Occurrence of Double Bond in π-Aromatic Rings: An Easy Way to Design Doubly Aromatic Carbon-Metal Structures

A chemical bonding of several metallabenzenes and metallabenzynes was studied via an adaptive natural density partitioning (AdNDP) algorithm and the induced magnetic field analysis. A unique chemical bonding pattern was discovered where the M=C (M: Os, Re) double bond coexists with the delocalized 6c-2e π-bonding elements responsible for aromatic properties of the investigated complexes. In opposition to the previous description where 8 delocalized π-electrons were reported in metallabenzenes and metallabenzynes, we showed that only six delocalized π-electrons are present in those molecules. Thus, there is no deviation from Hückel’s aromaticity rule for metallabenzynes/metallabenzenes complexes. Based on the discovered bonding pattern, we propose two thermodynamically stable novel molecules that possess not only π-delocalization but also retain six σ-delocalized electrons, rendering them as doubly aromatic species. As a result, our investigation gives a new direction for the search for carbon-metal doubly aromatic molecules.

Design and Experiments of a Galloping-Based Wind Energy Harvester Using Quadruple Halbach Arrays

This study aims to develop a device for harvesting electrical energy from low-speed natural wind. Four linear Halbach arrays are adopted to design a high-performance galloping harvester with the advantage of high durability and efficiency at low-frequency vibrations. The results of magnetic field analysis reveal that there are optimal sizes of the main and transit magnets of the Halbach arrays and coil to obtain the maximum magnetic flux density normal to the coil. The experimental and simulation results show that the electrical external load resistance significantly affects the vibration amplitude and the galloping onset velocity of the harvester. The results also reveal that the performance of the original design using the quadruple Halbach array was lower than that of the existing harvester because of the heavy magnet mass embedded in the tip prism. The modified design, reducing mass, improved the performance by four times compared to the original design.