kinetic deconvolution
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2021 ◽  
pp. 179082
Author(s):  
Panagiotis M. Angelopoulos ◽  
Nebojsa Manic ◽  
Bojan Jankovic ◽  
Maria Taxiarchou


2020 ◽  
Vol 22 (16) ◽  
pp. 8889-8901
Author(s):  
Roman Svoboda ◽  
Zuzana Olmrová Zmrhalová ◽  
Dušan Galusek ◽  
Daniela Brandová ◽  
Jozef Chovanec

Whereas thermogravimetry monitors only a single-step CaOx decomposition reaction, DSC in addition reveals the complex competing CO oxidation kinetics.



Molecules ◽  
2019 ◽  
Vol 24 (13) ◽  
pp. 2515 ◽  
Author(s):  
Yamamoto ◽  
Koga

Examining the kinetics of solids’ thermal decomposition with multiple overlapping steps is of growing interest in many fields, including materials science and engineering. Despite the difficulty of describing the kinetics for complex reaction processes constrained by physico-geometrical features, the kinetic deconvolution analysis (KDA) based on a cumulative kinetic equation is one practical method of obtaining the fundamental information needed to interpret detailed kinetic features. This article reports the application of KDA to thermal decomposition of clay minerals and indigo–clay mineral hybrid compounds, known as Maya blue, from ancient Mayan civilization. Maya blue samples were prepared by heating solid mixtures of indigo and clay minerals (palygorskite and sepiolite), followed by purification. The multistep thermal decomposition processes of the clay minerals and Maya blue samples were analyzed kinetically in a stepwise manner through preliminary kinetic analyses based on a conventional isoconversional method and mathematical peak deconvolution to finally attain the KDA. By comparing the results of KDA for the thermal decomposition processes of the clay minerals and the Maya blue samples, information about the thermal decomposition steps of the indigo incorporated into the Maya blue samples was extracted. The thermal stability of Maya blue samples was interpreted through the kinetic characterization of the extracted indigo decomposition steps.



Molecules ◽  
2019 ◽  
Vol 24 (12) ◽  
pp. 2298 ◽  
Author(s):  
Nikita V. Muravyev ◽  
Alla N. Pivkina ◽  
Nobuyoshi Koga

Thermal decomposition of solids often includes simultaneous occurrence of the overlapping processes with unequal contributions in a specific physical quantity variation during the overall reaction (e.g., the opposite effects of decomposition and evaporation on the caloric signal). Kinetic analysis for such reactions is not a straightforward, while the applicability of common kinetic calculation methods to the particular complex processes has to be justified. This study focused on the critical analysis of the available kinetic calculation methods applied to the mathematically simulated thermogravimetry (TG) and differential scanning calorimetry (DSC) data. Comparing the calculated kinetic parameters with true kinetic parameters (used to simulate the thermoanalytical curves), some caveats in the application of the Kissinger, isoconversional Friedman, Vyazovkin and Flynn–Wall–Ozawa methods, mathematical and kinetic deconvolution approaches and formal kinetic description were highlighted. The model-fitting approach using simultaneously TG and DSC data was found to be the most useful for the complex processes assumed in the study.



2017 ◽  
Vol 112 ◽  
pp. 234-243 ◽  
Author(s):  
Khashayar Ghanbari ◽  
Morteza Ehsani ◽  
Ali Jannesari Ladani ◽  
Majid Mohseni ◽  
Mehdi Ghaffari




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