Temporal variations of stable isotopes in precipitation from Yungui Plateau: Insights from moisture source and rainout effect
Abstract Long-term continuous monitoring of precipitation isotopes has great potential to advance our understanding of hydrometeorological processes that determine stable isotope variability in the monsoon regions. This study presents 4–year daily precipitation isotopes from Yungui Plateau in southwestern China that is influenced by Indian summer monsoon and East Asian monsoon. The local meteoric water line (LMWL, δ2H=8.12 δ18O+11.2) was firstly established at the Tengchong (TC) site, which was close to the global meteoric water line (GMWL, δ2H=8 δ18O+10) indicating little secondary sub–cloud evaporation in the falling rain. Precipitation δ18O values exhibited significant inverse relationships with precipitation amount (r = −0.42), air temperature (r = −0.43), and relative humidity (r = −0.41) with lower correlation coefficients throughout the entire period, which indicated that precipitation isotopic variability in TC could not be well explained by the local meteorological factors but influenced by other combined factors of regional precipitation amount and upstream rainout. Precipitation δ18O values showed a clear V–shaped trend throughout the observation period, characterized by higher δ18O values during the pre–monsoon period whereas lower values during the post–monsoon period. This seasonal variation of precipitation δ18O values was associated with the seasonal movement of the Intertropical convergence zone and seasonal changes in moisture transport. Combined with backward trajectory analysis, precipitation δ18O values were estimated by a Rayleigh distillation model showing that upstream rainout processes from Bay of Bengal (BoB) towards land (Myanmar), and recycling moisture over land were key factors affecting the isotopic compositions of the TC precipitation. These findings could enhance our understanding of atmospheric dynamics and moisture source in the monsoon regions and will potentially facilitate the interpretation of numerous isotopic proxy records from this region.