Decarbonizing Local Mobility and Greenhouse Agriculture through Residential Building Energy Upgrades: A Case Study for Québec

Electrification is an efficient way to decarbonize by replacing fossil fuels with low-emission power. In addition, energy efficiency measures can reduce consumption, making it easier to shift to a zero-carbon society. In Québec, upgrades to aging buildings that employ electric resistance heating offer a unique opportunity to free up large amounts of hydroelectricity that can serve to decarbonize heating in other buildings. However, another source of energy would be needed to electrify mobility because efficiency measures free up small amounts of electricity in summer compared to winter. This study reveals how building efficiency measures combined with solar electricity generation provide an energy profile that matches the requirements for decarbonizing both mobility and heating. The TRNSYS software was used to simulate the annual energy performance of an existing house and retrofitted/rebuilt low-energy houses equipped with a photovoltaic (PV) roof in Montreal, Québec, Canada (45.5° N). The electricity that is made available by upgrading the houses is mainly considered for powering battery and fuel cell electric vehicles (BEVs and FCEVs) and electrifying heating in greenhouses. The results indicate that retrofitting 16% or rebuilding 12% of single-detached homes in Québec can provide enough electricity to decarbonize heating energy use in existing greenhouses and to operate the new greenhouses required for growing all fresh vegetables locally. If all the single-detached houses that employ electric resistance heating are upgraded, 33.4 and 21.8 TWh year−1 of electricity would be available for decarbonization, equivalent to a 19% and 12% increase of the province’s electricity supply for the retrofitted or rebuilt houses, respectively. This is enough energy to convert 83–100% of personal vehicles to BEVs or 35–56% to FCEVs. Decarbonization using the electricity that is made available by upgrading to low-energy solar houses could reduce the province’s greenhouse gas (GHG) emissions by approximately 32% (26.5 MtCO2eq). The time required for the initial embodied GHG emissions to surpass the emissions avoided by electrification ranges from 3.4 to 11.2 years. Building energy efficiency retrofits/rebuilds combined with photovoltaics is a promising approach for Québec to maximize the decarbonization potential of its existing energy resources while providing local energy and food security.

Self-Piercing Riveting of Medium- and High-Strength Al and Mg Alloy Sheets Enabled by In-Process Electric Resistance Heating

Enduring joints of high-strength materials are becoming increasingly important for the manufacturing of highly loaded body-in-white structures, particularly for automobiles, which require structural light-weighting without sacrificing passenger safety. While self-piercing riveting has been proven suitable for various material classes, its application to high-strength, low-ductile materials is hindered by the occurrence of cracks and insufficient penetration. In this work, we demonstrated that these restrictions can be overcome by localized one-sided short-time electric resistance heating. The treatment can be integrated into the riveting process, allowing for short process times. The heating lowers the hardness of the materials to be joined and enables piercing and penetration of the sheets to yield crack-free joints. The local mechanical properties are hardly changed in case of peak-aged sheet material conditions but increase significantly in the close vicinity of the rivet in case of under-aged sheet material conditions. The outstanding static and dynamic mechanical properties of the resulting joints evidence their robustness.

Properties of a Laminated Wood Composite Produced with Thermomechanically Treated Veneers

The paper aimed at evaluating the properties of plywood made from thermomechanically treated wood veneers. Veneers from Amescla (Trattinnickia burseraefolia) wood were treated in a hydraulic press with electric resistance heating. Two temperature levels were applied, 140°C and 180°C, for 1 and 2 minutes with 2.7 N/mm2of pressure. A total of 30 plywood boards were produced, including six boards produced from untreated veneers. The results showed that the thermomechanical treatment did not have any deleterious effect on glue line strength and most of the mechanical properties of plywood made from treated veneers were improved. On the other hand, plywood made from untreated veneers presented better dimensional stability. Dimensional stability properties were most affected by the temperature of the treatment, while mechanical stability, represented by the glue line shear strength, was positively affected by temperature and duration of the treatment.

Unusual behavior in the reactivity of 5-substituted-1H-tetrazoles in a resistively heated microreactor

The decomposition of 5-benzhydryl-1H-tetrazole in an N-methyl-2-pyrrolidone/acetic acid/water mixture was investigated under a variety of high-temperature reaction conditions. Employing a sealed Pyrex glass vial and batch microwave conditions at 240 °C, the tetrazole is comparatively stable and complete decomposition to diphenylmethane requires more than 8 h. Similar kinetic data were obtained in conductively heated flow devices with either stainless steel or Hastelloy coils in the same temperature region. In contrast, in a flow instrument that utilizes direct electric resistance heating of the reactor coil, tetrazole decomposition was dramatically accelerated with rate constants increased by two orders of magnitude. When 5-benzhydryl-1H-tetrazole was exposed to 220 °C in this type of flow reactor, decomposition to diphenylmethane was complete within 10 min. The mechanism and kinetic parameters of tetrazole decomposition under a variety of reaction conditions were investigated. A number of possible explanations for these highly unusual rate accelerations are presented. In addition, general aspects of reactor degradation, corrosion and contamination effects of importance to continuous flow chemistry are discussed.