(1) Background: This work presents a high-efficiency, high sensitivity, compact rectifier based on a dual-band impedance matching network that employs a simple and straightforward T-matching circuit, for sub-1 GHz license-free applications. The development of a low-cost RF energy harvester dedicated to the ISM bands is introduced. The proposed rectifier design is optimized to operate at the sub-GHz frequency bands (0.9 to 2.4 GHz), specifically those at the ISM 900 and 2400 MHz. The motivation for this band is due to the low attenuation, well-known fundamental electromagnetic theories and background, and several wireless communications are emitting at those bands, such as RFID (2). Methods: The rectifier design is based on a simple, balanced single-series diode connected with a T-matching circuit. The dual-band performance is achieved by deploying reactive elements in each branch. The full mathematical analysis and simulation results are discussed in the manuscript. (3) Results: The rectifier can achieve a 80 MHz bandwidth around 920 MHz frequency and 200 MHz around the higher band 2.4 GHz. The resultant conversion efficiency level is maintained above 45% at both bands with a peak efficiency reaches up to 70% at the higher band. The optimum terminal load attached to the circuit at which the peak efficiency is achieved, is given as 4.7 kΩ. (4) Conclusion: Due to the compactness and small footprint, simple design, and simple integration with microwave circuits, the proposed rectifier architecture might find several potential applications in wireless RF energy harvesting.