Extremely high upper critical field in BiCh2-based (Ch: S and Se) layered superconductor LaO0.5F0.5BiS2−xSex (x = 0.22 and 0.69)

Centrosymmetric compounds with local inversion symmetry breaking have tremendously interesting and intriguing physical properties. In this study, we focus on a BiCh2-based (Ch: S, Se) layered superconductor, as a system with local inversion asymmetry, because spin polarisation based on the Rashba–Dresselhaus-type spin–orbit coupling has been observed in centrosymmetric BiCh2-based LaOBiS2 systems, while the BiCh2 layer lacks local inversion symmetry. Herein, we report the existence of extremely high in-plane upper critical fields in the BiCh2-based system LaO0.5F0.5BiS2−xSex (x = 0.22 and 0.69). The superconducting states are not completely suppressed by the applied magnetic fields with strengths up to 55 T. Thus, we consider that the in-plane upper critical field is enhanced by the local inversion symmetry breaking and its layered structure. Our study will open a new pathway for the discovery of superconductors that exhibit a high upper critical field by focusing on the local inversion symmetry breaking.

Structural descriptor for enhanced spin-splitting in 2D hybrid perovskites

Two-dimensional (2D) hybrid metal halide perovskites have emerged as outstanding optoelectronic materials and are potential hosts of Rashba/Dresselhaus spin-splitting for spin-selective transport and spin-orbitronics. However, a quantitative microscopic understanding of what controls the spin-splitting magnitude is generally lacking. Through crystallographic and first-principles studies on a broad array of chiral and achiral 2D perovskites, we demonstrate that a specific bond angle disparity connected with asymmetric tilting distortions of the metal halide octahedra breaks local inversion symmetry and strongly correlates with computed spin-splitting. This distortion metric can serve as a crystallographic descriptor for rapid discovery of potential candidate materials with strong spin-splitting. Our work establishes that, rather than the global space group, local inorganic layer distortions induced via appropriate organic cations provide a key design objective to achieve strong spin-splitting in perovskites. New chiral perovskites reported here couple a sizeable spin-splitting with chiral degrees of freedom and offer a unique paradigm of potential interest for spintronics.

Structural descriptor for enhanced spin-splitting in 2D hybrid perovskites

Two-dimensional (2D) hybrid metal halide perovskites have emerged as outstanding optoelectronic materials and are potential hosts of Rashba/Dresselhaus spin-splitting for spin-selective transport and spin-orbitronics. However, a quantitative microscopic understanding of what controls the spin-splitting magnitude is generally lacking. Through crystallographic and first-principles studies on a broad array of chiral and achiral 2D perovskites, we demonstrate that a specific bond angle disparity connected with asymmetric tilting distortions of metal halide octahedra breaks local inversion symmetry and strongly correlates with computed spin-splitting. This distortion metric can serve as a crystallographic descriptor for rapid discovery of potential candidate materials with strong spin-splitting. Our work establishes that rather than global space group, local inorganic layer distortions induced via appropriate organic cations provide a key design principle to achieve strong spin-splitting in perovskites. New chiral perovskites reported here couple a sizeable spin-splitting with chiral degrees of freedom and offer a unique paradigm of potential interest for spintronics.

Local null controllability of a model system for strong interaction between internal solitary waves

In this paper, we prove the local null controllability property for a nonlinear coupled system of two Korteweg–de Vries equations posed on a bounded interval and with a source term decaying exponentially on [Formula: see text]. The system was introduced by Gear and Grimshaw to model the interactions of two-dimensional, long, internal gravity waves propagation in a stratified fluid. We address the controllability problem by means of a control supported on an interior open subset of the domain and acting on one equation only. The proof consists mainly on proving the controllability of the linearized system, which is done by getting a Carleman estimate for the adjoint system. While doing the Carleman, we improve the techniques for dealing with the fact that the solutions of dispersive and parabolic equations with a source term in [Formula: see text] have a limited regularity. A local inversion theorem is applied to get the result for the nonlinear system.

Comparative Mitogenomic Analysis of Two Cuckoo Bees (Apoidea: Anthophila: Megachilidae) with Phylogenetic Implications

Bees (Hymenoptera, Apoidea and Anthophila) are distributed worldwide and considered the primary pollinators of angiosperm. Megachilidae is one of the largest families of Anthophila. In this study, two complete mitogenomes of cuckoo bees in Megachilidae, namely Coelioxys fenestrata and Euaspis polynesia, were amplified and sequenced, with a length of 17,004 bp (C. fenestrata) and 17,682 bp (E. polynesia). The obtained results show that 37 mitogenomic genes and one putative control region were conserved within Hymenoptera. Truncated stop codon T was found in the cox3 gene of E. polynesia. The secondary structure of small (rrnS) and large (rrnL) rRNA subunits contained three domains (28 helices) and five domains (44 helices) conserved within Hymenoptera, respectively. Compared with ancestral gene order, gene rearrangement events included local inversion and gene shuffling. In order to reveal the phylogenetic position of cuckoo bees, we performed phylogenetic analysis. The results supported that all families of Anthophila were monophyletic, the tribe-level relationship of Megachilidae was Osmiini + (Anthidiini + Megachilini) and Coelioxys fenestrata was clustered to the Megachile genus, which was more closely related to Megachile sculpturalis and Megachile strupigera than Euaspis polynesia.

Seismic and borehole-based mapping of the late Carboniferous succession in the Canonbie Coalfield, SW Scotland: evidence for a ‘broken’ Variscan foreland?

Local seismic and borehole-based mapping of the Carboniferous Pennine Coal Measures and Warwickshire Group successions in the Canonbie Coalfield (SW Scotland) provides evidence of repeated episodes of positive inversion, syn-depositional folding and unconformities. A Duckmantian (Westphalian B) episode of NE–SW transpression is recognized, based on onlapping seismic reflector geometries against NE-trending positive inversion structures and contemporaneous NNE-trending syn-depositional growth folding. The basin history thus revealed at Canonbie is at variance with generally accepted models in neighbouring northern England that imply subsidence was due to post-rift thermal subsidence during late Carboniferous times. A late Westphalian–Stephanian unconformity recognized within the Warwickshire Group succession signifies NW–SE, c. 10% local basin shortening during a time of major shortening in the late Carboniferous Variscan foreland, contradicting suggestions that maximum Variscan shortening had negligible impact on Carboniferous basins in northern Britain. Local inversion structures appear to have strongly influenced local late Westphalian–Stephanian depocentres. In this respect, the Variscan foreland at Canonbie may have resembled a ‘broken’ foreland system. Variations in crustal rheology, fault strength and orientation, and mid-crustal detachments are suggested to have played important roles in determining strain localization and the nature of Westphalian–Stephanian depocentres in the Canonbie Coalfield.

Tectonic controlled sedimentary features at the NE marigin of the Sorgenfrei-Tornquist Zone (STZ), southern Sweden

<p>The Hanö Bay basin was formed during Late Cretaceous transgression as a sedimentary trough on the NE margin of the Sorgenfrei-Tornquist Zone (STZ), a narrow NW-SE striking intraplate inversion zone within the Fennoscandian Border Zone. Sedimentation within the basin was primarily controlled by inversion tectonics, resulting in a coarse-grained syn-inversion clastic wedge forming adjacent to the basin-bounding fault in the Santonian-Maastrichtian. Previous studies have highlighted the deposition of contourite sediments associated with topographic relief of the chalk sea created by such local inversion-induced uplift. Imaged upper Cretaceous clinforms in the marginal trough show a NE-ward progadational character, that is, away from the uplifted and eroded inversion zone. These extend along the inversion axis all the way to NE of the Mid-Polish trough.</p><p>To gain detailed stratigraphic constraints and to better understand the interaction of these syn-sedimentary features that developed during inversion tectonics, we use a combination of high-resolution multichannel seismic data (MCS) from the 2019 AL526 cruise and a number of key profiles from reprocessed 70-80’s legacy industry MCS. Preliminary results suggest a drift-moat system developed during a stepwise uplift of the SW shoulder of the STZ, with the uplift driven by transpressional reactivation of basement faults. The resultant aggradational wedge formed a shelf-margin extending fairly far into the basin. The overlying clinoform depositional successions clearly demonstrate several depositional stages; including highstand-progradation, highstand-aggradation and distinct transgression-retrogradation, during which an overall landward migration of the paleo-shoreline position is revealed. The results constrain relative sea-level changes in this area that were primarily related to tectonic events during the Santonian-Campanian.</p>