Water Quality across the River Ganga Basin in India: Trends, Dominant Geochemical Processes and Impacts

<p>In a basin-wide survey of the River Ganga and key tributaries, from the Himalayan source to the Bay of Bengal in India, we aim to improve the conceptual understanding of downstream water quality trends along > 2000 km.  Here we explore the spatial distribution of a suite of inorganic and organic chemicals, nutrients and wastewater indicators to determine the dominant geochemical process controls across the basin.  Sampling was undertaken at 81 sites in the post-monsoon period of 2019.  We use chemical signatures to identify likely sources, characterise potential higher-pollution zones and to determine the relative importance of regional versus localized controls on the observed water quality parameters, including in relation to contaminant type.  The influence from key tributaries is determined.  We seek to unravel the relative importance of mechanisms such as dilution, evaporation, water-rock interactions and anthropogenic inputs in controlling contaminant distribution.  We assess the representativeness of river bank sampling in comparison to cross-river transects in select locations.  We compare our data to historical records across previous annual cycles, noting differences in extent of agreement according to contaminant type.  This coordinated, catchment-wide survey presents a much broader and more comprehensive dataset than typically reported, hence leading to substantially improved process understanding of dominant controls on contaminant distribution across the catchment.  This work may have implications on informing future monitoring efforts and in identifying future remediation priorities.</p><p><strong>Acknowledgements </strong>This research was supported by the NERC-DST Indo-UK Water Quality Programme (NE/R003386/1 and DST/TM/INDO-UK/2K17/55(C) & 55(G) to DP et al; NE/R003106/1 and DST/TM/INDO-UK/2K17/30 to DR et al.), NE/R000131/1 to Jenkins et al. and a Dame Kathleen Ollerenshaw Fellowship (LR).</p>

Mathematical Modeling of Heat, Mass and Moisture Transfer in Catalytic Porous Media

The discovery of ordered mesoporous materials has opened great opportunities for new applications in heterogeneous catalysis e.g. in soil purification processes. The focus of this study is the development of a mathematical model to simulate heat, mass and moisture transfer in soil arrays tacking into account catalytic micro- or nanoparticles. The nonlinear mathematical model of contaminant distribution in unsaturated catalytic porous media to the filter-trap in non-isothermal conditions is presented. The finite differences method was used to find the numerical solution of the corresponding boundary value problem and the analytical solution for mass transfer in catalytic micro- or nanoparticles was presented as well. Numerical experiments and their analysis were conducted using NanoSurface software complex.

Nonlinear Mathematical Model of Contaminant Distribution in Unsaturated Catalytic Porous Media

The nonlinear mathematical model of contaminant distribution in unsaturated catalytic porous media to the filter-trap in isothermal conditions is presented. The mathematical model takes into account the micro and the meso/macro scale factors of the heat and mass transfer processes. The numerical solution of the respective boundary value problem was obtained by the method of finite differences. The analytical solution for mass transfer in nanoparticles was presented as well.