Получение пленки оксида железа на сапфировой подложке

Iron-oxide films on sapphire substrates were obtained using laser radiation with 1064-nm wavelength and studied by methods of scanning electron microscopy, energy-dispersive X-ray spectroscopy, and transmission Mössbauer spectroscopy. The obtained Fe_2O_3 films probably occur in a superparamagnetic state and may find application in gas sensors and various magnetic devices.

Thermodynamic properties of dilute Co-Fe solid solutions studied by 57Fe Mössbauer spectroscopy

The Co1-xFex alloys where x ranges from 0.01 to 0.06 were measured at room temperature using transmission Mössbauer spectroscopy (TMS). The analysis of the obtained data allowed the determination of the short-range order (SRO), the binding energy Eb between two iron atoms in the studied materials using the extended Hrynkiewicz-Królas idea and the enthalpy of solution HCo-Fe of Fe in Co. The results showed that the Fe atoms dissolved in a Co matrix interact repulsively and the estimated value of HCo-Fe = -0.166(33) eV/atom. Finally, values of the enthalpy of solution were used to predict the enthalpy of mixing for the Co-Fe system. These findings were compared with corresponding data given in the literature, which were derived from calorimetric experiments and from the cellular atomic model of alloys described by Miedema.

Mössbauer and XRD Studies on Composite Powder with Phases from Fe-Al System Obtained by Mechanically Activated SHS Mehtod

The systematic studies of non-stoichiometric phases from Fe-Al system obtained by selfpropagating high-temperature synthesis (SHS) were the aim of the present work. Investigations were performed using 57Fe transmission Mössbauer spectroscopy. The presence of nonsteichiomertic FeAl, FeAl2 and Fe2Al5 phases was found. It is can be concluded that the studied powder material is in non-equilibrium state. As the result of milling process the contents of FeAl phase increase whereas of FeAl2 and Fe2Al5 ones decrease. The determined crystal structure parameters and the hyperfine interaction parameters are presented and discussed.