The method of radiation-thermal sintering (RTS) in the fast electron beam by accelerator ILU-6 obtained samples of barium hexaferrite BaFe12O19 and substituted barium hexaferrite BaFe9,5Al2,5O19 (with additions of Ni, Ti, Mn). The research synthesized samples was carried out by X-ray structural analysis and X-ray phase analysis. It is found that both compounds besides the main phase samples (BaFe12O19 and BaFe9,5Al2,5O19, respectively), is also present phase BaFe2O4. With increasing sintering temperature from 1100°C to 1300°C phase barium monoferrite intensity decreases or disappears completely, and at a temperature of 1400°C this phase is fixed again (its intensity continues to increase). The possibility of practical use of the results.