Circular Dichroism Spectral Similarity Plots to Extend Validation and Correction to All Measured Wavelengths

Interlaboratory comparisons of circular dichroism (CD) spectra are useful for developing confidence in the measurements associated with optically active molecules. These measurements also help define the higher-order (secondary and tertiary) structure of biopolymers. Unfortunately, the extent of the validity of these measurements has been unclear. In this work, a method is described to extend CD validation over the entire observed wavelength range using what will be called spectral similarity plots. The method involves plotting, wavelength by wavelength, all measured spectral intensities of a sample at one concentration against the intensity values of the same material at a different concentration or pathlength. These spectral similarity plots validate the instrument in terms of spectral shape and whether the shape is shifted in intensity and/or in wavelength. This comparison tests the linearity of instrument’s signal, the balance of its left and right polarizations, its wavelengths, and its spectral intensity scales. When the process is applied to materials with accepted and archived intensity values, the method can be linked to older single-wavelength and double-wavelength calibration techniques. Further, spectral similarity testing of CD spectra from samples with different concentrations run in different labs suggests that improved interlaboratory validation of CD data is possible. Since a database of archival CD measurements is available online, spectral similarity comparisons could possibly provide the ability to compare linearity, polarization balance, wavelength, and spectral intensity between all current CD instruments. If the preliminary results published here prove robust and transferable, then comparisons of full-wavelength range spectra to archived data using spectral similarity plots should become part of the standard process to validate and calibrate the performance of CD instruments.

Влияние параллельного слоям магнитного поля на фототок в GaAs/AlAs p-i-n-структурах

The behavior of the photocurrent in GaAs / AlAs p-i-n heterostructures is studied in a magnetic field parallel to the heterolayers in the wavelength range from 395 to 650 nm. A strong dependence of the non-oscillating component of the photocurrent on the radiation wavelength associated with the suppression of the diffusion current by the magnetic field was found. It is shown that the behavior of the oscillating component of the photocurrent in a magnetic field does not depend on the wavelength of light and is determined by the transfer of electrons through the dimensional quantization level in a triangular near-barrier well. It is shown that the suppression of the oscillating component by the magnetic field is due to the smearing of the level in the triangular well due to the motion of electrons parallel to the walls of the well and perpendicular to the magnetic field.

3-mm wavelength range radar altitude sensors

In this study, we analyse the specific features of design of 3-mm wavelength range radar altitude sensors based on domestic-made super high frequency modules М55323 and М55328. Some results of full-scale tests are given.

Sulfide-Based Photocatalysts Using Visible Light, with Special Focus on In2S3, SnS2 and ZnIn2S4

Sulfides are frequently used as photocatalysts, since they absorb visible light better than many oxides. They have the disadvantage of being more easily photocorroded. This occurs mostly in oxidizing conditions; therefore, they are commonly used instead in reduction processes, such as CO2 reduction to fuels or H2 production. Here a summary will be presented of a number of sulfides used in several photocatalytic processes; where appropriate, some recent reviews will be presented of their behaviour. Results obtained in recent years by our group using some octahedral sulfides will be shown, showing how to determine their wavelength-dependent photocatalytic activities, checking their mechanisms in some cases, and verifying how they can be modified to extend their wavelength range of activity. It will be shown here as well how using photocatalytic or photoelectrochemical setups, by combining some enzymes with these sulfides, allows achieving the photo-splitting of water into H2 and O2, thus constituting a scheme of artificial photosynthesis.

Passive Measurements of the Refractive Index of Liquid Nitrogen and Free-flowing substances by the Prism Method in the Millimeter Wavelength Range

It is proposed to use the classical prism method in the millimeter wavelength range for measuring the refractive index of liquid and free-flowing substances, including mixtures with particle sizes comparable to the wavelength. The method is implemented using a hollow radio transparent rectangular prism filled with a test substance. The measurements were carried out in the thermal radiation mode using radiometers with horn-lens antennas at frequencies of 37.5 and 94 GHz. To measure the deflection of the refracted beam, a linear scanner with a black body mounted on it, cooled with liquid nitrogen, was used. The distance between the prism and the scanner was 1 m. The refractive index of liquid nitrogen, sand, gravel, marble chips and granular polyethylene were measured. Using the refractive formula and the Landau-Lifshitz-Looeng formula for calculating the dependence of the refractive index of binary mixtures on the bulk density of particles, estimates of the refractive index of the material of the particles that make up the substances under study are obtained. They are in satisfactory agreement with the known experimental data for quartz, feldspar, granite, and marble.

Comparison of Marine Gravity Measurements from Shipborne and Satellite Altimetry in the Arctic Ocean

To understand the influence of sea ice on shipborne gravity measurements and the accuracy of the satellite-altimetry-derived gravity field in the Arctic Ocean, we compared shipborne gravity measurements with those obtained from satellite altimetric gravity measurements. The influence of sea ice on the shipborne gravity measurements was mainly concentrated in the 0–6 km wavelength range, and the standard deviation of the noise amplitudes was 2.62 mGal. Compared to ice-free regions, the accuracies in the region with floating ice were reduced by 13% for DTU21 and 6% for SV31. Due to the influence of sea ice, satellite altimetric gravity data lose significant information in the 9–12 km wavelength range. The coherence curve of the shipborne gravity with bathymetry was nearly the same as that of the satellite altimetric gravity. The satellite data contain nearly all of the significant information that is present in the shipborne data. The differences between the shipborne and satellite gravity data are small and can be used to study the crustal structure of the Arctic.

Single-Port Coherent Perfect Loss in a Photonic Crystal Nanobeam Resonator

We numerically demonstrated single-port coherent perfect loss (CPL) with a Fabry–Perot resonator in a photonic crystal (PC) nanobeam by using a perfect magnetic conductor (PMC)-like boundary. The CPL mode with even symmetry can be reduced to a single-port CPL when a PMC boundary is applied. The boundary which acts like a PMC boundary, here known as a PMC-like boundary, and can be realized by adjusting the phase shift of the reflection from the PC when the wavelength of the light is within the photonic bandgap wavelength range. We designed and optimized simple Fabry–Perot resonator and coupler in nanobeam to get the PMC-like boundary. To satisfy the loss condition in CPL, we controlled the coupling loss in the resonator by modifying the lattice constant of the PC used for coupling. By optimizing the coupling loss, we achieved zero reflection (CPL) in a single port with a PMC-like boundary.