A review on the development of electro-carburisation process

The purpose of this paper is to review the early development of electro-carburisation technology and the research findings related to the electro-carburisation process. In general, conventional liquid carburisation of steel using a molten cyanide bath is carried out to improve the performance of mild steel, however this process produces toxic cyanide waste. Thus, other alternatives for liquid carburisation are necessary. Electro-carburisation process using carbonate-base molten salt, under a CO2 environment was developed as one of the alternatives to liquid carburising. Metal to be treated is exposed to the carbon-rich liquid in the molten cyanide bath and electro-carburisation. However, the metal is simply immersed inside the cyanide bath during conventional liquid carburising, while connected to the cathode in the electro-carburisation. The electro-carburisation involves a diffusion of carbon atoms into the surface of the metal which enhance the surface hardness of the metal. The effects of electrolysis parameters to the surface hardness and case hardening of treated metal have been reported in several journals. This article summarises the research findings. Apart from that, the quenching process and heat treatment post quenching also plays an important role in the quality of the carburised metal, therefore also reviewed in this article.

NHCs and Visible Light-mediated Photoredox Co-catalyzed Radical 1,2-Dicarbonylation of Alkenes for 1,4-Diketones

Alkenes are ubiquitous, and radical difunctionalization of alkenes represents one of the most practical approaches to constructing value-added compounds. Dicarbonylation of alkenes provides direct access to value-added 1,4-dicarbonyl compounds. However, selectivity control for unsymmetric 1,2-dicarbonylation is an unclosed challenge. We herein describe NHCs and photocatalysis co-catalyzed three competent radical 1,2-dicarbonylation of alkenes by distinguishing two carbonyl groups, providing structurally diversified 1,4-diketones. Mechanistic studies indicated that NHCs-stabilized ketyl-type radicals originate from aroyl fluorides via oxidative quenching process of excited photocatalysis, and acyl radicals are generated from single-electron-oxidation of α-keto acids. Distinct properties of acyl radical and NHCs-stabilized ketyl radical contributed to selectivity control. Transient acyl radicals are rapidly added to alkenes delivering alkyl radicals, which undergo subsequent radical-radical cross-coupling with ketyl-type radicals, affording 1,2-dicarbonylation products. This transformation features mild reaction conditions, broad substruct scope, and excellent selectivity, providing a general and practical approach for the dicarbonylation of olefins.

HST/WFC3 Grism Observations of z ∼ 1 Clusters: Evidence for Rapid Outside-in Environmental Quenching from Spatially Resolved Hα Maps

We present and publicly release (www.gclasshst.com) the first spatially resolved Hα maps of star-forming cluster galaxies at z ∼ 1, made possible with the Wide Field Camera 3 (WFC3) G141 grism on the Hubble Space Telescope (HST). Using a similar but updated method to 3D-HST in the field environment, we stack the Hα maps in bins of stellar mass, measure the half-light radius of the Hα distribution, and compare it to the stellar continuum. The ratio of the Hα to stellar continuum half-light radius, R [ H α / C ] = R eff , H α R eff , Cont , is smaller in the clusters by (6 ± 9)%, but statistically consistent within 1σ uncertainties. A negligible difference in R[Hα/C] with environment is surprising, given the higher quenched fractions in the clusters relative to the field. We postulate that the combination of high quenched fractions and no change in R[Hα/C] with environment can be reconciled if environmental quenching proceeds rapidly. We investigate this hypothesis by performing similar analysis on the spectroscopically confirmed, recently quenched cluster galaxies. 87% have Hα detections, with star formation rates 8 ± 1 times lower than star-forming cluster galaxies of similar stellar mass. Importantly, these galaxies have an R[Hα/C] that is (81 ± 8)% smaller than coeval star-forming field galaxies at fixed stellar mass. This suggests the environmental quenching process occurred outside-in. We conclude that disk truncation due to ram pressure stripping is occurring in cluster galaxies at z ∼ 1, but more rapidly and/or efficiently than in z ≲ 0.5 clusters, such that the effects on R[Hα/C] become observable just after the cluster galaxy has recently quenched.

Quenching and Distortion*

This paper is based on a keynote lecture presented by Prof. Fechte-Heinen during the 2nd International Conference on Quenching and Distortion Engineering in April 2021. Firstly, it presents a short summary of the basics of distortion formation. The mechanisms and the potential for distortion with its carriers are discussed in more detail. Furthermore, the method of Distortion Engineering is explained. Finally, selected examples are presented that illustrate the connections between distortion and the quenching process.

On the Thermal Dynamics of Metallic and Superconducting Wires. Bifurcations, Quench, the Destruction of Bistability and Temperature Blowup

In the present study, a numerical bifurcation analysis is carried out in order to investigate the multiplicity and the thermal runaway features of metallic and superconducting wires in a unified framework. The analysis reveals that the electrical resistance, combined with the boiling curve, are the dominant factors shaping the conditions of bistability—which result in a quenching process—and the conditions of multistability—which may lead to a temperature blowup in the wire. An interesting finding of the theoretical analysis is that, for the case of multistability, there are two ways that a thermal runaway may be triggered. One is associated with a high current value (“normal” runaway) whereas the other one is associated with a lower current value (“premature” runaway), as has been experimentally observed with certain types of superconducting magnets. Moreover, the results of the bifurcation analysis suggest that a static criterion of a warm or a cold thermal wave propagation may be established based on the limit points obtained.

The influence of anionic surfactant in water on the quenching process

Understanding the patterns of heat transfer during quenching is important for many technical applications. Of particular interest is the boiling regime, which is characterized by high intensity and occurs at surface temperatures exceeding the temperature of attainable liquid superheat. This work is aimed at studying the effect of surfactants on the onset of intense heat transfer during quenching. For this, experiments were carried out on quenching spheres made of different metals (nickel, stainless steel and zirconium) in water with different concentrations of surfactants. The surfactant was alkylbenzene sulfonate, the concentration of which varied from 0.1 to 2%. The analysis of the obtained cooling thermograms revealed the influence of not only the surfactant concentration on the beginning of the intensive cooling mode, but also the state of the heat transfer surface.

Features of cooling bodies with a high coefficient of thermal effusivity in subcooled mixtures

The paper focuses on the study a special type of boiling, "microbubble boiling". Experiments are carried out on water-ethanol mixtures of different concentrations. The pressure varies from 0.1 to 0.3 MPa; and copper and stainless-steel samples are used as working samples. The purpose of the experiments is to investigate the effect of such parameters as solid and liquid properties and subcooling on the transition temperature from the stable film boiling to “microbubble” boiling regime. In the course of direct comparison of the results obtained by cooling the samples with different thermal effusivity under the same conditions, a strong influence of the properties of the cooled body on the quenching process has been revealed.

A Comparative Study of Fabricating IrOx Electrodes by High Temperature Carbonate Oxidation and Cyclic Thermal Oxidation and Quenching Process

IrOx electrodes were fabricated by cyclic thermal heating and water quenching (CHQ) process and high temperature carbonate oxidation (HCO), respectively. By examining the E-pH relationship, response rate, potential drift behavior of the fabricated electrodes, the electrodes prepared by CHQ process seemed to show better comprehensive performance. Characterization tests such as scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), Raman spectroscopy, and electrochemical impedance spectroscopy (EIS) were used to characterize the fabricated IrOx electrodes and find out the reason for the better performance of the electrodes prepared by CHQ process. Morphology tests indicate that the CHQ electrode shows a multi-layer structure with more ion channels, which could provide larger surface area for the H+ response process. Furthermore, combining the XPS, Raman and EIS tests etc., more effective response composition, better crystal quality, and smaller response reaction resistance of surface IrOx film could account for the better performance of the CHQ-fabricated IrOx electrode. The film formation process, H+ response mechanism, as well as the response behavior difference between the two kinds of the electrodes are further elaborated.