and δ18O, respectively) are important source signatures for understanding the hydrological cycle and paleoclimatic reconstruction. In this study, 32 precipitation samples were collected from April to October 2014 at the Luya Mountain summit, a representative site in the monsoon marginal area of north-central China. The isotopic signatures of precipitation exhibited strong seasonal variations ranging from -185.61‰ to -18.50‰ and -25.51‰ to -4.59‰ for δD and δ18O, respectively, which were relatively higher in August and lower in September. The local meteoric water line was δD=(7.95±0.16) δ18O+(15.79±1.77) (R2 = 0.988, N = 32, p < 0.001), which had a similar slope but higher intercept than that of the global meteoric water line, indicating that the precipitation in this area is mainly sourced from the ocean surface transported via monsoons. Additionally, the secondary evaporated water by continental recycled moisture was identified by the significantly higher deuterium excess value (16.09‰). Backward trajectories generated via the Hybrid Single-Particle Lagrangian Integrated Trajectory model indicated seasonal moisture transport changes in the studied monsoonal marginal region, in which the main moisture sources were the Westerly winds in April, the Pacific Ocean in July, and the Indian Ocean in September. Secondary evaporated water from the alpine ecosystem may also influence the local atmospheric water cycle throughout the year. Positive temperature-isotopic signature effect (δD and δ18O) was observed in the cold season (before mid-May); however, the precipitation amount effect was observed in the monsoon season from June to August, and both effects became vague across the entire period. These findings suggest that the stable isotope compositions of precipitation can be utilized to determine the moisture sources in the monsoon marginal region of north-central China and potentially be utilized to reconstruct the precipitation signals in this region.